Source rock pyrolysis and bulk kinetic modelling of Miocene sedimentary sequences in southeastern Sabah, Malaysia: The variability of thermal maturity to oil-gas producing kerogen

2022 ◽  
Vol 208 ◽  
pp. 109513
Author(s):  
Nur Amalina Ahmad Thana’Ani ◽  
Khairul Azlan Mustapha ◽  
Mohammed Idris
2019 ◽  
Vol 24 (6) ◽  
pp. 74
Author(s):  
Adnan Q. Mahdi1 ◽  
Fawzi M. Al-Beyati2 ◽  
A. M. Al Tarif ◽  
El-Arabi H. Shendi4 ◽  
Mohamed I .Abdel-fattah4

This work depends on a detailed optical observation study of sedimentary organic facies from the Hauterivian – early Aptian Ratawi and Zubair formations from the Ba-1 well, Balad oilfield, Central Iraq. This study has manifested the advantages of palynofacies analysis methods for source rock evaluation of the studied formations, twenty five cutting rock samples organic facies data indicate a wide variation of source richness, quality and thermal maturity, the Ratawi Formation samples has the Type-II< I kerogen indicates marine environment in immature stage, while Zubair Formation has the Type-II<<  I kerogen (oil-gas prone) reflect the marine environment with  terrigenous influx in early mature to mature stage (early oil window).   http://dx.doi.org/10.25130/tjps.24.2019.111


2020 ◽  
Vol 10 (8) ◽  
pp. 3207-3225
Author(s):  
Mohamed Ragab Shalaby ◽  
Muhammad Izzat Izzuddin bin Haji Irwan ◽  
Liyana Nadiah Osli ◽  
Md Aminul Islam

Abstract This research aims to conduct source rock characterization on the Narimba Formation in the Bass Basin, Australia, which is made of mostly sandstone, shale and coal. The geochemical characteristics and depositional environments have been investigated through a variety of data such as rock–eval pyrolysis, TOC, organic petrography and biomarkers. Total organic carbon (TOC) values indicated good to excellent organic richness with values ranging from 1.1 to 79.2%. Kerogen typing of the examined samples from the Narimba Formation indicates that the formation contains organic matter capable of generating kerogen Type-III, Type-II-III and Type-II which is gas prone, oil–gas prone and oil prone, respectively. Pyrolysis maturity parameters (Tmax, PI), in combination with vitrinite reflectance and some biomarkers, all confirm that all samples are at early mature to mature and are in the oil and wet gas windows. The biomarkers data (the isoprenoids (Pr/Ph), CPI, isoprenoids/n-alkanes distribution (Pr/nC17 and Ph/nC18), in addition to the regular sterane biomarkers (C27, C28 and C29) are mainly used to evaluate the paleodepositional environment, maturity and biodegradation. It has been interpreted that the Narimba Formation was found to be deposited in non-marine (oxygen-rich) depositional environment with a dominance of terrestrial plant sources. All the analyzed samples show clear indication to be considered at the early mature to mature oil window with some indication of biodegradation.


2017 ◽  
Vol 5 (2) ◽  
pp. SF225-SF242 ◽  
Author(s):  
Xun Sun ◽  
Quansheng Liang ◽  
Chengfu Jiang ◽  
Daniel Enriquez ◽  
Tongwei Zhang ◽  
...  

Source-rock samples from the Upper Triassic Yanchang Formation in the Ordos Basin of China were geochemically characterized to determine variations in depositional environments, organic-matter (OM) source, and thermal maturity. Total organic carbon (TOC) content varies from 4 wt% to 10 wt% in the Chang 7, Chang 8, and Chang 9 members — the three OM-rich shale intervals. The Chang 7 has the highest TOC and hydrogen index values, and it is considered the best source rock in the formation. Geochemical evidence indicates that the main sources of OM in the Yanchang Formation are freshwater lacustrine phytoplanktons, aquatic macrophytes, aquatic organisms, and land plants deposited under a weakly reducing to suboxic depositional environment. The elevated [Formula: see text] sterane concentration and depleted [Formula: see text] values of OM in the middle of the Chang 7 may indicate the presence of freshwater cyanobacteria blooms that corresponds to a period of maximum lake expansion. The OM deposited in deeper parts of the lake is dominated by oil-prone type I or type II kerogen or a mixture of both. The OM deposited in shallower settings is characterized by increased terrestrial input with a mixture of types II and III kerogen. These source rocks are in the oil window, with maturity increasing with burial depth. The measured solid-bitumen reflectance and calculated vitrinite reflectance from the temperature at maximum release of hydrocarbons occurs during Rock-Eval pyrolysis ([Formula: see text]) and the methylphenanthrene index (MPI-1) chemical maturity parameters range from 0.8 to [Formula: see text]. Because the thermal labilities of OM are associated with the kerogen type, the required thermal stress for oil generation from types I and II mixed kerogen has a higher and narrower range of temperature for hydrocarbon generation than that of OM dominated by type II kerogen or types II and III mixed kerogen deposited in the prodelta and delta front.


2020 ◽  
Vol 10 (8) ◽  
pp. 3191-3206
Author(s):  
Olusola J. Ojo ◽  
Ayoola Y. Jimoh ◽  
Juliet C. Umelo ◽  
Samuel O. Akande

Abstract The Patti Formation which consists of sandstone and shale offers the best potential source beds in the Bida Basin. This inland basin is one of the basins currently being tested for hydrocarbon prospectivity in Nigeria. Fresh samples of shale from Agbaja borehole, Ahoko quarry and Geheku road cut were analysed using organic geochemical and palynological techniques to unravel their age, paleoecology, palynofacies and source bed hydrocarbon potential. Palynological data suggest Maastrichtian age for the sediments based on the abundance of microfloral assemblage; Retidiporites magdalenensis, Echitriporites trianguliformis and Buttinia andreevi. Dinocysts belonging to the Spiniferites, Deflandrea and Dinogymnium genera from some of the analysed intervals are indicative of freshwater swamp and normal sea conditions. Palynological evidence further suggests mangrove paleovegetation and humid climate. Relatively high total organic carbon TOC (0.77–8.95 wt%) was obtained for the shales which implies substantial concentration of organic matter in the source beds. Hydrocarbon source rock potential ranges from 0.19 to 0.70 mgHC/g.rock except for a certain source rock interval in the Agbaja borehole with high yield of 25.18 mgHC/g.rock. This interval also presents exceptionally high HI of 274 mgHC/g.TOC and moderate amount of amorphous organic matter. The data suggests that in spite of the favourable organic matter quantity, the thermal maturity is low as indicated by vitrinite reflectance and Tmax (0.46 to 0.48 Ro% and 413 to 475 °C, respectively). The hydrocarbon extracts show abundance of odd number alkanes C27–C33, low sterane/hopane ratio and Pr/Ph > 2. We conclude that the source rocks were terrestrially derived under oxic condition and dominated by type III kerogen. Type II organic matter with oil and gas potential is a possibility in Agbaja area of Bida Basin. Thermal maturity is low and little, or no hydrocarbon has been generated from the source rocks.


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