Fabrication of Anisotropic Polyphosphazene/Bio-based Poly(urethane-acrylate) composite foams with High Thermal Insulation and Flame Retardancy

Polymer ◽  
2021 ◽  
pp. 124108
Author(s):  
Yongtai Guo ◽  
Shengmiao Zhang ◽  
Guiyou Wang ◽  
Yun Zhu
2015 ◽  
Vol 31 (3) ◽  
pp. 189-205 ◽  
Author(s):  
Nuchnapa Tangboriboon ◽  
Wasirin Pannangpetch ◽  
Khomkrit Aranyik ◽  
Karat Petcharoen ◽  
Anuvat Sirivat

2021 ◽  
Vol 8 ◽  
Author(s):  
Xiujuan Li ◽  
Ruisong Guo ◽  
Xiaodong Qian

Under high temperature, aqueous film forming foam extinguishing agent has poor flame retardancy and low fire efficiency. In order to solve this problem, talc was introduced into foam to form composite foam. The fire resistance and fire extinguishing properties of the composite foam were studied. The results showed that talc composite foam had good flame retardant resistance. when the concentration of talc reached 40 g/100 ml, the 50% liquid separation time of the composite foam was 21.1 min. The fuel burning in the anti burning tank did not ignite the gasoline in the oil pan, and burned out at 51.5 min. It was related to the structure of composite foam and the properties of talc. Due to the introduction of talc, the viscosity of the composite foam increased. The network structure of composite foam was important to the improved stability of foam. Talc powder formed a dense layer covering the oil surface, which effectively isolated the oil from the air.


2011 ◽  
Vol 99-100 ◽  
pp. 1117-1120 ◽  
Author(s):  
Mao Quan Xue

As new building materials, plastic has light weigh, corrosion resistance, low thermal conductivity, thermal insulation, waterproof, energy-saving, molding convenient, high recycling characteristic, widely used in building materials. According to the research of improving its flame retardancy, strength, thermal insulation, waterproof properties, the application of plastic use in doors and windows, pipeline, building walls and roofs of buildings, etc. were reviewed, and the developing direction was discussed.


2017 ◽  
Vol 748 ◽  
pp. 51-54
Author(s):  
Pei Bang Dai ◽  
Lin Ying Yang ◽  
Ting Zheng ◽  
Chang Qin ◽  
Qi Chen Tang

A rigid polyurethane (PU) flame retardant composite foam was prepared by the compounding of polyols and diisocyanates with a modified intumescent flame retardant (MIFR). The MIFR was based on the three components of intumescent flame retardant normally used and was modified in a surfactant TX-10 solution. The flame retardancy of the PU flame retardant composite foams were evaluated by using the limiting oxygen index (LOI), the UL-94 (vertical flame) test and scanning electron microscopy (SEM). When MIFR was fixed at 20.0 wt% in PU/MIFR composite foams, the MIFR could enhance the flame retardancy and pass V-0 rating of UL-94 test. The microstructures observed by SEM demonstrate that a suitable amount of MIFR can promote formation of compact intumescent charred layers in PU foams.


2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
MinYi Luo ◽  
Jiayou Xu ◽  
Shu Lv ◽  
XueFeng Yuan ◽  
Xiaolan Liang

Polyvinyl alcohol- (PVA-) based aerogels have attracted widespread attention owing to their low cost, eco-friendliness, and low density. However, the applications of PVA-based aerogels are limited by their flammability. In this study, a flame retardant, ammonium polyphosphate (APP), and a biopolymer, chitosan (CS), were added to polyvinyl alcohol (PVA), and the polymer was further crosslinked using boric acid (H3BO3). In the PVA aerogels, the negatively charged APP and positively charged CS formed a polyelectrolyte complex (PEC) through ionic interaction. Cone calorimetry and vertical burning tests (UL-94) indicated that the PVA composite aerogels have excellent flame retardancy; they could decrease the heat release rate, total heat release rate, and carbon dioxide (CO2) generation. Both PVA/H3BO3 and APP-CS in the composite aerogel could be burned to carbon, and the foamed char layer could act together to impart the PVA composite aerogels with good flame retardancy. Further, the decrease in the temperature at the backside of the aerogels with increasing APP-CS content, as determined by the flame-spraying experiment, indicated that the PVA-based aerogels with APP-CS can also serve as thermal insulation materials. This work provides an effective and promising method for the preparation of PVA-based aerogels with good flame retardancy and thermal insulation property for construction materials.


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