An approach to carbon nanotubes with high surface area and large pore volume

2007 ◽  
Vol 100 (1-3) ◽  
pp. 1-5 ◽  
Author(s):  
Jun Jie Niu ◽  
Jian Nong Wang ◽  
Ying Jiang ◽  
Lian Feng Su ◽  
Jie Ma
2020 ◽  
Vol 56 (1) ◽  
pp. 66-69 ◽  
Author(s):  
Bin Wang ◽  
Xiu-Liang Lv ◽  
Jie Lv ◽  
Li Ma ◽  
Rui-Biao Lin ◽  
...  

A highly chemically and thermally stable mesoporous hydrogen-bonded organic framework with a high surface area and a large pore volume has been rationally designed and constructed.


2016 ◽  
Vol 178 ◽  
pp. 248-251 ◽  
Author(s):  
Guohui Cai ◽  
Xiaohai Zheng ◽  
Yong Zheng ◽  
Yihong Xiao ◽  
Ying Zheng

Nanoscale ◽  
2021 ◽  
Author(s):  
Hui Wen ◽  
Shengqi Zhang ◽  
tao yu ◽  
ZiYu Yi ◽  
Rui Guo

As a new type of crystalline porous material, the imidazole zeolite framework (ZIF) has attracted widespread attention due to its ultra-high surface area, large pore volume, and unique advantages of...


2019 ◽  
Vol 43 (3) ◽  
pp. 1380-1387 ◽  
Author(s):  
Jun Zhang ◽  
Jinxin Guo ◽  
Yang Xia ◽  
Yongping Gan ◽  
Hui Huang ◽  
...  

Hierarchically assembled carbon nanosheets with a high surface area and an ultra large pore volume were derived by the direct carbonization of an adipic acid and zinc powder mixture. This structure enables fast ion and electron kinetics, resulting in an enhanced electrochemical performance of lithium–sulfur batteries.


2016 ◽  
Vol 75 (2) ◽  
pp. 350-357
Author(s):  
Graham Dawson ◽  
Wei Chen ◽  
Luhua Lu ◽  
Kai Dai

The adsorption properties of two nanomorphologies of trititanate, nanotubes (TiNT) and plates (TiNP), prepared by the hydrothermal reaction of concentrated NaOH with different phases of TiO2, were examined. It was found that the capacity for both morphologies towards methylene blue (MB), an ideal pollutant, was extremely high, with the TiNP having a capacity of 130 mg/g, higher than the TiNT, whose capacity was 120 mg/g at 10 mg/L MB concentration. At capacity, the well-dispersed powders deposit on the floor of the reaction vessel. The two morphologies had very different structural and adsorption properties. TiNT with high surface area and pore volume exhibited exothermic monolayer adsorption of MB. TiNP with low surface area and pore volume yielded a higher adsorption capacity through endothermic multilayer adsorption governed by pore diffusion. TiNP exhibited a higher negative surface charge of −23 mV, compared to −12 mV for TiNT. The adsorption process appears to be an electrostatic interaction, with the cationic dye attracted more strongly to the nanoplates, resulting in a higher adsorption capacity and different adsorption modes. We believe this simple, low cost production of high capacity nanostructured adsorbent material has potential uses in wastewater treatment.


2017 ◽  
Vol 1 (6) ◽  
pp. 1414-1424 ◽  
Author(s):  
Michael Cox ◽  
Robert Mokaya

Mesoporous carbons (with up to 95% of pore volume from mesopores) with surface area and pore volume of ∼4000 m2 g−1 and ∼3.6 cm3 g−1, respectively, are excellent CO2 absorbers under pre combustion conditions and can store 55 mmol g−1 (i.e., 2.42 g g−1) or 930 g l−1 at 25 °C and 50 bar.


Nanomaterials ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 1328 ◽  
Author(s):  
Marlon Danny Jerez-Masaquiza ◽  
Lenys Fernández ◽  
Gema González ◽  
Marjorie Montero-Jiménez ◽  
Patricio J. Espinoza-Montero

In this work, a new hydrogen peroxide (H2O2) electrochemical sensor was fabricated. Prussian blue (PB) was electrodeposited on a glassy carbon (GC) electrode modified with zirconia doped functionalized carbon nanotubes (ZrO2-fCNTs), (PB/ZrO2-fCNTs/GC). The morphology and structure of the nanostructured system were characterized by scanning and transmission electron microscopy (TEM), atomic force microscopy (AFM), specific surface area, X-ray diffraction (XRD), thermogravimetric analysis (TGA), Raman and Fourier transform infrared (FTIR) spectroscopy. The electrochemical properties were studied by cyclic voltammetry (CV) and chronoamperometry (CA). Zirconia nanocrystallites (6.6 ± 1.8 nm) with cubic crystal structure were directly synthesized on the fCNTs walls, obtaining a well dispersed distribution with a high surface area. The experimental results indicate that the ZrO2-fCNTs nanostructured system exhibits good electrochemical properties and could be tunable by enhancing the modification conditions and method of synthesis. The fabricated sensor could be used to efficiently detect H2O2, presenting a good linear relationship between the H2O2 concentration and the peak current, with quantification limit (LQ) of the 10.91 μmol·L−1 and detection limit (LD) of 3.5913 μmol·L−1.


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