Two dimensional perovskite La 2 Ti 2 O 7 nanosheet as Pt catalyst support for photo-assisted methanol oxidation reaction

2017 ◽  
Vol 80 ◽  
pp. 231-238 ◽  
Author(s):  
Jiayue Hu ◽  
Mingjuan Sun ◽  
Xiaoyan Cai ◽  
Chunyang Zhai ◽  
Junying Zhang ◽  
...  
2017 ◽  
Vol 5 (36) ◽  
pp. 19467-19475 ◽  
Author(s):  
Jing-Jing Fan ◽  
You-Jun Fan ◽  
Rui-Xiang Wang ◽  
Sheng Xiang ◽  
Hua-Guo Tang ◽  
...  

Sulfur-doped multi-walled carbon nanotubes (S-MWCNTs) derived from PEDOT-functionalized MWCNTs can significantly improve the dispersion of supported Pt nanoparticles and enhance their electrocatalytic performance for the MOR.


2016 ◽  
Vol 18 (22) ◽  
pp. 14859-14866 ◽  
Author(s):  
Geon-Hyoung An ◽  
Eun-Hwan Lee ◽  
Hyo-Jin Ahn

Ru and RuO2 nanofiber composites arranged into nanosized grains as Pt catalyst supports are synthesized by electrospinning and post-calcination, which show excellent electrochemical activity.


2015 ◽  
Vol 273 ◽  
pp. 33-40 ◽  
Author(s):  
Yonghao Xiao ◽  
Zhenggao Fu ◽  
Guohe Zhan ◽  
Zhanchang Pan ◽  
Chumin Xiao ◽  
...  

2018 ◽  
Vol 18 (12) ◽  
pp. 8296-8301
Author(s):  
Ruimin Xing ◽  
Rui Li ◽  
Liangyu Tong ◽  
Bingyue Li ◽  
Deling Kong ◽  
...  

Special morphological noble metal-based bimetallic alloy nanostructures became popular for methanol oxidation reaction in order to reduce the high cost of the Pt catalyst and improve the catalyst activity. Herein, we developed a facile one pot hydrothermal method for the synthesis of platinum–copper bimetallic nanoflowers (Pt–Cu NFs) in the presence of hexadecyl trimethyl ammonium bromide (CTAB). The morphology, structure and composition of Pt–Cu NFs were carefully characterized and the synthesized parameters were optimized systematically by adjusting different experimental conditions. Results showed that the CTAB usage and the NaI amount were critical to the controlled synthesis of Pt–Cu NFs. The Pt–Cu NFs were high-performance electrocatalysts for the methanol oxidation reaction (MOR) with superior activity and superior stability in alkaline solution, which were far better than pure Pt nanoparticle electrocatalysts.


Carbon ◽  
2015 ◽  
Vol 87 ◽  
pp. 424-433 ◽  
Author(s):  
Yuanqin Chang ◽  
Fei Hong ◽  
Jinxin Liu ◽  
Minsui Xie ◽  
Qianling Zhang ◽  
...  

2006 ◽  
Vol 51 ◽  
pp. 181-186
Author(s):  
Marco Alvisi ◽  
Giovanna Galtieri ◽  
L. Giorgi ◽  
Emanuele Serra ◽  
Tiziana Di Luccio ◽  
...  

The proton exchange membrane fuel cells (PEMFC) have been developed mainly as a power source for vehicles, power generation and consumer electronics since they combine high energy conversion efficiency at relatively low temperatures without pollutants emission in the environment. An electrode for a PEMFC is a layered structure composed by a catalyst layer deposited on a porous carbon substrate. The substrate is usually covered by a diffusion layer that enhances the gas and water flow. Platinum nanoparticles supported by carbon microparticles are commonly employed as catalyst layer. In this work an extreme ultra-low loading of Pt catalyst (< 0.02 mg/cm2) has been deposited by magnetron sputtering on gas diffusion electrodes, with different carbon supports (Vulcan and SuperP), in order to enhance the activity of PEM fuel cells. The morphology (shape and grain size) and microstructure have been studied combining field emission scanning electron microscopy (FEG-SEM), grazing incidence synchrotron x-ray diffraction (GIXRD) and x-ray photoelectron spectroscopy (XPS). The results presented here concern the evolution of the cluster size and shape after the ageing, induced by cyclic voltammetry for methanol oxidation reaction.


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