Inclusion of mother liquor inside KDP crystals in a continuous MSMPR crystallizer

The paper presents a simple model of recrystallization with countercurrent flows of the solution and the crystals being purified. The model assumes steady-state operating conditions, an equilibrium between the outlet streams of each stage, and the same equilibrium temperature and distribution coefficient for all stages. With these assumptions, the model provides the basis for analyzing the variation in the degree of purity as a function of the number of recrystallization stages. The analysis is facilitated by the use of a diagram constructed for the limiting case of perfect removal of the mother liquor from the crystals between the stages.

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Identification of novel erythromycin derivatives in mother liquor concentrates of Streptomyces erythraeus.

The Journal of Antibiotics ◽

10.7164/antibiotics.40.1 ◽

1987 ◽

Vol 40 (1) ◽

pp. 1-6 ◽

Cited By ~ 10

Author(s):

ISAAC O. KIBWAGE ◽

GERARD JANSSEN ◽

ROGER BUSSON ◽

Jos HOOGMARTENS ◽

HUBERT VANDERHAEGHE ◽

...

Keyword(s):

Mother Liquor

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Lactose mother liquor stream valorisation using electrodialysis

International Dairy Journal ◽

10.1016/j.idairyj.2021.105102 ◽

2021 ◽

pp. 105102

Author(s):

Arthur Merkel ◽

Matej Vavro ◽

Martin Ondrušek ◽

Daria Voropaeva ◽

Andrey Yaroslavtsev ◽

...

Keyword(s):

Mother Liquor

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Successive Crystallization of Organically Templated Uranyl Sulfates: Synthesis and Crystal Structures of [pyH](H3O)[(UO2)3(SO4)4(H2O)2], [pyH]2[(UO2)6(SO4)7(H2O)], and [pyH]2[(UO2)2(SO4)3]

ChemEngineering ◽

10.3390/chemengineering5010005 ◽

2021 ◽

Vol 5 (1) ◽

pp. 5

Author(s):

Evgeny V. Nazarchuk ◽

Dmitri O. Charkin ◽

Oleg I. Siidra

Keyword(s):

Hydrogen Bonds ◽

Crystal Structures ◽

Hydrothermal Treatment ◽

Mother Liquor ◽

Hydration Water ◽

Isothermal Evaporation ◽

Pyridinium Cations

Three new uranyl sulfates, [pyH](H3O)[(UO2)3(SO4)4(H2O)2] (1), [pyH]2[(UO2)6(SO4)7(H2O)] (2), and [pyH]2[(UO2)2(SO4)3] (3), were produced upon hydrothermal treatment and successive isothermal evaporation. 1 is monoclinic, P21/c, a = 14.3640(13), b = 10.0910(9), c = 18.8690(17) Å, β = 107.795(2), V = 2604.2(4) Å3, R1 = 0.038; 2 is orthorhombic, C2221, a = 10.1992(8), b = 18.5215(14), c = 22.7187(17) Å, V = 4291.7(6) Å3, R1 = 0.030; 3 is orthorhombic, Pccn, a = 9.7998(8), b = 10.0768(8), c = 20.947(2) Å, V = 2068.5(3) Å3, R1 = 0.055. In the structures of 1 and 2, the uranium polyhedra and SO4 tetrahedra share vertices to form ∞3[(UO2)3(SO4)4(H2O)2]2− and ∞3[(UO2)6(SO4)7(H2O)]2− frameworks featuring channels (12.2 × 6.7 Å in 1 and 12.9 × 6.5 Å in 2), which are occupied by pyridinium cations. The structure of 3 is comprised of ∞2[(UO2)2(SO4)3]2− layers linked by hydrogen bonds donated by pyridinium cations. The compounds 1–3 are formed during recrystallization processes, in which the evaporation of mother liquor leads to a stepwise loss of hydration water.

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The Strain Rate Sensitivity and Creep Behavior for the Tripler Plane of Potassium Dihydrogen Phosphate Crystal by Nanoindentation

Micromachines ◽

10.3390/mi12040369 ◽

2021 ◽

Vol 12 (4) ◽

pp. 369

Author(s):

Jianhui Mao ◽

Wenjun Liu ◽

Dongfang Li ◽

Chenkai Zhang ◽

Yi Ma

Keyword(s):

Strain Rate ◽

Strain Rate Sensitivity ◽

Creep Deformation ◽

Potassium Dihydrogen Phosphate ◽

Rate Sensitivity ◽

Dislocation Nucleation ◽

Machining Process ◽

Dihydrogen Phosphate ◽

Potassium Dihydrogen ◽

Kdp Crystals

As an excellent multifunctional single crystal, potassium dihydrogen phosphate (KDP) is a well-known, difficult-to-process material for its soft-brittle and deliquescent nature. The surface mechanical properties are critical to the machining process; however, the characteristics of deformation behavior for KDP crystals have not been well studied. In this work, the strain rate effect on hardness was investigated on the mechanically polished tripler plane of a KDP crystal relying on nanoindentation technology. By increasing the strain rate from 0.001 to 0.1 s−1, hardness increased from 1.67 to 2.07 GPa. Hence, the strain rate sensitivity was determined as 0.053, and the activation volume of dislocation nucleation was 169 Å3. Based on the constant load-holding method, creep deformation was studied at various holding depths at room temperature. Under the spherical tip, creep deformation could be greatly enhanced with increasing holding depth, which was mainly due to the enlarged holding strain. Under the self-similar Berkovich indenter, creep strain could be reduced at a deeper location. Such an indentation size effect on creep deformation was firstly reported for KDP crystals. The strain rate sensitivity of the steady-state creep flow was estimated, and the creep mechanism was qualitatively discussed.

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