Determination of benzodiazepines in beverages using green extraction methods and capillary HPLC-UV detection

2018 ◽  
Vol 154 ◽  
pp. 492-500 ◽  
Author(s):  
Maurizio Piergiovanni ◽  
Achille Cappiello ◽  
Giorgio Famiglini ◽  
Veronica Termopoli ◽  
Pierangela Palma
2013 ◽  
Vol 48 (2) ◽  
pp. 133-144 ◽  
Author(s):  
Bahman Banihashemi ◽  
Ronald L. Droste

The purpose of this study was to develop and optimize a simple and economical method for the extraction and determination of bisphenol-A (BPA), using high-performance liquid chromatography (HPLC) coupled with ultraviolet (UV) detection at environmentally relevant concentrations in both dissolved and particulate phases. To clean-up and pre-concentrate liquid samples, solid-phase extraction (SPE) method was optimized with regard to pH, volume, washing and elution solvents for high recovery of BPA and good clean-up. For sludge samples, four extraction methods, microwave-assisted extraction (MAE), ultrasonication extraction (USE), accelerated solvent extraction (ASE) and high-pressure homogenizer (HPH), were compared for isolation of BPA from activated sludge samples. Analysis was performed by optimized procedures using HPLC–UV. Recoveries of BPA from liquid and solid phases were determined to be 90–105 and 60–90%, respectively. MAE had the highest recovery among examined extraction methods. The method detection limits were 100 ng/L and 100 ng/g dry weight. To validate the method, a mass balance study was conducted with 100 mL spiked mixed liquor volatile suspended solids (VSS) samples from three laboratory-scale porous pot reactors and concentrations of BPA in liquid and solid phases were determined using the optimized conditions. The results had an average 86% overall recovery for all samples.


2020 ◽  
Vol 49 (8) ◽  
pp. 822-828
Author(s):  
Jimin Yoon ◽  
Naeun Kim ◽  
Ahyeong Jeon ◽  
Jihyun Kwon ◽  
Sang-Hoon Lee ◽  
...  

2020 ◽  
Vol 75 (11) ◽  
pp. 1451-1460
Author(s):  
Z. A. Temerdashev ◽  
V. V. Milevskaya ◽  
L. P. Ryabokon’ ◽  
N. N. Latin ◽  
N. V. Kiseleva ◽  
...  

Talanta ◽  
2021 ◽  
Vol 232 ◽  
pp. 122286
Author(s):  
María Melania Ramírez-Quesada ◽  
Jimmy Venegas-Padilla ◽  
José Pablo Sibaja-Brenes ◽  
Bryan Calderón-Jiménez

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2995
Author(s):  
Laurynas Jarukas ◽  
Liudas Ivanauskas ◽  
Giedre Kasparaviciene ◽  
Juste Baranauskaite ◽  
Mindaugas Marksa ◽  
...  

Black, brown, and light peat and sapropel were analyzed as natural sources of organic and humic substances. These specific substances are applicable in industry, agriculture, the environment, and biomedicine with well-known and novel approaches. Analysis of the organic compounds fulvic acid, humic acid, and humin in different peat and sapropel extracts from Lithuania was performed in this study. The dominant organic compound was bis(tert-butyldimethylsilyl) carbonate, which varied from 6.90% to 25.68% in peat extracts. The highest mass fraction of malonic acid amide was in the sapropel extract; it varied from 12.44% to 26.84%. Significant amounts of acetohydroxamic, lactic, and glycolic acid derivatives were identified in peat and sapropel extracts. Comparing the two extraction methods, it was concluded that active maceration was more efficient than ultrasound extraction in yielding higher amounts of organic compounds. The highest amounts of fulvic acid (1%) and humic acid and humin (15.3%) were determined in pure brown peat samples. This research on humic substances is useful to characterize the peat of different origins, to develop possible aspects of standardization, and to describe potential of the chemical constituents.


1979 ◽  
Vol 84 (2) ◽  
pp. 163-171 ◽  
Author(s):  
A.-C. Ericson ◽  
M. Sjöquist ◽  
H. R. Ulfendahl

2010 ◽  
Vol 25 (5) ◽  
pp. 588-593 ◽  
Author(s):  
Mitsuhiro Kinoshita ◽  
Naotaka Kakoi ◽  
Yu-ki Matsuno ◽  
Takao Hayakawa ◽  
Kazuaki Kakehi

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