scholarly journals Study on Flame Retardancy and Mechanism of Talc Composite Foams

2021 ◽  
Vol 8 ◽  
Author(s):  
Xiujuan Li ◽  
Ruisong Guo ◽  
Xiaodong Qian

Under high temperature, aqueous film forming foam extinguishing agent has poor flame retardancy and low fire efficiency. In order to solve this problem, talc was introduced into foam to form composite foam. The fire resistance and fire extinguishing properties of the composite foam were studied. The results showed that talc composite foam had good flame retardant resistance. when the concentration of talc reached 40 g/100 ml, the 50% liquid separation time of the composite foam was 21.1 min. The fuel burning in the anti burning tank did not ignite the gasoline in the oil pan, and burned out at 51.5 min. It was related to the structure of composite foam and the properties of talc. Due to the introduction of talc, the viscosity of the composite foam increased. The network structure of composite foam was important to the improved stability of foam. Talc powder formed a dense layer covering the oil surface, which effectively isolated the oil from the air.

2017 ◽  
Vol 748 ◽  
pp. 51-54
Author(s):  
Pei Bang Dai ◽  
Lin Ying Yang ◽  
Ting Zheng ◽  
Chang Qin ◽  
Qi Chen Tang

A rigid polyurethane (PU) flame retardant composite foam was prepared by the compounding of polyols and diisocyanates with a modified intumescent flame retardant (MIFR). The MIFR was based on the three components of intumescent flame retardant normally used and was modified in a surfactant TX-10 solution. The flame retardancy of the PU flame retardant composite foams were evaluated by using the limiting oxygen index (LOI), the UL-94 (vertical flame) test and scanning electron microscopy (SEM). When MIFR was fixed at 20.0 wt% in PU/MIFR composite foams, the MIFR could enhance the flame retardancy and pass V-0 rating of UL-94 test. The microstructures observed by SEM demonstrate that a suitable amount of MIFR can promote formation of compact intumescent charred layers in PU foams.


e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 563-573 ◽  
Author(s):  
Zeyu Xia ◽  
Zhengzhou Wang

AbstractExpanded vermiculite (EV) was introduced into rigid polyurethane (RPU) foam. The incorporation of 10 wt% EV into RPU foam increases the compressive strength and the flexural strength by 82% and by 115%, respectively compared with untreated RPU foam. The LOI of RPU foam containing 20 wt% EV is only 19.5%. To further improve the flame retardancy of RPU/EV composite foam, melamine phenylphosphate (MPP) was synthesized and introduced into the RPU/EV composite foam. The RPU/EV composite foam with 15% MPP (sample RPU/EV/MPP15) has a LOI of 27.5% and a V0 rating in the vertical UL-94 test. The PHRR and THR of sample RPU/EV/MPP15 decrease by 39% and 24%, respectively, compared with the ones of untreated RPU/EV composite foam. The compressive strength and flexural strength of RPU/EV/MPP composite foam gradually decrease with the increase in the amount of MPP. TGA results indicated that the addition of MPP further increase the residue char of the RPU/EV composite foam.


Author(s):  
Soo-yeon Seo ◽  
Jong-wook Lim ◽  
Su-hyun Jeong

AbstractTo figure out the change in the reinforcing effect of FRP system used for the retrofit of RC beam when it is exposed to high temperature, it is required to evaluate not only the behavior of the entire beam, but also the bond performance at anchorage zone through a bond test according to the increase of external temperature. Moreover, the study to find various fire-protection methods is necessary to prevent the epoxy from reaching the critical temperature during an exposure to high temperature. In this manner, the fire-resistance performances of externally bonded (EB) FRP and near-surface-mounted (NSM) FRP to concrete block were evaluated by high-temperature exposure tests after performing a fire-protection on the surface in this paper. Board-type insulation with mortar was considered for the fire-protection of FRP system. After the fire-protection of the FRPs bonded to concrete blocks, an increasing exposure temperature was applied to the specimens with keeping a constant shear bond stress between concrete and the FRP. Based on the result, the temperature when the bond strength of the FRP disappears was evaluated. In addition, a finite element analysis was performed to find a proper method for predicting the temperature variation of the epoxy which is fire-protected with board-type insulation during the increase of external temperature. As a result of the test, despite the same fire-protection, NSM specimens were able to resist 1.54–2.08 times higher temperature than EB specimens. In the design of fire-protection of FRP system with the board-type insulation, it is necessary to consider the transfer from sides as well as the face with FRP. If there is no insulation of FP boards on the sides, the epoxy easily reaches its critical temperature by the heat penetrated to the sides, and increasing the thickness of the FP board alone for the face with FRP does not increase the fire-resistance capacity. As a result of the FE analysis, the temperature variation at epoxy can be predicted using the analytical approach with the proper thermal properties of FP mortar and board.


2013 ◽  
Vol 634-638 ◽  
pp. 3688-3695 ◽  
Author(s):  
Yang Xiao ◽  
Shu Gang Li ◽  
Jun Deng ◽  
Xu Wang

In China, as popularizing the technology of fully mechanized top-coal mining and increasing the strength and depth of mining, the gutter-up gob can be formed. But the work of fire preventing and extinguishing for its coal spontaneous combustion is more complexity and difficulty. In this paper, based on geology parameters and mining practice for 93up12 fully mechanized top-coal caving face in Nantun coalmine, the form and character of gutter-up gob are analyzed. According to the hidden danger of high temperature for spontaneous combustion in the gob, we adopt the comprehension technologies of fire extinguishing and preventing which include sealing air-leakage, grouting, and injecting compound gel with fly-ash, foam of retarding oxidation, liquid carbon dioxide, and gas of nitrogen. By putting in practice the pre-controlling technology in gutter-up gob and monitoring data of target gases, it obtains a good effect and ensures the safety in production of the fully-mechanized top-coal caving face.


2011 ◽  
Vol 393-395 ◽  
pp. 1012-1017 ◽  
Author(s):  
Yu Feng Ma ◽  
Wei Zhang ◽  
Ling Li ◽  
Ming Ming Zhang ◽  
Zeng Hui Cheng ◽  
...  

New composite foams were prepared by co-foaming of Melamine-Urea-Formaldehyde (MUF) resin and wood fiber in the closed mould at 70°C. The effects of amount of wood fiber on mechanical properties, brittleness, flame-retardant, insulation and microscopic structures of wood fiber-MUF foam were investigated. Results indicated that the flame-retardant properties increased, and the brittleness and mechanical properties decreased with the increase of the amount of wood fiber in composite foams. The addition of wood fiber resulted in more uniform cell size distribution and irregular cell shape, but had little effect on insulation properties.


2014 ◽  
Vol 1065-1069 ◽  
pp. 1358-1362
Author(s):  
Jin Sheng Han ◽  
Hao Ran Liu ◽  
Shu Ping Cong

The fire resistance of concrete filled steel tubular column is usually obtained by the numerical analysis method, which is difficult to operate and not convenient in the actual civil engineering. So it is necessary to study the simplified calculation method. A large number of numerical simulation results of the temperature distribution of the section and the bearing capacity at high temperature of the concrete filled steel tubular columns are analyzed. The influences of secondary parameters are simplified. The simplified calculation method at 150 min and 180 min for the bearing capacity at high temperature of concrete filled steel tubular columns subjected to axial compression and fire is presented on the basis of comprehensive analysis of the numerical calculation results. The calculation results can be used as the basis to judge the fire resistance. It is shown by the comparison with the experimental results that the precision of the simplified calculation method can meet the requirements of engineering application.


Author(s):  
NurFadhlin Sakina Jamil ◽  
◽  
Mazatusziha Ahmad ◽  
Ahmad Hakiim Jamaluddin ◽  
◽  
...  

Biodegradable foam packaging was chosen as an alternative food packaging material due to non-toxic and produced from renewable sources. Researchers has turned to incorporate natural fibre to enhance the mechanical properties of polymer composite foam. In this study, the objective is to identify the studies which investigated on the tensile properties of natural fiber incorporated polymer composite foam and analyzed the effect of natural fibre content and size on tensile properties. Further correlation between the natural fibre content and size on tensile properties of composite polymer foam was conducted. The studies on the natural fibre incorporated polymer composite was identify via PRISMA method. The effect of natural fibre content and natural fibre size on tensile properties of polymer composite foam were analyzed in terms of qualitative analysis via systematic review. This study employs systematic review method on the existing literature. This study has utilized supplementary databases such as SAGE Journals, ScienceDirect, Taylor & Francis, Emerald Insight, ERIC ProQuest, SpringerLink and IEEE Xplore to cater all the possible relevant literature for a comprehensive review. The systematic review method comprised of the steps that explain on the review process in the sequence of the (identification, screening, eligibility), data analysis and data abstraction. From the article used in this systematic review, most of the result shown the increased tensile properties on natural fibre reinforced polymer composite foams. The study by Texteira et al. (2014) shows that the softwood fibre with 33% of PLA loading has the highest elongation at break, and highest natural fibre size (2470 µm). While the study by Long et al. (2019) has the highest tensile strength with 30% of ABF fibre content. The composition of 20 wt% BF with 80 wt% PLA composites were concluded to have the optimum tensile properties


2019 ◽  
Vol 206 ◽  
pp. 6-11 ◽  
Author(s):  
Jong Chan Lee ◽  
Jeongho Min ◽  
P. Justin Jesuraj ◽  
Hassan Hafeez ◽  
Dong Hyun Kim ◽  
...  

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