Doppler-broadened NICE-OHMS beyond the cavity-limited weak absorption condition – I. Theoretical description

Author(s):  
Weiguang Ma ◽  
Isak Silander ◽  
Thomas Hausmaninger ◽  
Ove Axner
2018 ◽  
Vol 8 (9) ◽  
pp. 1630 ◽  
Author(s):  
Xue Zhou ◽  
Jia Yu ◽  
Lin Wang ◽  
Zhiguo Zhang

The relationship between absorption and gas concentration was studied using a diffuse integrating cavity as a gas cell. The light transmission process in an arbitrary diffuse cavity was theoretically derived based on a beam reflection analysis. It was found that a weak absorption condition must be satisfied to ensure a linear relationship between absorbance and gas concentration. When the weak absorption condition is not satisfied, a non-linear relation will be observed. A 35 × 35 × 35 cm diffuse integrating cavity was used in the experiment. Different oxygen concentrations were measured by detecting the P9 absorption line at 763.8 nm, based on tunable diode laser absorption spectroscopy. The relationship between the absorption signals and oxygen concentration was linear at low oxygen concentrations and became non-linear when oxygen concentrations were higher than 21%. The absorbance value of this transition point was 0.17, which was considered as the weak absorption condition for this system. This work studied the theoretical reason for the non-linear phenomenon and provided an experimental method to determine the transition point when using a diffuse integrating cavity as a gas cell.


2000 ◽  
Vol 627 ◽  
Author(s):  
Prabhu R. Nott ◽  
K. Kesava Rao ◽  
L. Srinivasa Mohan

ABSTRACTThe slow flow of granular materials is often marked by the existence of narrow shear layers, adjacent to large regions that suffer little or no deformation. This behaviour, in the regime where shear stress is generated primarily by the frictional interactions between grains, has so far eluded theoretical description. In this paper, we present a rigid-plastic frictional Cosserat model that captures thin shear layers by incorporating a microscopic length scale. We treat the granular medium as a Cosserat continuum, which allows the existence of localised couple stresses and, therefore, the possibility of an asymmetric stress tensor. In addition, the local rotation is an independent field variable and is not necessarily equal to the vorticity. The angular momentum balance, which is implicitly satisfied for a classical continuum, must now be solved in conjunction with the linear momentum balances. We extend the critical state model, used in soil plasticity, for a Cosserat continuum and obtain predictions for flow in plane and cylindrical Couette devices. The velocity profile predicted by our model is in qualitative agreement with available experimental data. In addition, our model can predict scaling laws for the shear layer thickness as a function of the Couette gap, which must be verified in future experiments. Most significantly, our model can determine the velocity field in viscometric flows, which classical plasticity-based model cannot.


2005 ◽  
Vol 64 (3) ◽  
pp. 227-237
Author(s):  
A. V. Zhizhelev ◽  
S. V. Zhilinskii ◽  
A. V. Klyshevskii ◽  
S. A. Golovin

Author(s):  
Р. М. Плекан ◽  
В. Ю. Пойда ◽  
І. В. Хіміч

2013 ◽  
Vol 58 (4) ◽  
pp. 1401-1403 ◽  
Author(s):  
J.A. Bartkowska ◽  
R. Zachariasz ◽  
D. Bochenek ◽  
J. Ilczuk

Abstract In the present work, the magnetoelectric coupling coefficient, from the temperature dependences of the dielectric permittivity for the multiferroic composite was determined. The research material was ferroelectric-ferromagnetic composite on the based PZT and ferrite. We investigated the temperature dependences of the dielectric permittivity (") for the different frequency of measurement’s field. From the dielectric measurements we determined the temperature of phase transition from ferroelectric to paraelectric phase. For the theoretical description of the temperature dependence of the dielectric constant, the Hamiltonian of Alcantara, Gehring and Janssen was used. To investigate the dielectric properties of the multiferroic composite this Hamiltonian was expressed under the mean-field approximation. Based on dielectric measurements and theoretical considerations, the values of the magnetoelectric coupling coefficient were specified.


1988 ◽  
Vol 53 (4) ◽  
pp. 671-685 ◽  
Author(s):  
Oldřich Pytela ◽  
Miroslav Ludwig

A theoretical description of the effect of changed composition of mixed solvents on processes in solutions has been suggested on the basis of the proportionality between the Gibbs energy change of the process and that of the solvent due to the transition from pure components to the mixture. The additional Gibbs energy has been expressed by means of the so-called classical functions by Margules, van Laar-Wohl, and van Laar-Null. The application to 115 various processes (pK, IR, UV-VIS, NMR, log k, and others) has confirmed that the theoretical presumptions are justified, the most suitable being Margules' 4th order model which shows a statistically significant difference from the models of lower orders.


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