New hybrid graphene/inorganic salt composites for thermochemical energy storage: Synthesis, cyclability investigation and heat exchanger metal corrosion protection performance

2020 ◽  
Vol 215 ◽  
pp. 110601 ◽  
Author(s):  
Hanane Ait Ousaleh ◽  
Said Sair ◽  
Said Mansouri ◽  
Younes Abboud ◽  
Abdessamad Faik ◽  
...  
Keyword(s):  
Energy Storage ◽  
Heat Exchanger ◽  
Corrosion Protection ◽  
Inorganic Salt ◽  
Metal Corrosion

scholarly journals Demonstration of Phase Change Thermal Energy Storage in Zinc Oxide Microencapsulated Sodium Nitrate

2021 ◽  
Vol 11 (13) ◽  
pp. 6234
Author(s):  
Ciprian Neagoe ◽  
Ioan Albert Tudor ◽  
Cristina Florentina Ciobota ◽  
Cristian Bogdanescu ◽  
Paul Stanciu ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Thermal Properties ◽  
High Temperature ◽  
Energy Storage ◽  
Phase Change ◽  
Thermal Energy ◽  
Sodium Nitrate ◽  
Thermal Energy Storage ◽  
Metal Corrosion ◽  
Scanning Calorimetry

Microencapsulation of sodium nitrate (NaNO3) as phase change material for high temperature thermal energy storage aims to reduce costs related to metal corrosion in storage tanks. The goal of this work was to test in a prototype thermal energy storage tank (16.7 L internal volume) the thermal properties of NaNO3 microencapsulated in zinc oxide shells, and estimate the potential of NaNO3–ZnO microcapsules for thermal storage applications. A fast and scalable microencapsulation procedure was developed, a flow calorimetry method was adapted, and a template document created to perform tank thermal transfer simulation by the finite element method (FEM) was set in Microsoft Excel. Differential scanning calorimetry (DSC) and transient plane source (TPS) methods were used to measure, in small samples, the temperature dependency of melting/solidification heat, specific heat, and thermal conductivity of the NaNO3–ZnO microcapsules. Scanning electron microscopy (SEM) and chemical analysis demonstrated the stability of microcapsules over multiple tank charge–discharge cycles. The energy stored as latent heat is available for a temperature interval from 303 to 285 °C, corresponding to onset–offset for NaNO3 solidification. Charge–self-discharge experiments on the pilot tank showed that the amount of thermal energy stored in this interval largely corresponds to the NaNO3 content of the microcapsules; the high temperature energy density of microcapsules is estimated in the range from 145 to 179 MJ/m3. Comparison between real tank experiments and FEM simulations demonstrated that DSC and TPS laboratory measurements on microcapsule thermal properties may reliably be used to design applications for thermal energy storage.

scholarly journals Effect of Twisted Fin Array in a Triple-Tube Latent Heat Storage System during the Charging Mode

2021 ◽  
Vol 13 (5) ◽  
pp. 2685
Author(s):  
Mohammad Ghalambaz ◽  
Jasim M. Mahdi ◽  
Amirhossein Shafaghat ◽  
Amir Hossein Eisapour ◽  
Obai Younis ◽  
...  
Keyword(s):  
Energy Storage ◽  
Heat Exchanger ◽  
Latent Heat ◽  
Thermal Energy ◽  
Heat Storage ◽  
Hot Water ◽  
Melting Time ◽  
Latent Heat Storage ◽  
Tube Heat Exchanger ◽  
Storage Rate

This study aims to assess the effect of adding twisted fins in a triple-tube heat exchanger used for latent heat storage compared with using straight fins and no fins. In the proposed heat exchanger, phase change material (PCM) is placed between the middle annulus while hot water is passed in the inner tube and outer annulus in a counter-current direction, as a superior method to melt the PCM and store the thermal energy. The behavior of the system was assessed regarding the liquid fraction and temperature distributions as well as charging time and energy storage rate. The results indicate the advantages of adding twisted fins compared with those of using straight fins. The effect of several twisted fins was also studied to discover its effectiveness on the melting rate. The results demonstrate that deployment of four twisted fins reduced the melting time by 18% compared with using the same number of straight fins, and 25% compared with the no-fins case considering a similar PCM mass. Moreover, the melting time for the case of using four straight fins was 8.3% lower than that compared with the no-fins case. By raising the fins’ number from two to four and six, the heat storage rate rose 14.2% and 25.4%, respectively. This study presents the effects of novel configurations of fins in PCM-based thermal energy storage to deliver innovative products toward commercialization, which can be manufactured with additive manufacturing.

scholarly journals Thermal Energy Storage Performance of Tetrabutylammonium Acrylate Hydrate as Phase Change Materials

2021 ◽  
Vol 11 (11) ◽  
pp. 4848
Author(s):  
Hitoshi Kiyokawa ◽  
Hiroki Tokutomi ◽  
Shinichi Ishida ◽  
Hiroaki Nishi ◽  
Ryo Ohmura
Keyword(s):  
Energy Storage ◽  
Heat Exchanger ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Solid Phase ◽  
Agitation Rate ◽  
Mechanical Agitation ◽  
External Forces

Kinetic characteristics of thermal energy storage (TES) using tetrabutylammonium acrylate (TBAAc) hydrate were experimentally evaluated for practical use as PCMs. Mechanical agitation or ultrasonic vibration was added to detach the hydrate adhesion on the heat exchanger, which could be a thermal resistance. The effect of the external forces also was evaluated by changing their rotation rate and frequency. When the agitation rate was 600 rpm, the system achieved TES density of 140 MJ/m3 in 2.9 hours. This value is comparable to the ideal performance of ice TES when its solid phase fraction is 45%. UA/V (U: thermal transfer coefficient, A: surface area of the heat exchange coil, V: volume of the TES medium) is known as an index of the ease of heat transfer in a heat exchanger. UA/V obtained in this study was comparable to that of other common heat exchangers, which means the equivalent performance would be available by setting the similar UA/V. In this study, we succeeded in obtaining practical data for heat storage by TBAAc hydrate. The data obtained in this study will be a great help for the practical application of hydrate heat storage in the future.

scholarly journals Experimental and Theoretical Investigation of the Natural Convection Heat Transfer Coefficient in Phase Change Material (PCM) Based Fin-and-Tube Heat Exchanger

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 716
Author(s):  
Saulius Pakalka ◽  
Kęstutis Valančius ◽  
Giedrė Streckienė
Keyword(s):  
Heat Transfer ◽  
Heat Transfer Coefficient ◽  
Natural Convection ◽  
Energy Storage ◽  
Heat Exchanger ◽  
Transfer Coefficient ◽  
Convection Heat Transfer ◽  
Natural Convection Heat Transfer ◽  
Convection Heat ◽  
Convection Heat Transfer Coefficient

Latent heat thermal energy storage systems allow storing large amounts of energy in relatively small volumes. Phase change materials (PCMs) are used as a latent heat storage medium. However, low thermal conductivity of most PCMs results in long melting (charging) and solidification (discharging) processes. This study focuses on the PCM melting process in a fin-and-tube type copper heat exchanger. The aim of this study is to define analytically natural convection heat transfer coefficient and compare the results with experimental data. The study shows how the local heat transfer coefficient changes in different areas of the heat exchanger and how it is affected by the choice of characteristic length and boundary conditions. It has been determined that applying the calculation method of the natural convection occurring in the channel leads to results that are closer to the experiment. Using this method, the average values of the heat transfer coefficient (have) during the entire charging process was obtained 68 W/m2K, compared to the experimental result have = 61 W/m2K. This is beneficial in the predesign stage of PCM-based thermal energy storage units.

Corrosion prevention prospects of polymeric nanocomposites: A review

2018 ◽  
Vol 35 (2) ◽  
pp. 181-202 ◽  
Author(s):  
Ayesha Kausar
Keyword(s):  
Corrosion Protection ◽  
High Performance ◽  
Barrier Properties ◽  
Metal Corrosion ◽  
Future Research ◽  
Polymeric Nanocomposites ◽  
Bipolar Plates ◽  
Corrosion Prevention ◽  
Covalent Interaction ◽  
Structural Parts

Corrosion is a serious problem for implementing metallic components and devices in industrial zones. Considerable effort has been made to develop corrosion prevention strategies. Initially, paints, pigments, and organic coatings have been applied to prevent metal corrosion. Consequently, conjugated polymers, epoxy resin, phenolics, acrylic polymers, and many thermoplastics as well as thermoset resins have been used to inhibit corrosion. Lately, nanofillers such as fullerene, nanodiamond, graphene, graphene oxide, carbon nanotube, carbon black, nanoclay, and inorganic nanoparticle have been introduced in polymeric matrices to harness valuable corrosion protection properties of the nanocomposite. Corrosion protection performance of a nanocomposite depends on nanofiller dispersion, physical and covalent interaction between matrix/nanofiller and nanofiller adhesion to the substrate. Moreover, a high performance anti-corrosion nanocomposite must have good barrier properties, and high scratch, impact, abrasion, and chemical resistance. Thus, polymeric nanocomposites have been found to prevent corrosion in aerospace and aircraft structural parts, electronic components, bipolar plates in fuel cells, and biomedical devices and systems. However, numerous challenges need to be addressed in this field to attain superior corrosion resistant nanocomposites. Future research on polymer nanocomposites has the potential to resolve the current challenges of metal corrosion through entire replacement of metal-based materials with advanced nanomaterials.

scholarly journals Flow and heat transfer performance of plate phase change energy storage heat exchanger

2019 ◽  
Vol 23 (3 Part B) ◽  
pp. 1989-2000
Author(s):  
Ji-Min Zhang ◽  
Shi-Ting Ruan ◽  
Jian-Guang Cao ◽  
Tao Xu
Keyword(s):  
Heat Transfer ◽  
Energy Storage ◽  
Heat Exchanger ◽  
Phase Change ◽  
Thermal Control ◽  
Heat Transfer Characteristics ◽  
Liquid Distribution ◽  
Transfer Characteristics ◽  
Flow And Heat Transfer ◽  
Short Time

In the present work, the phase change energy storage heat exchanger in thermal control system of short-time and periodic working satellite payloads is taken as the research object. Under the condition of constant heated power of the satellite payload, the heat transfer characteristics of phase change energy storage heat exchanger are analyzed by numerical simulation and experimental method. The heat exchanger with fin arrays to enhance heat transfer is filled with tetradecane, whose density varies with temperature. The flow field distribution, the solid-liquid distribution, the temperature distribution, and the phase change process in the plate phase change energy storage heat exchanger unit are analyzed. The flow and heat transfer characteristics of heat exchangers under different fluid-flow rates and temperature were investigated.

The Optimum Design of Stratified Thermal Energy Storage Systems—Part II: Completion of the Analytical Model, Presentation and Interpretation of the Results

1992 ◽  
Vol 114 (3) ◽  
pp. 204-208 ◽  
Author(s):  
R. J. Krane ◽  
M. J. M. Krane
Keyword(s):  
Energy Storage ◽  
Heat Exchanger ◽  
Analytical Model ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Storage System ◽  
Energy Storage System ◽  
Thermal Energy Storage System ◽  
Thermal Energy Storage Systems ◽  
Performance Gains

This investigation is presented in two parts. The basic analytical model is developed in Part I. Part II includes the completion of the analytical model and the results of an optimization study performed with this model. The results show that: 1) Significant performance gains, that is, reductions in the entropy generation number on the order of 10 percent, are possible by employing perfectly stratified thermal energy storage systems that are designed on the basis of the second law of thermodynamics. 2) These performance gains are mainly due to the complete elimination of the entropy generation due to heat transfer through finite temperature differences within the storage element. 3) In general, the optimum design of a perfectly stratified thermal energy storage system requires the use of a very large heat exchanger; however, it is possible to employ a much smaller than optimum heat exchanger without seriously degrading the superior performance of the system. 4) The operation of a stratified system is quite flexible because it has no optimum storage time. 5) The optimum values of the capacity rate ratios, (φR)opt and (φR)opt, for a perfectly stratified thermal energy storage system are in general not equal to unity; however, this finding is shown to be in concert with Bejan’s theory of “remanent” irreversibilities for a heat exchanger.

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