nEffects of Temperature and Pressure on Chemical Vapour Deposition in Micro-nano Porous Structure in Char Layer of Polymer Composites

Author(s):  
Hui Kun ◽  
Jiang Li ◽  
Kang Li ◽  
Ning Yan ◽  
Cheng bian ◽  
...  
Author(s):  
K. P. Yung ◽  
J. Wei ◽  
B. K. Tay

In this study, polystyrene was mixed with toluene by ratios of 1 wt%, 2 wt%, and 3 wt% to create polystyrene solutions. CNTs-polymer composites have been fabricated by introducing polymeric material into the CNT film grown by plasma enhanced chemical vapour deposition (PECVD). The nanotubes act as conductive filler to the composite and resulting in increases in surface conductivities. Depending on the concentration of the polystyrene solution, the increases in conductivity varied. It is shown that the surface conductance is lower for CNT-polymer composite with higher concentrated polystyrene solution.


1999 ◽  
Vol 09 (PR8) ◽  
pp. Pr8-395-Pr8-402 ◽  
Author(s):  
B. Armas ◽  
M. de Icaza Herrera ◽  
C. Combescure ◽  
F. Sibieude ◽  
D. Thenegal

1999 ◽  
Vol 09 (PR8) ◽  
pp. Pr8-373-Pr8-380 ◽  
Author(s):  
P. Sourdiaucourt ◽  
A. Derré ◽  
P. Delhaès ◽  
P. David

2020 ◽  
Author(s):  
Polla Rouf ◽  
Pitsiri Sukkaew ◽  
Lars Ojamäe ◽  
Henrik Pedersen

<p>Aluminium nitride (AlN) is a semiconductor with a wide range of applications from light emitting diodes to high frequency transistors. Electronic grade AlN is routinely deposited at 1000 °C by chemical vapour deposition (CVD) using trimethylaluminium (TMA) and NH<sub>3</sub> while low temperature CVD routes to high quality AlN are scarce and suffer from high levels of carbon impurities in the film. We report on an ALD-like CVD approach with time-resolved precursor supply where thermally induced desorption of methyl groups from the AlN surface is enhanced by the addition of an extra pulse, H<sub>2</sub>, N<sub>2</sub> or Ar between the TMA and NH<sub>3</sub> pulses. The enhanced desorption allowed deposition of AlN films with carbon content of 1 at. % at 480 °C. Kinetic- and quantum chemical modelling suggest that the extra pulse between TMA and NH<sub>3</sub> prevents re-adsorption of desorbing methyl groups terminating the AlN surface after the TMA pulse. </p>


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