Improvement of EB-PVD thermal barrier coatings by treatments of a vacuum plasma-sprayed bond coat

2008 ◽  
Vol 203 (1-2) ◽  
pp. 160-170 ◽  
Author(s):  
U. Schulz ◽  
O. Bernardi ◽  
A. Ebach-Stahl ◽  
R. Vassen ◽  
D. Sebold
Keyword(s):  
Thermal Barrier Coatings ◽  
Bond Coat ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Vacuum Plasma ◽  
Plasma Sprayed

NONDESTRUCTIVE IMPEDANCE SPECTROSCOPY EVALUATION OF THE BOND COAT OXIDATION IN THERMAL BARRIER COATINGS

2007 ◽  
Vol 14 (05) ◽  
pp. 935-943 ◽  
Author(s):  
L. YANG ◽  
Y. C. ZHOU ◽  
W. G. MAO ◽  
Q. X. LIU
Keyword(s):  
Impedance Spectroscopy ◽  
Thermal Barrier Coatings ◽  
Bond Coat ◽  
Equivalent Circuit Model ◽  
Isothermal Oxidation ◽  
Thermally Grown Oxide ◽  
Thermal Barrier ◽  
Air Plasma ◽  
Barrier Coatings ◽  
Plasma Sprayed

In this paper, the impedance spectroscopy technique was employed to examine nondestructively the isothermal oxidation of air plasma sprayed (APS) thermal barrier coatings (TBCs) in air at 800°C. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were also used to characterize the microstructure evolution of TBCs. After oxidation, the thermally grown oxide (TGO), which was mainly composed of alumina as confirmed by EDX, formed at the upper ceramic coat/bond coat interface, the lower bond coat/substrate interface, and the bond coat. Impedance diagrams obtained from impedance measurements at room temperature were analyzed according to the equivalent circuit model proposed for the TBCs. Various observed electrical responses relating to the growth of oxides and the sintering of YSZ were explained by simulating the impedance spectra of the TBCs.

Vacuum Plasma Sprayed ZrO2-Based Thermal Barrier Coatings for Aerospace Applications

1998 ◽  
Author(s):  
T. Brzezinski ◽  
A. Cavasin ◽  
S. Grenier ◽  
E. Kharlanova ◽  
G. Kim ◽  
...  
Keyword(s):  
Thermal Shock ◽  
Thermal Barrier Coatings ◽  
Temperature Drop ◽  
Single Step ◽  
Atmospheric Plasma ◽  
Thermal Barrier ◽  
Vacuum Plasma Spray ◽  
Barrier Coatings ◽  
Vacuum Plasma ◽  
Plasma Sprayed

Abstract Zirconia-based thermal barrier coatings (TBCs), produced using Vacuum Plasma Spray (VPS) technology, were recently subjected to burner rig testing. The VPS TBC performance was compared to TBCs deposited using conventional Atmospheric Plasma Sprayed (APS) and Electron Beam Physical Vapor Deposition (EB-PVD) techniques. All of the coatings consisted of an MCrAlY bond coat and a partially stabilized ZrO2-8%Y2O3 (PSZ) top coat. The TBC coated pins (6.35 mm in diameter) were tested using gas temperatures ranging from 110CC to 1500°C. The pins were tested to failure under severe conditions (1500°C gas temperature, with no internal cooling). The initial testing indicated that under typical operating gas temperatures (1400°C), the VPS TBC performance was comparable, if not superior, to conventional TBCs. Following the encouraging results, thick composite TBCs, produced in a single-step operation, were investigated. Preliminary work on ZrO2-8% Y2O3/Ca2SiO4 composite TBCs with interlayer grading included thermal shock testing and temperature drop measurements across the TBC. The composite TBC thicknesses ranged from 850µm to 1.8 mm. Initial results indicate that thick adherent composite TBCs, with high resistance to severe thermal shock, can be produced in a single step using the VPS process.

A comparative study on the performance of suspension plasma sprayed thermal barrier coatings with different bond coat systems

2015 ◽  
Vol 275 ◽  
pp. 276-282 ◽  
Author(s):  
Zhonghua Zou ◽  
Jack Donoghue ◽  
Nicholas Curry ◽  
Lixia Yang ◽  
Fangwei Guo ◽  
...  
Keyword(s):  
Comparative Study ◽  
Thermal Barrier Coatings ◽  
Bond Coat ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Plasma Sprayed

Depletion Model of Aluminum in Bond Coat for Plasma-Sprayed Thermal Barrier Coatings

2009 ◽  
Vol 75 ◽  
pp. 31-35 ◽  
Author(s):  
Chang Che ◽  
G.Q. Wu ◽  
Hong Yu Qi ◽  
Z. Huang ◽  
Xiao Guang Yang
Keyword(s):  
Mathematical Model ◽  
Thermal Barrier Coating ◽  
Thermal Barrier Coatings ◽  
Bond Coat ◽  
Thermal Exposure ◽  
Thermal Barrier ◽  
Air Plasma ◽  
Barrier Coatings ◽  
Barrier Coating ◽  
Plasma Sprayed

The aluminum depletion of NiCrAlY bond coat in an air-plasma-sprayed thermal barrier coating (TBC) has been studied by experimental and simulative approaches. Upon thermal exposure, Al depletion regions were observed. The depletion of aluminum is resulting from Al diffusion towards the surface of bond coat and into substrate. A mathematical model of Al depletion was presented. The model is able to explain the observed results in a qualitative way and has been shown that Al depletes within the bond coat by diffusion.

scholarly journals The Evaluation of Durability of Plasma-Sprayed Thermal Barrier Coatings with Double-layer Bond Coat

Coatings ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 241 ◽  
Author(s):  
Li ◽  
Peng ◽  
Dong ◽  
Zhou ◽  
Wang ◽  
...  
Keyword(s):  
Thermal Barrier Coatings ◽  
Double Layer ◽  
Bond Coat ◽  
Coefficient Of Thermal Expansion ◽  
Type A ◽  
Thermal Barrier ◽  
Type B ◽  
Barrier Coatings ◽  
Oxidation Layer ◽  
Plasma Sprayed

The durability of atmospheric plasma-sprayed thermal barrier coatings (APS TBCs) with a double-layer bond coat was evaluated via isothermal cycling tests under 1120 °C. The bond coat consisted of a porosity layer deposited on the substrate and an oxidation layer deposited on the porosity layer. Two types of double-layer bond coats with different thickness ratios of the porosity layer to the oxidation layer (type A: 1:2 and type B: 2:1, respectively) were prepared. The results show that the porosity layer was oxidation free, the oxidation layer included a fraction of well-distributed α-Al2O3. The coefficient of thermal expansion of the oxidation layer was about 11.2 × 10−6 K−1, which was rather lower than that of the porosity layer. Thus, the oxidation layer can be regards as a secondary bond coat between ceramic topcoat and traditional bond coat. The thermal cyclic lifetime of type A TBCs was about 60 cycles, which exceeded 1.2 times the durability of type B TBCs. The delamination cracks in both TBCs all propagated in the ceramic topcoat, which were all identical to those in traditional TBCs. Therefore, the design of the double-layer bond coat affected the stress level rather than the stress distribution in TBCs.

Properties of ZrO2-7wt%Y2O3 Thermal Barrier Coatings in Relation to Plasma Spraying Conditions

1997 ◽  
Author(s):  
C. Funke ◽  
B. Siebert ◽  
D. Stöver ◽  
R. Vaßen
Keyword(s):  
Elastic Modulus ◽  
Plasma Spraying ◽  
Thermal Barrier Coatings ◽  
Bond Coat ◽  
Free Edge ◽  
Ceramic Coatings ◽  
Thermal Barrier ◽  
Normal Stresses ◽  
Barrier Coatings ◽  
Plasma Sprayed

Abstract Superalloy samples were coated with thermal barrier coatings (TBC). This TBC-system consisted of two layers. The first layer was a vacuum-plasma sprayed, corrosion resistant layer (MCrAlY) which also acted as a bond coat. The ceramic top layer was atmospheric-plasma sprayed Y2O3-stabilized ZrO2. In order to produce different microstructures, the plasma-spraying parameters for the production of the ceramic coatings were varied. The different ceramic coatings were characterized in terms of porosity and mean elastic modulus. The porosity distribution was also investigated due to its influence on the measured elastic modulus. To record the changes of the plasma sprayed Zirconia due to sintering, the mean elastic modulus of selected coatings was measured as a function of annealing time. One series of TBC-coated specimens was cyclically oxidized at a maximum temperature of 1100°C. After 500 h of thermal cycling, creep within the MCrAlY-bond coat led to a coating failure at both the internal beveled edge and free edge around the specimen. A finite element analysis study of the cyclic oxidation experiment was performed to gain insight into the stress redistributions within the bond coat as a function of time. During the initial temperature increase, critical tensile normal stresses developed above the MCrAlY-Zirconia interface at the free edge. However, these normal stresses became compressive for all following cooling cycles. On the other hand, large tensile normal stresses developed above the MCrAlY-Zirconia interface at the beveled edge during all the cooling cycles. Therefore, high normal stresses responsible for debonding were present within the ceramic coating during all cooling cycles with the most critical stresses occurring at the free edge during the first cooling cycle and near the beveled edge for all the following cooling cycles.

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