Assessment of radon and potentially toxic metals in agricultural soils of Punjab, India

In recent years, Qatar has witnessed exponential growth in the human population, urbanization, and increased anthropogenic activities, including agriculture. Potentially toxic environmental contaminants, including metals and metalloids, are commonly found in emerging economies. At high concentrations, elements such as As, Cr, and Ni can be hazardous and may lead to various health problems in humans, including cancer. The current study measured As, Cd, Cr, Cu, Ni, Pb, V, and Zn concentrations in agricultural soils. Pollution levels and potential negative impacts on human and environmental health were determined using the United States Environmental Protection Agency (USEPA) standard methodologies. According to the study’s findings, the studied element concentrations descended in the following order: Zn > Cr > V > Ni > As > Cu > Pb > Cd. Of these, As (27.6 mg/kg), Cr (85.7 mg/kg), Ni (61.9 mg/kg), and Zn (92.3 mg/kg) concentrations were higher than average world background levels. Each of these elements also had an enrichment factor (EF > 1), indicating their anthropogenic origin. The combined pollution load index (PLI > 1) and geo-accumulation index (Igeo) range values of −0.2–2.5 further indicated that the soil was up to 58% polluted. However, the ecological risk factor (Er ≤ 40.6) and potential ecological risk index (PERI = 79.6) suggested low ecological risk. A human health risk evaluation showed that only As, with a hazard index (HI) of 1.3, posed a noncarcinogenic risk to infants. Additionally, As, Cr, and Ni, with total carcinogenic risk (TCR) values of 1.18 × 10−4 and 2.06 × 10−4 for adults and children, respectively, proved carcinogenic to both age groups. The elements’ carcinogenic risk (CR) potential descended in the following order: Ni > As > Cr. Additionally, for both adults and children, oral ingestion is the most likely exposure pathway. Our findings support the need for closer monitoring of potentially toxic metals and metalloids levels in cultivated soils and farm produce in Qatar. Reducing the elements’ bioavailability in soil and developing innovative remediation technologies is needed to limit potential risks to human health. Further studies on As, Cr, and Ni gastrointestinal bioaccessibilities are needed to fully understand the effects after long-term exposure and the cancer-causing potential of these elements over a lifetime.

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Geogenic enrichment of potentially toxic metals in agricultural soils derived from black shale in northwest Zhejiang, China: Pathways to and risks from associated crops

Ecotoxicology and Environmental Safety ◽

10.1016/j.ecoenv.2021.112102 ◽

2021 ◽

Vol 215 ◽

pp. 112102

Author(s):

Shuang Zhang ◽

Yingfei Xu ◽

Mengjie Wu ◽

Xiali Mao ◽

Yucai Yao ◽

...

Keyword(s):

Black Shale ◽

Toxic Metals ◽

Agricultural Soils ◽

Potentially Toxic Metals

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Spatial distribution and risk assessment of toxic metals in agricultural soils from endemic nasopharyngeal carcinoma region in South China

Open Geosciences ◽

10.1515/geo-2020-0110 ◽

2020 ◽

Vol 12 (1) ◽

pp. 568-579

Author(s):

Liping Mo ◽

Yongzhang Zhou ◽

Gnanachandrasamy Gopalakrishnana ◽

Xingyuan Li

Keyword(s):

Nasopharyngeal Carcinoma ◽

South China ◽

Toxic Metals ◽

Agricultural Soils ◽

Hazard Index ◽

Toxic Metal ◽

Carcinogenic Risk ◽

Pollution Indices ◽

High Incidence ◽

Low Incidence

AbstractSihui city (South China) is much affected by nasopharyngeal carcinoma (NPC). To investigate the relationships between the toxic metals in soil and NPC incidence in Sihui, 119 surface soil samples were collected from agricultural fields and analyzed. The soil As–Cr contents in Longjiang (high-incidence area) are significantly lower than those in Weizheng and Jianglin (low-incidence areas), whereas the soil Pb content in Longjiang is significantly higher than that in Weizheng. The Nemerow pollution indices (PIN) of soils decrease in the order of Jianglin > Weizheng > Longjiang. The enrichment factor (EF) of Cd indicates that the Cd enrichment is contributed by human activities. Potential toxic metal-related ecological risk values decrease in the order of Jianglin > Weizheng > Longjiang. The mean hazard index (HI) value of Longjiang was lower than those of Weizheng and Jianglin. There are no adverse noncarcinogenic health effects of soil toxic metals to adults in the study areas. Carcinogenic risks of As and Cr via ingestion and dermal contact and total carcinogenic risk are within the warning range, from 10−6 to 10−4. Hence, we suggest that toxic metals in the soil may not be major geochemical carcinogenic factors of high NPC incidence in Sihui.

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Accumulation of Potentially Toxic Metals in Egyptian Alluvial Soils, Berseem Clover (Trifolium alexandrinum L.), and Groundwater after Long-Term Wastewater Irrigation

Agriculture ◽

10.3390/agriculture11080713 ◽

2021 ◽

Vol 11 (8) ◽

pp. 713

Author(s):

Ahmed S. Abuzaid ◽

Hossam S. Jahin ◽

Amany A. Asaad ◽

Mohamed E. Fadl ◽

Mohamed A. E. AbdelRahman ◽

...

Keyword(s):

Toxic Metals ◽

Translocation Factor ◽

Wastewater Irrigation ◽

Alluvial Soils ◽

Trifolium Alexandrinum ◽

Potentially Toxic Metals ◽

Groundwater Samples ◽

Safe Limits ◽

Berseem Clover ◽

Irrigated Soils

The reduced availability of water resources in Egypt has imposed the need to intensify the use of wastewater for crop irrigation in the alluvial soils of anthropogenic origin. Relevant effects can derive from contents of potentially toxic metals (PTMs) in supply resources soils, crops, and groundwater in these areas. For this reason the PTM content has to be monitored to evaluate and minimize health hazards. Therefore, in this context, two areas of the SE Nile Delta subjected to 25 year of wastewater irrigation, using agricultural drainage water (ADW) and mixed wastewater (MWW) were chosen and compared with a nearby site irrigated with Nile freshwater (NFW). At each of the three sites, ten samples of irrigation water, topsoil, berseem clover (Trifolium alexandrinum L.) plants, and seven groundwater samples were collected and analyzed for Cr, Co, Cu, Pb, Ni, and Zn. Results indicate that the total contents of Co, Cu, Ni, and Zn in soils collected from the three sampling sites and Pb in the MWW-irrigated soils were higher than their average natural contents in the earth’s crust, indicating potential risks. The DTPA-extractable contents of Cu in the three sites, in addition to Pb and Zn in the MWW-irrigated soils, exceeded the safe limits. The MWW-irrigated soils showed a considerable degree of metal contamination, while the NFW- and ADW-irrigated soils showed moderate and low levels of contamination, respectively. The contents of the six PTMs in the three sites showed low individual ecological risks, except for Pb in the MWW-irrigated soils that showed a moderate risk; however, the overall ecological risk remained low in all samples. The values of Co, Cu, and Ni in berseem shoot in addition to Pb from the MWW-irrigated soils were over the maximum permissible levels for animal feeding. Values of root-to-shoot translocation factor were lower than 1.0 for Cr, Co and Ni but higher than 1.0 for Cu, Pb, and Zn. Berssem plant is a good candidate for phytofiltration of Cr, Co and Ni, while for extracting Cu, Pb and Zn from polluted soils. The groundwater samples collected from the three sampling sites showed lower metal concentrations than the safe limits for drinking standards. Further remediation studies should be taken into account to alleviate potential environmental and health-related risks when using supply resources different from freshwater.

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