Accurate quantitative detection for trace gas has long been the center of failure diagnosis for gas-insulated equipment. An absorption spectroscopy-based detection system was developed for trace SF6 decomposition SO2 detection in this paper. In order to reduce interference from other decomposition, ultraviolet spectrum of SO2 was selected for detection. Firstly, an excimer lamp was developed in this paper as the excitation of the absorption spectroscopy compared with regular light sources with electrodes, such as electrodeless lamps that are more suitable for long-term monitoring. Then, based on the developed excimer lamp, a detection system for trace SO2 was established. Next, a proper absorption peak was selected by calculating spectral derivative for further analysis. Experimental results indicated that good linearity existed between the absorbance and concentration of SO2 at the chosen absorption peak. Moreover, the detection limit of the proposed detection system could reach the level of 10−7. The results of this paper could serve as a guide for the application of excimer lamp in online monitoring for SF6-insulated equipment.
Purpose
This paper aims to establish a photoacoustic detection system for SO2 using UV-LED and testify its feasibility for sensitive measurement. The work in this paper can avoid potential crossover interference in infrared (IR) range and also balance the capability and cost of feasible excitation for photoacoustic detection system.
Design/methodology/approach
In this experimental work, a cantilever-enhanced–based photoacoustic SO2 detection system using an ultraviolet (UV) LED light source with a light power of 4 mW as the excitation was established.
Findings
A feasible photoacoustic detection system for SO2 using UV-LED was established. Experimental results demonstrate that the detection limit of the system can reach the level of 0.667 ppm, which can serve as a reference for the application of PAS in insulation fault diagnosis.
Originality/value
This work investigated the potential of using ultraviolet photoacoustic spectroscopy to detect trace SO2, which provided an ideal replacement of infrared-laser-based detection system. In this paper, a photoacoustic detection system using LED with a low light power was established. Low light power requirement can expand the options of light sources accordingly. In this paper, the absorption characteristics of SO2 in the presented detection system and ultraviolet range were studied. And the detection limit of the presented system was given. Both of which can provide reference to SO2 detection in ambient SF6.
The scavenging and detection of sulfur hexafluoride (SF6) decomposition products (SO2, H2S, SO2F2, SOF2) critically matters to the stable and safe operation of gas-insulated switchgear (GIS) equipment. In this paper, the Rh-doped nitrogen vacancy boron nitride monolayer (Rh-VNBN) is proposed as a gas scavenger and sensor for the above products. The computational processes are applied to investigate the configurations, adsorption and sensing processes, and electronic properties in the gas/Rh-VNBN systems based on the first-principle calculations. The binding energy (Eb) of the Rh-VNBN reaches −8.437 eV, while the adsorption energy (Ead) and band gap (BG) indicate that Rh-VNBN exhibits outstanding adsorption and sensing capabilities. The density of state (DOS) analysis further explains the mechanisms of adsorption and sensing, demonstrating the potential use of Rh-VNBN in sensors and scavengers of SF6 decomposition products. This study is meaningful as it explores new gas scavengers and sensors of SF6 decomposition products to allow the operational status assessment of GIS equipment.
Application of Excimer Lamp in Quantitative Detection of SF6 Decomposition Component SO2