Comparative analysis of metal diffusion effects in polymer films coated with spin coating and floating film transfer techniques

2020 ◽  
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Kshitij Bhargava ◽  
Nikita Kumari ◽  
Shyam S. Pandey ◽  
Vipul Singh
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Jin Kon Kim

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John M. Torkelson

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Rahmi Ozisik ◽  
Richard W. Siegel

ABSTRACTNanoporous polymer films have been prepared using immiscible blends of polyetherimide (PEI) and poly(caprolactone diol) (PCLD). The films were prepared by spin-coating from a common solvent — dichloromethane (DCM). To create the nanoporous films, PCLD was removed by immersing the films in acetone, which dissolves PCLD only. Field emission scanning electron microscopy was used to study the porous structure. The pore structure of the films was affected by many factors such as composition of the blend, molecular weight, and various processing parameters. The formation of nanometer size pores was mainly due to the fast phase separation process during spin-coating. The pore size and pore size distribution was found to depend on the blend composition.


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