A novel halogen-free flame retardant for glass-fiber-reinforced poly(ethylene terephthalate)

2008 ◽  
Vol 93 (6) ◽  
pp. 1188-1193 ◽  
Author(s):  
Cheng-Shou Zhao ◽  
Fu-Lin Huang ◽  
Wei-Cheng Xiong ◽  
Yu-Zhong Wang
2021 ◽  
Author(s):  
Zhenya Zhang ◽  
Kunpeng Cai ◽  
Yaxin Guo ◽  
Xiaohua Liu ◽  
Suqin He ◽  
...  

Abstract Halogen-free flame retardants are ideal plastic additives that meet carbon neutral requirements. In this work, halogen free flame retardant with glass fiber reinforced PA66/PPO composites were prepared by using coated red phosphorus (FRM-150B) and phosphorus-silicon flame retardant (WR6002). The mechanical properties, heat resistance, friction and wear properties and flame retardancy were carried out to evaluate the performances of composites using as structural parts that require heat resistance, dimensional stability and accuracy. It was found that the friction coefficient and wear volume of the composites were improved with the contents of glass fiber increased, as a result, PA66/PPO composites was obtained with excellent comprehensive performance when the content of compatilizer is 7%, the glass fiber was 30%, the content of FRM is 8% and the phosphorous-silicon flame retardant is 16%. The flame retardant effect of FRM-150B and WR6002 in PA66/PPO was presented in the condensed phase, the results showed that the composite material with 16% WR6002 forms a carbon layer with excellent thermal stability. On the other hand, the mechanical properties of composites were hardly affected, has important prospects in automotive components and household appliances


2011 ◽  
Vol 96 (3) ◽  
pp. 363-370 ◽  
Author(s):  
Yun Liu ◽  
Cheng-Liang Deng ◽  
Jing Zhao ◽  
Jun-Sheng Wang ◽  
Li Chen ◽  
...  

2018 ◽  
Vol 89 (18) ◽  
pp. 3700-3707 ◽  
Author(s):  
Bo Yang ◽  
Yanyun Mao ◽  
Yihui Zhang ◽  
Yi Wei ◽  
Wanshuang Liu ◽  
...  

A series of novel fast-curing halogen-free flame-retardant epoxy resins were formulated and used to prepare glass fiber-reinforced composites. Dynamic mechanical analysis showed that the optimized epoxy system could be completely cured in 0.5 h at 150℃ and had a glass transition temperature ( Tg) of above 130℃. The optimized epoxy system was also used as matrix resin to make glass fiber prepregs and composite panels. The flame-retardant properties of the glass fiber-reinforced composites were investigated, including the limiting oxygen index (LOI) and flaming, smoke and toxicity properties. The glass fiber-reinforced composite had good flame retardancy with a UL-94 V-1 rating and high LOI of ∼36%. More significantly, the composite based on the flame-retardant epoxy resin showed lower smoke density compared with those based on phenolic resins. Finally, the glass fiber prepregs were used to fabricate honeycomb sandwich composites. The peel strength of the epoxy-based composites was almost twice that of the composites based on phenolic resin.


2018 ◽  
Vol 5 (3) ◽  
pp. 9569-9578
Author(s):  
Wiranphat Thodsaratpreeyakul ◽  
Putinun Uawongsuwan ◽  
Akio Kataoka ◽  
Takanori Negoro ◽  
Hiroyuki Inoya ◽  
...  

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