scholarly journals Screening and optimization of processing temperature for Sb2Se3 thin film growth protocol: Interrelation between grain structure, interface intermixing and solar cell performance

2021 ◽  
Vol 225 ◽  
pp. 111045
Author(s):  
Nicolae Spalatu ◽  
Robert Krautmann ◽  
Atanas Katerski ◽  
Erki Karber ◽  
Raavo Josepson ◽  
...  
2000 ◽  
Vol 653 ◽  
Author(s):  
Jie Zhang ◽  
James B. Adams

AbstractWe present FACET: a two dimensional simulator to model polycrystalline thin film growth, which links atomic scale processes to macroscopic phenomena. The model is based on the concept of describing the crystal surface in terms of preferred facets. Line segments were used to depict the profile of the grain and grain boundaries. Multiple nuclei are semi-randomly distributed along the textured or non-textured surface, and crystallographycally appropriate facets are created in the nucleation simulation. We use a Kinetic Lattice Monte Carlo (KLMC) method to calculate the inter-facet diffusion rates and use a continuum approach to grow the facets, hence the multiple grains. The software is Windows(95/98/2000/NT) based and has an integrated Graphical User Interface, within which a user can input deposition conditions and experimental and simulation data, visualize the nucleation and growth of the grains, and obtain the final grain structure and texture.


2020 ◽  
Vol 110 ◽  
pp. 110524
Author(s):  
Ali Baltakesmez ◽  
Betül Güzeldir ◽  
Yunus Alkan ◽  
Mustafa Sağlam ◽  
Mehmet Biber

2015 ◽  
Vol 1738 ◽  
Author(s):  
Liyuan Zhang ◽  
Sreejith Karthikeyan ◽  
Mandip J. Sibakoti ◽  
Stephen A. Campbell

ABSTRACTWe investigate the synthesis of kesterite Cu2ZnSnS4 (CZTS) thin films using thermal evaporation from copper, zinc and tin pellets and post-annealing in a sulfur atmosphere. The effects of chemical composition were studied both on the absorber layer properties and on the final solar cell performance. It is confirmed that CZTS thin film chemical composition affects the carrier concentration profile, which then influences the solar cell properties. Solar cells using a CZTS thin film with composition ratio Cu/(Zn+Sn) = 0.87, and Zn/Sn = 1.24 exhibited an open-circuit voltage of 483 mV, a short-circuit current of 14.54 mA/cm2, a fill factor of 37.66 % and a conversion efficiency of 2.64 %. Only a small deviation from the optimal chemical composition can drop device performance to a lower level, which confirms that the CZTS solar cells with high conversion efficiency existed in a relatively narrow composition region.


2016 ◽  
Vol 688 ◽  
pp. 12-17 ◽  
Author(s):  
In Young Kim ◽  
Ju Yeon Lee ◽  
Uma V. Ghorpade ◽  
M.P. Suryawanshi ◽  
Dong Seon Lee ◽  
...  

1998 ◽  
Vol 13 (3) ◽  
pp. 551-556
Author(s):  
A. F. Marshall

The evolution of surface structure, grain microstructure, and superconducting transition temperature of a-axis YBa2Cu3O7 thin films has been studied as a function of film thickness. The grain size increases and develops a bimodal distribution of grain size during film growth, concurrent with an improvement in Tc. The surface structure does not represent the grain size, but rather the development of the bimodal grain structure follows the formation of the surface structure. The results are discussed in terms of thin film growth modes.


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