Due to the widespread use of antibiotics in medical treatment, animal husbandry and aquaculture, a large number of antibiotics are discharged into the environment as metabolites or in their original state, causing pollution to water bodies, which is a serious issue. In this study, a novel nanocomposite adsorbent MIL-53/D201 was successfully prepared by hydrothermal synthesis. This approach overcomes the disadvantage of easy dissociation of MOF material in the water phase and realizes the efficient removal of antibiotic azlocillin sodium in water. The crystal morphology and basic structure of the composites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy scattering spectroscopy (EDS), and specific surface area and porosity analyzer (BET). The results showed that MIL-53 was successfully synthesized in situ in D201. The results of adsorption experiments show that the maximum saturated adsorption capacity of the composite is 122.3 mg/g when the dosage of the composite is 1.0 g/L. Compared with pure MIL-53 material, the composite material exhibits greater stability and efficient adsorption performance for target pollutants at different pH values. The adsorption process accords with the quasi-second-order kinetic adsorption model and Langmuir adsorption isothermal model. After five cycles of adsorption and desorption, the removal rate of MIL-53/D201 to azlocillin sodium was still above 87%.
Acid green crystal-based in situ synthesis of polyaniline hollow nanotubes for the adsorption of anionic and cationic dyes
