scholarly journals Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina

Author(s):  
Happiness Imuetiyan ◽  
Augustine Agi ◽  
Afeez Gbadamosi ◽  
Radzuan Junin ◽  
Jeffrey Oseh
2021 ◽  
Author(s):  
Xu-Guang Song ◽  
Ming-Wei Zhao ◽  
Cai-Li Dai ◽  
Xin-Ke Wang ◽  
Wen-Jiao Lv

AbstractThe ultra-low permeability reservoir is regarded as an important energy source for oil and gas resource development and is attracting more and more attention. In this work, the active silica nanofluids were prepared by modified active silica nanoparticles and surfactant BSSB-12. The dispersion stability tests showed that the hydraulic radius of nanofluids was 58.59 nm and the zeta potential was − 48.39 mV. The active nanofluids can simultaneously regulate liquid–liquid interface and solid–liquid interface. The nanofluids can reduce the oil/water interfacial tension (IFT) from 23.5 to 6.7 mN/m, and the oil/water/solid contact angle was altered from 42° to 145°. The spontaneous imbibition tests showed that the oil recovery of 0.1 wt% active nanofluids was 20.5% and 8.5% higher than that of 3 wt% NaCl solution and 0.1 wt% BSSB-12 solution. Finally, the effects of nanofluids on dynamic contact angle, dynamic interfacial tension and moduli were studied from the adsorption behavior of nanofluids at solid–liquid and liquid–liquid interface. The oil detaching and transporting are completed by synergistic effect of wettability alteration and interfacial tension reduction. The findings of this study can help in better understanding of active nanofluids for EOR in ultra-low permeability reservoirs.


2018 ◽  
Vol 1 (1) ◽  

After primary and secondary oil production from carbonate reservoirs, approximately 60% oil-in-place remains in the pore space of reservoir rocks. Chemical flooding is one of the promising ways to produce the remained oil. Nowadays, surfactant flooding is a low-cost and a common method generally used to improve oil recovery due to the oil-water Interfacial Tension (IFT) reduction and alteration of the rock wettability to water-wet state, leading to decrease the capillary number. In this study, a novel leaf-derived non-ionic natural surfactant, named Eucalyptus is introduced and the capability of this natural surfactant for IFT reduction and wettability alteration is analyzed. Accordingly, the natural surfactant was derived from Eucalyptus leaves and the effect of natural surfactant solution on the Oil-water IFT and carbonate rock wettability alteration was investigated. The results demonstrated that the addressed natural surfactant significantly reduced IFT value from 35.2 mN/m to 10.5 mN/m (at CMC of 3.5 wt. %) and the contact angle value from 140.6° to 60.2°. As a result, Compared to conventional chemical surfactants, the Eucalyptus natural surfactant had an excellent surface chemical activity and confirmed its performance by laboratory experiments which could be used for EOR applications.


Crystals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 626
Author(s):  
Nurul Afiqah Mohd Mokhtar ◽  
Hoe Guan Beh ◽  
Kean Chuan Lee

Recently, a non-invasive method of injecting magnetic/dielectric nanofluids into the oil reservoir was used for oil recovery application. The use of magnetic nanofluids in Enhanced Oil Recovery (EOR) has been reported to improve oil recovery. It is believed that the magnetic properties of nanoparticles (NPs) have a direct influence on the viscosity and wettability of nanofluid, and on oil-water interfacial tension (IFT). Thus, Mn0.5Zn0.5Fe2O4 (MnZn) ferrites may be a good candidate to be used in nanofluids for wettability alteration and oil-water IFT reduction due to their excellent magnetic properties, such as a high initial permeability and low magnetic losses. Therefore, this work investigated the potential of MnZn ferrite NPs to alter viscosity, wettability, and oil-water IFT. MnZn Ferrite NPs have been synthesized by a sol-gel auto-combustion process. The effects of calcination temperature varying from 300 °C to 700 °C on the phase formation, microstructures such as surface morphology, and magnetic characterizations were studied. MnZn ferrite nanofluids were prepared using synthesized MnZn NPs that dispersed into brine along with sodium dodecylbenzenesulfonate (SDBS) as a dispersant, and their effects on the wettability and oil-water IFT were studied. X-ray diffraction (XRD) measurements revealed that MnZn ferrite calcined at 300 °C and 400 °C were single phase. The average crystallite size calculated through Scherrer’s equation differed from 32.0 to 87.96 nm. The results showed that the nanofluid with MnZn particles calcined at 300 °C is the best nanofluid in terms of IFT reduction and base nanofluid’s wettability alteration. Moreover, the overall results proved that nanofluid with MnZn ferrite NPs can alter the wettability of base nanofluid, oil-nanofluid IFT, and nanofluid viscosity. This study provides insights towards a better understanding of the potential application of MnZn Ferrite nanofluids to Wettability Alteration and IFT Reduction in Enhanced Oil Recovery.


e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 317-327
Author(s):  
Chenliang Shi ◽  
Ling Lin ◽  
Yukun Yang ◽  
Wenjia Luo ◽  
Maoqing Deng ◽  
...  

AbstractThe influence of density of amino groups, nanoparticles dimension and pH on the interaction between end-functionalized polymers and nanoparticles was extensively investigated in this study. PS–NH2 and H2N–PS–NH2 were prepared using reversible addition–fragmentation chain transfer polymerization and atom transfer radical polymerization. Zero-dimensional carbon dots with sulfonate groups, one-dimensional cellulose nanocrystals with sulfate groups and two-dimensional graphene with sulfonate groups in the aqueous phase were added into the toluene phase containing the aminated PS. The results indicate that aminated PS exhibited the strongest interfacial activity after compounding with sulfonated nanoparticles at a pH of 3. PS ended with two amino groups performed better in reducing the water/toluene interfacial tension than PS ended with only one amino group. The dimension of sulfonated nanoparticles also contributed significantly to the reduction in the water/toluene interfacial tension. The minimal interfacial tension was 4.49 mN/m after compounding PS–NH2 with sulfonated zero-dimensional carbon dots.


2015 ◽  
Vol 93 (8) ◽  
pp. 1410-1415 ◽  
Author(s):  
Zhan Weng ◽  
Peng-Yuan Zhang ◽  
Guang-Wen Chu ◽  
Wei Wang ◽  
Jimmy Yun ◽  
...  

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