Co-hydrothermal carbonization of swine manure and cellulose: Influence of mutual interaction of intermediates on properties of the products

Author(s):  
Qingyin Li ◽  
Haisheng Lin ◽  
Shu Zhang ◽  
Xiangzhou Yuan ◽  
Mortaza Gholizadeh ◽  
...  
2019 ◽  
Vol 3 (9) ◽  
pp. 2329-2336 ◽  
Author(s):  
Qianqian Lang ◽  
Hainan Luo ◽  
Yi Li ◽  
Dong Li ◽  
Zhengang Liu ◽  
...  

Process water recirculation during co-HTC of swine manure and sawdust changed the combustion behavior of hydrochar.


2019 ◽  
Vol 233 ◽  
pp. 440-446 ◽  
Author(s):  
Qianqian Lang ◽  
Bo Zhang ◽  
Zhengang Liu ◽  
Wentao Jiao ◽  
Yu Xia ◽  
...  

Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 560
Author(s):  
Zac Lentz ◽  
Praveen Kolar ◽  
John J. Classen

There is a significant interest in valorizing swine manure that is produced in enormous quantities. Therefore, considering the high moisture content in swine manure, the objective of this research was to convert manure slurry into hydrochars via hydrothermal carbonization and analyze the yields, pH, energy contents, and thermal and oxidation kinetic parameters. Experiments were performed in triplicate in 250 mL kettle reactors lined with polypropylene at 180 °C, 200 °C, 240 °C, 220 °C, and 260 °C for 24 h. Analyses of the results indicated that the process temperature affected the hydrochar yields, with yield generally decreasing with increasing temperature, but it had little effect on the composition of the hydrochar. The hydrochars were found to have higher volatile contents and H/C and O/C ratios and about 85% of the energy compared to coal. However, the presence of high fraction (35–38%) of ash in hydrochars is a serious concern and needs to be addressed before the complete utilization of hydrochars as fuels. The surface characterization of hydrochars coupled with wet chemistry experiments indicated that hydrochars were equipped with nitrogen functional groups with points of zero charges between 6.76 and 7.85, making them suitable as adsorbents and soil remediation agents and energy storage devices.


2017 ◽  
Vol 60 (3) ◽  
pp. 591-600 ◽  
Author(s):  
Zachary A Lentz ◽  
John Classen ◽  
Praveen Kolar

Abstract. The growth of North Carolina’s swine industry in recent decades has led to a subsequent increase in the production of swine manure. This manure represents a potential threat to environmental and human health, as well as an opportunity to add value to pork production. Technologies for treating swine manure safely while generating products to offset costs are part of an expanding field of research centered on sustainable food production for our growing population. Thermochemical conversion processes use heat to degrade organic feedstocks and drive chemical reactions, which generate valuable products. The high moisture content of swine manure is prohibitive for most thermochemical processes, but gasification and hydrothermal carbonization may be more accommodating. Gasification, a time-tested thermochemical conversion process, yields a combustible gas through a series of endothermic reactions, and hydrothermal carbonization yields a solid, coal-like char that can be used as a fuel or chemical precursor. Advances in thermochemical conversion processes have indicated the potential for yielding valuable products from swine manure, but viable scalable processes are still under development, requiring further research to apply these processes to swine manure management and evaluate the usefulness of their products. This review (1) describes, generally, thermochemical conversion via both hydrothermal gasification (HTG) and hydrothermal carbonization (HTC), (2) shows the usefulness of each conversion process for biomass, and (3) discusses the potential of HTG and HTC of swine manure to enhance the value of pork production. Keywords: Energy, Gases, Hydrothermal carbonization, Hydrothermal gasification, Pig manure, Pigs, Sustainable.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4114
Author(s):  
Jiangbo Xiong ◽  
Shuaiwei Chen ◽  
Jiaxin Wang ◽  
Yujie Wang ◽  
Xiaolin Fang ◽  
...  

Hydrothermal carbonization (HTC) has been proved to be a promising technology for swine manure (SM) treatment. Currently, there is a lack of systematic understanding of the transformation characteristics of nutrient speciation in the HTC of SM. In this study, the speciation of the main nutrients (N/P/K) in SM-derived hydrochar produced at different reaction temperatures (200–280 °C) was investigated. The recovery of P (61.0–67.1%) in hydrochars was significantly higher than that of N (23.0–39.8%) and K (25.5–30.0%), and the increase in reaction temperature promoted the recovery of P and reduced the recovery of N. After the HTC treatment, the percentage of soluble/available P was reduced from 61.6% in raw SM to 4.0–23.9% in hydrochars, while that of moderately labile/slow-release P was improved from 29.2% in raw SM feedstock to 65.5–82.7%. An obvious reduction was also found in the amounts of available N (from 51.3% in raw SM feedstock to 33.0–40.5% in hydrochars). The percentages of slow-release N and residual N in hydrochars produced at 240 °C reached the maximum and minimum values (46.4% and 18.9%), respectively. A total of 49.5–58.3% of K retained in hydrochars was residual (invalid) potassium. From the perspective of the mobility and availability of N, P and K only, it was suggested that the HTC of SM should be carried out at 220–240 °C. Compared with the original SM, it is safer and more effective to use the SM-derived hydrochar as an organic fertilizer.


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