Characterization of the Gacka River basin karst aquifer (Croatia): Hydrochemistry, stable isotopes and tritium-based mean residence times

2014 ◽  
Vol 487 ◽  
pp. 245-254 ◽  
Author(s):  
Nur N. Ozyurt ◽  
Hans O. Lutz ◽  
Tamara Hunjak ◽  
Diana Mance ◽  
Zvjezdana Roller-Lutz
2014 ◽  
Vol 18 (6) ◽  
pp. 2415-2431 ◽  
Author(s):  
S. Tekleab ◽  
J. Wenninger ◽  
S. Uhlenbrook

Abstract. Measurements of the stable isotopes oxygen-18 (18O) and deuterium (2H) were carried out in two meso-scale catchments, Chemoga (358 km2) and Jedeb (296 km2) south of Lake Tana, Abay/Upper Blue Nile basin, Ethiopia. The region is of paramount importance for the water resources in the Nile basin, as more than 70% of total Nile water flow originates from the Ethiopian highlands. Stable isotope compositions in precipitation, spring water and streamflow were analysed (i) to characterise the spatial and temporal variations of water fluxes; (ii) to estimate the mean residence time of water using a sine wave regression approach; and (iii) to identify runoff components using classical two-component hydrograph separations on a seasonal timescale. The results show that the isotopic composition of precipitation exhibits marked seasonal variations, which suggests different sources of moisture generation for the rainfall in the study area. The Atlantic–Indian Ocean, Congo basin, Upper White Nile and the Sudd swamps are the potential moisture source areas during the main rainy (summer) season, while the Indian–Arabian and Mediterranean Sea moisture source areas during little rain (spring) and dry (winter) seasons. The spatial variation in the isotopic composition is influenced by the amount effect as depicted by moderate coefficients of determination on a monthly timescale (R2 varies from 0.38 to 0.68) and weak regression coefficients (R2 varies from 0.18 to 0.58) for the altitude and temperature effects. A mean altitude effect accounting for −0.12‰/100 m for 18O and −0.58‰/100 m for 2H was discernible in precipitation isotope composition. Results from the hydrograph separation on a seasonal timescale indicate the dominance of event water, with an average of 71 and 64% of the total runoff during the wet season in the Chemoga and Jedeb catchments, respectively. Moreover, the stable isotope compositions of streamflow samples were damped compared to the input function of precipitation for both catchments. This damping was used to estimate mean residence times of stream water of 4.1 and 6.0 months at the Chemoga and Jedeb catchment outlets, respectively. Short mean residence times and high fractions of event water components recommend catchment management measures aiming at reduction of overland flow/soil erosion and increasing of soil water retention and recharge to enable sustainable development in these agriculturally dominated catchments.


Water ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 537
Author(s):  
Paúl Carrión-Mero ◽  
F. Javier Montalván ◽  
Fernando Morante-Carballo ◽  
Javier Heredia ◽  
F. Javier Elorza ◽  
...  

Coastal aquifers are strategic and fundamental in the development of touristic areas. The coastal aquifer within the Manglaralto River Basin in Ecuador is essential, as it is the only source of water supply for a large part of the northern part of the Santa Elena province. It is a semi-arid region where high volumes of water are pumped from the aquifer, causing a significant drawdown of groundwater levels, thus affecting the water quality. This work aims to characterize the characteristics of groundwater in the coastal aquifer using hydrochemistry and stable isotopes to propose a hydrogeological conceptual model. The methodology for determining the chemical and isotopic characteristics of groundwater follows the following scheme: (i) studies of ionic concentrations using the Piper diagram, (ii) assessment of the origin of salinity through the Cl/Br ratio, the presence of seawater intrusion through the Hydrochemical Facies Evolution Diagram HFE-D, (iii) characterization of precipitation events using stable isotopes (18O and 2H), and, (iv) development of a hydrogeological conceptual model of the study area. The results indicate that in the basin there are mixing processes of the existing water in the aquifer with recharge water, direct cation exchange processes in the freshening process during recharge, and evaporation in the unsaturated zone. A conceptual model of the flow system in the basin is built, based on the mentioned processes. The main conclusions are: seawater intrusion is present in the areas of the wells located closest to the coast, urban activity through septic tanks is affecting the quality of the aquifer, and rainfall is highly relevant in the different hydrochemical and isotopic processes that operate in the basin.


Water ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1360 ◽  
Author(s):  
Cervi ◽  
Dadomo ◽  
Martinelli

This study discusses a dataset of water stable isotopes from precipitation (4 rain gauges) and surficial water (9 rivers) from the northern Italian Apennines, an area in which clay-rich bedrocks widely outcrop and the runoff response to precipitation events is very rapid. The dataset has been compiled starting from existing data that had previously been published in the literature and consists of monthly values of stable isotopes oxygen-18 (18O) and deuterium (2H) lasting over the period from January 2003 to December 2006 (precipitation) and from January 2006 to December 2007 (surficial water). For this period, mean residence times estimated by means of a sine-wave fitting technique make evident the significant differences over time spent by water molecules within the 9 catchments. Moreover, isotopic compositions of rivers deviated from those of precipitations revealing the influence of some catchment characteristics in differentiating the isotopic composition in rivers. Further correlations between mean residence times of river water and selected catchment characteristics reveal the role of orography and bedrocks in delaying the water molecules during their flow-paths. In addition, time series and cross–correlation analyses indicate a certain control by the main watershed divide on the isotopic composition of river waters, which is reflected in a progressive isotopic variation with longitude. The study shows that, despite using a short-time dataset (2-years for surficial water) of sparse stable isotopes can provide remarkable indications for depicting hydrological processes in large catchments made up of clay-rich bedrocks.


1999 ◽  
Vol 237-238 ◽  
pp. 15-30 ◽  
Author(s):  
P. Schlosser ◽  
R. Bayer ◽  
G. Bönisch ◽  
L.W. Cooper ◽  
B. Ekwurzel ◽  
...  

2014 ◽  
Vol 32 (4) ◽  
pp. 637
Author(s):  
Olivar Antônio Lima de Lima

ABSTRACT. The Salitre River basin, which is located in the semi-arid land of northeastern Brazil, is annually faced with severe surface-water scarcity. Twomain aquifersystems, which are distributed in depth, can be exploited to supply the water needs of the population and its present agro-industrial development: (i) a fractured-karst,water-table component, totally developed within the upper carbonate sequence of the Salitre Formation; and (ii) a fractured-clastic, semi-confined component, mostlikely associating lower Salitre limestones with the meta-sandstones of the Morro do Chap´eu Formation. Geophysical efforts have been useful in developing a regional,three-dimensional characterization of these two aquifer components of the Salitre river aquifer system and in detailing a useful electric tomographic scheme to implementtheir exploration. The geophysical survey, which comprised 64 Schlumberger electrical soundings of resistivity and five tomographic sections, was combined with welldata to define the geometric and hydraulic characteristics of these aquifer components. The inversion of the resistivity data, under the control of the well data, was usefulto reduce electrical ambiguities and to better define the depth of the water table and that of the thick, impervious aquifer substrate. The lateral and depth boundaries of thefracture-karst aquifer zones were outlined, allowing the estimation of a total reserve of approximately 100 billion m3 of groundwater. Chemical analysis of water samplescollected at production wells was used to define a water quality zoning within the basin. These results are very important to define an optimum exploration regime for thegroundwater available in the basin.Keywords: electrical sounding, tomographic section, Salitre aquifer system. RESUMO. A bacia hidrogáafica do rio Salitre faz parte da região semiárida da Bahia e, por isso, apresenta severa escassez de água superficial. Dois principais componentes aquíferos, distribuídos em profundidade, podem ser explorados para suprir as necessidades hídricas da população humana e de seu incipiente desenvolvimento agroindustrial: (i) um componente cárstico-fraturado, de natureza livre, desenvolvido nas rochas carbonáticas superiores da Formação Salitre; e (ii) um componentefraturado, semi-confinado, combinando rocha basais da sequência Salitre e unidades meta-quartzíticas da Formação Morro do Chapéu. Foram executadas 64 sondagens elétricas verticais usando o arranjo Schlumberger de eletrodos, centradas em pontos selecionados da bacia, e cinco seções tomográficas de resistividade, para detalhara estrutura subsuperficial de locais selecionados. A inversão dos dados de resistividade aparente, com controle de informações de poços, foi útil para reduzir ambiguidades elétricas e melhor definir as profundidades do nível estático e do topo do espesso substrato impermeável do sistema aquífero Salitre. Esses estudos permitiramavaliar, regionalmente, os recursos hídricos subterrâneos da bacia, em termos de geometria e características hidráulicas, bem como propor um procedimento para efetuar tomografia elétrica bidimensional, visando sua efetiva exploração por meio de poços. Os limites laterais e em profundidade das zonas de maior carstificação e de densos fraturamentos foram delineados, possibilitando estimar uma reserva total de água no sistema do rio Salitre em cerca de 220 bilhões de m3. Análises físico-químicas deamostras de água coletadas em poços foram usadas para caracterizar a variabilidade na qualidade da água subterrânea na bacia. Tais resultados podem ser usados paraplanejar um regime de exploração eficiente e conservativo das reservas de água subterrânea disponíveis.Palavras-chave: sondagem elétrica, seção tomográfica, sistema aquífero Salitre.


Data in Brief ◽  
2020 ◽  
Vol 30 ◽  
pp. 105491 ◽  
Author(s):  
Hariri Arifin ◽  
John Kayode ◽  
Khairul Arifin ◽  
Zuhar Zahir ◽  
Manan Abdullah ◽  
...  

2016 ◽  
Vol 46 (3) ◽  
pp. 271-284 ◽  
Author(s):  
Guillem Mateu-Vicens ◽  
Teresa Sebastián ◽  
Anna Khokhlova ◽  
Maria del Mar Leza ◽  
Salud Deudero

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