scholarly journals A DFT study on the adsorption of Ga-BNNT to SF6 decomposition products under partial discharge

2019 ◽  
Vol 14 ◽  
pp. 102419 ◽  
Author(s):  
Hai Qian ◽  
Jun Deng ◽  
Haibin Zhou ◽  
Xu Yang ◽  
Wei Chen
Author(s):  
Visa Musa Ibrahim

A solid analytic procedure of Gas insulated switchgear condition checking is utilized in this studies as a part of exploration for the detection of sulphur hexafluoride gas (SF6) decomposition by-product because of its high affectability, reliability and anti-electromagnetic obstruction. This is known as chemical decomposition by-product method. A simulated coaxial deterioration chamber was designed and used on the high voltage electrode to re-enact the decomposition of SF6 under the impact of protrusion defect that generates partial discharge in the coaxial chamber at a pressure of 0.2MPa.The chamber is energised at 50kv for the period of 50 hours and the generated partial discharge simulate the decomposition of SF6 gas. The deterioration decomposition products SO2, SOF2, SO2F2, SO2F10, SiF4, CO, C3F8, C2F6 were detected offline by FTIR spectrometer. These deteriorated items and its concentration can be utilized to recognize and distinguish the type and the magnitude of fault in gas insulated switchgear (protrusion fault) before failure occur for the aim of preventive maintenance.


High Voltage ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 454-462 ◽  
Author(s):  
Yingang Gui ◽  
Jinzhi Shi ◽  
Pingan Yang ◽  
Tao Li ◽  
Chao Tang ◽  
...  

2014 ◽  
Vol 21 (1) ◽  
pp. 105-115 ◽  
Author(s):  
Ju Tang ◽  
Fuping Zeng ◽  
Xiaoxing Zhang ◽  
Jianyu Pan ◽  
Yinjun Qiu ◽  
...  

2018 ◽  
Vol 8 (10) ◽  
pp. 2010 ◽  
Author(s):  
Yongqian Wu ◽  
Shaojian Song ◽  
Dachang Chen ◽  
Xiaoxing Zhang

Based on the first-principles of density functional theory, the SF6 decomposition products including single molecule (SO2F2, SOF2, SO2), double homogenous molecules (2SO2F2, 2SOF2, 2SO2) and double hetero molecules (SO2 and SOF2, SO2 and SO2F2, SOF2 and SO2F2) adsorbed on Pt doped graphene were discussed. The adsorption parameters, electron transfer, electronic properties and energy gap was investigated. The adsorption of SO2, SOF2 and SO2F2 on the surface of Pt-doped graphene was a strong chemisorption process. The intensity of chemical interactions between the molecule and the Pt-graphene for the above three molecules was SO2F2 > SOF2 > SO2. The change of energy gap was also studied and according to the value of energy gap, the conductivity of Pt-graphene before and after adsorbing different gas molecules can be evaluated.


Polymers ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 3507
Author(s):  
Zhen Shi ◽  
Sheng-Yuan Xia

The scavenging and detection of sulfur hexafluoride (SF6) decomposition products (SO2, H2S, SO2F2, SOF2) critically matters to the stable and safe operation of gas-insulated switchgear (GIS) equipment. In this paper, the Rh-doped nitrogen vacancy boron nitride monolayer (Rh-VNBN) is proposed as a gas scavenger and sensor for the above products. The computational processes are applied to investigate the configurations, adsorption and sensing processes, and electronic properties in the gas/Rh-VNBN systems based on the first-principle calculations. The binding energy (Eb) of the Rh-VNBN reaches −8.437 eV, while the adsorption energy (Ead) and band gap (BG) indicate that Rh-VNBN exhibits outstanding adsorption and sensing capabilities. The density of state (DOS) analysis further explains the mechanisms of adsorption and sensing, demonstrating the potential use of Rh-VNBN in sensors and scavengers of SF6 decomposition products. This study is meaningful as it explores new gas scavengers and sensors of SF6 decomposition products to allow the operational status assessment of GIS equipment.


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