Amorphous fraction controlled mechanical and optical properties of polylactic acid below glass transition temperature

2020 ◽  
Vol 91 ◽  
pp. 106731
Author(s):  
Tsung-Han Yu ◽  
Yu-Hsun Su ◽  
Hsuan-Hao Huang ◽  
Hsin-Jung Tsai ◽  
Wen-Kuang Hsu
2013 ◽  
Vol 594-595 ◽  
pp. 823-827
Author(s):  
Luqman Hakim Ahmad Subri ◽  
Sakinah Mohd Alauddin ◽  
Senawi Rosman

Biocomposites demands are significantly rising due to environmental regulations and concerns. However, incompatibility between the fibre and matrix is a major setback that diminishes the biocompostie properties. Therefore in this work, methylene diphenyl diisocynate (MDI) compatibilizers were used together with fibre surface treatment in order to increase compatibility between polylactic acid (PLA) and Elaeis Guineensis Fibres (EGF) biocomposite. Nonisothermal properties were investigated and it was found that, MDI increased compatibility of the PLA and EGF which led to the restriction of chain movements in the biocomposite. This restriction in chain mobility caused an increase the glass transition temperature and crystallization temperature and also reduced the degree of crystallinity.


2013 ◽  
Vol 130 (2) ◽  
pp. 1148-1157 ◽  
Author(s):  
Marion Dasriaux ◽  
Sylvie Castagnet ◽  
Ludovic Thilly ◽  
Laurence Chocinski-Arnault ◽  
Séverine A. E. Boyer

Molecules ◽  
2019 ◽  
Vol 24 (11) ◽  
pp. 2104
Author(s):  
Renyu Yang ◽  
Dongyue Wang ◽  
Hongli Li ◽  
Yi He ◽  
Xiangyu Zheng ◽  
...  

Polylactic acid (PLA) is limited in its application due to its high price, high brittleness and low glass-transition temperature. Modification methods are currently used to overcome these shortcomings. In this study, Bletilla striata polysaccharide (BSP) was blended with PLA by a solvent method. DMA data showed that the BSP/PLA film had a higher glass-transition temperature, and the glass-transition temperature of the film showed an extreme value of 68 °C when the proportion of the chalk polysaccharide was 0.8%. TG data indicates that the composite film material has good thermal stability. Tensile tests show that the composite film is improved in rigidity and elasticity compared to the pure PLA film. The blending modification of PLA with white peony polysaccharide not only reduces the cost of PLA, but also improves the thermal and mechanical properties of PLA.


Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2091
Author(s):  
Mohamed Saeed Barkhad ◽  
Basim Abu-Jdayil ◽  
Abdel Hamid I. Mourad ◽  
Muhammad Z. Iqbal

This work aims to provide an extensive evaluation on the use of polylactic acid (PLA) as a green, biodegradable thermal insulation material. The PLA was processed by melt extrusion followed by compression molding and then subjected to different annealing conditions. Afterwards, the thermal insulation properties and structural capacity of the PLA were characterized. Increasing the annealing time of PLA in the range of 0–24 h led to a considerable increase in the degree of crystallization, which had a direct impact on the thermal conductivity, density, and glass transition temperature. The thermal conductivity of PLA increased from 0.0643 W/(m·K) for quickly-cooled samples to 0.0904 W/(m·K) for the samples annealed for 24 h, while the glass transition temperature increased by approximately 11.33% to reach 59.0 °C. Moreover, the annealing process substantially improved the compressive strength and rigidity of the PLA and reduced its ductility. The results revealed that annealing PLA for 1–3 h at 90 °C produces an optimum thermal insulation material. The low thermal conductivity (0.0798–0.0865 W/(m·K)), low density (~1233 kg/m3), very low water retention (<0.19%) and high compressive strength (97.2–98.7 MPa) in this annealing time range are very promising to introduce PLA as a green insulation material.


2013 ◽  
Vol 749 ◽  
pp. 255-259 ◽  
Author(s):  
Yu Xing Cheng ◽  
Gui Sheng Xu ◽  
Jian Ding Yu ◽  
Xiu Hong Pan ◽  
Ming Hui Zhang ◽  
...  

Bulk glasses of xNb2O5(1-x)La2O3(NL) with high refractive index were prepared by aerodynamic levitation method. Only when x ranges from 0.62 to 0.72, NL glasses can be obtained. The effect of compositions on the thermal property and refractive index was investigated. The results indicated that the glass transition temperature ranged from 733 to 767 with the increasing of La2O3in NL glasses, while the crystallization peak ranged from 811 to 837 . The glasses had high refractive index ranging from 2.26 to 2.31. According to the Drude-Voigt relationship, the Abbe number of the glasses was calculated to be about 20. This type of glass was colorless and transparent in the region from visible to infrared region. Thus, the niobate glass system has promising application in lenses, next-generation optical disk, and endoscopes.


2016 ◽  
Vol 18 (15) ◽  
pp. 4170-4175 ◽  
Author(s):  
Pengxu Qi ◽  
Hsiao-Li Chen ◽  
Ha Thi Hoang Nguyen ◽  
Chu-Chieh Lin ◽  
Stephen A. Miller

Polylactam esters are readily made from biobased itaconic acid and are compared to polylactic acid. The lactam ring improves the glass transition temperature and the main-chain ester groups are more readily hydrolyzed, degrading fully via agitation in water for one year.


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