The synergistic effects of boroxo siloxanes with magnesium hydroxide in halogen-free flame retardant EVA/MH blends

2013 ◽  
Vol 98 (4) ◽  
pp. 868-874 ◽  
Author(s):  
Lei Ye ◽  
Yueying Miao ◽  
Hong Yan ◽  
Ze Li ◽  
Yulong Zhou ◽  
...  
2008 ◽  
Vol 47 (6) ◽  
pp. 613-618 ◽  
Author(s):  
Y. Xia ◽  
S. Liu ◽  
X. Wang ◽  
Y. Han ◽  
J. Li ◽  
...  

2011 ◽  
Vol 239-242 ◽  
pp. 1317-1321 ◽  
Author(s):  
Xiao Yan Li ◽  
Xia Wang

By using Bisphenol A bis (diphenyl) phosphate ester (BDP) and a kind of Intumescent Flame Retardant (IFR) as Halogen-free Flame Retarding (HFFR), flame retarded oil-extended hydrogenated styrene-butylenes-styrene (SEBS) were prepared. The samples were systemically characterized by TGA, LOI and FESEM; influence of BDP and IFR for oil-extended SEBS was compared. The results showed that BDP can improve thermal decomposition temperature of SEBS; while the IFR retardant can produce remarkable residual chars to improve SEBS’s decomposition temperature; meanwhile BDP and the IFR retardant can bring synergistic effects in the flame retardancy for the oil-extended SEBS.


Author(s):  
A. Yu. Svatikov ◽  
I. D. Simonov-Emelyanov

Currently, halogen-free cable compositions are becoming increasingly common in the manufacture of cable compositions. The concept of halogen-free or “zero halogen” becomes a symbol of fire resistance, low-smoke characteristics, low toxicity of volatile products of combustion, the absence of the toxic, corrosive and irritating gas - hydrogen chloride - and other hydrogen halides in the volatile products. More and more manufacturers of cable products are beginning to pay increasing attention to the problems of processing, toxicity and fire safety. It should be noted that the requirements for improving the fire safety of cable products are constantly becoming tougher, since the main problem of most of these polymeric materials is their flammability, high smoke generation and high flame spread rate. In this regard, there is a burning question to increase these characteristics and bring them to the level of compounds based on PVC. The main way to increase the flame-retardant characteristics of halogenfree cable compositions is to introduce mineral fire retardants into these compositions. The study of the composition and packaging of these mineral fillers-flame retardants makes it possible to increase the level of flame-retardant characteristics of halogen-free cable compositions. The paper presents the results of studies on the thermal stability of cable compositions based on PE + EVA mixtures containing magnesium hydroxide crystalline hydrate as a filler-flame retardant. It is shown that cable compositions containing magnesium hydroxide crystal hydrate are characterized by higher heat resistance and thermal stability (~ 2-fold) compared to a polymeric matrix based on PE + SEVA. This allows to process them at high temperatures (more than 200°C) by extrusion and pressure casting.


2017 ◽  
Vol 10 (04) ◽  
pp. 1750042 ◽  
Author(s):  
Hao Tang ◽  
Kunfeng Chen ◽  
Xiaonan Li ◽  
Man Ao ◽  
Xinwen Guo ◽  
...  

Halogen-free and environment-friendly magnesium hydroxide (Mg(OH)2) was synthesized to enhance the flame retardant properties of thermoplastic elastomer (TPE). When the Mg(OH)2 content was optimized to 35[Formula: see text]wt.%, the TPE–Mg(OH)2 composites exhibited the best flame retardant properties. The results showed that there was a delay of ignition time of the samples containing Mg(OH)2; compared with the samples without Mg(OH)2, the heat release rate and total heat release decrease by 31.4% and 35.6%, while total smoke production and mass loss rate reduce by 56% and 34.2%, respectively. This work opens a door to manufacture fire-resistant polymer-based composites with environmental-friendly flame retardant additives by controllable crystallization and chemical strategies.


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