Synthesis of layered vs planar Mo2C: role of Mo diffusion

Chemical Vapor Deposition (CVD) growth of Metal Carbides is of great interest as this method provides large area growth of MXenes. This growth is mainly done using a melted diffusion-based process; however, different morphologies in growth process is not well understood. In this work, we report deterministic synthesis of layered (non-uniform c-axis growth) and planar (uniform c-axis growth) of Molybdenum Carbide (Mo2C) using a diffusion-mediated growth. Mo-diffusion limited growth mechanism is proposed where the competition between Mo and C adatoms determines the morphology of grown crystals. Difference in thickness of catalyst at the edge and center lead to enhanced Mo diffusion which plays a vital role in determining the structure of Mo2C. The layered structures exhibit an expansion in the lattice confirmed by the presence of strain. Density Functional Theory (DFT) shows consistent presence of strain which is dependent upon Mo diffusion during growth. This work demonstrates the importance of precise control of diffusion through the catalyst in determining the structure of Mo2C and contributes to broader understanding of metal diffusion in growth of MXenes.

Progenitor-mass-dependent yields amplify intrinsic scatter in dwarf-galaxy elemental abundance ratios

ABSTRACT We explore the effect of including progenitor mass- and metallicity-dependent yields, supernova rates and energetics on variations in elemental abundance ratios (particularly [α/Fe]) in dwarf galaxies. To understand how the scatter and overall trends in [α/Fe] are affected by including variable metal yields from a discretely sampled initial mass function, we run FIRE simulations of a dwarf galaxy (M⋆(z = 0$) \sim 10^6\rm \, M_{\odot })$ using nucleosynthetic yields from the NuGrid data base that depend on the stellar progenitor mass and metallicity. While NuGrid exhibits lower aggregate α-element production than default FIRE yields, we find that its explicit mass dependence, even when including turbulent metal diffusion, substantially widens the intrinsic scatter in the simulated [Fe/H]-[α/Fe] – a phenomenon visible in some observations of dwarf galaxies.

The physics of gas phase metallicity gradients in galaxies

We present a new model for the evolution of gas phase metallicity gradients in galaxies from first principles. We show that metallicity gradients depend on four ratios that collectively describe the metal equilibration timescale, production, transport, consumption, and loss. Our model finds that most galaxy metallicity gradients are in equilibrium at all redshifts. When normalized by metal diffusion, metallicity gradients are governed by the competition between radial advection, metal production, and accretion of metal-poor gas from the cosmic web. The model naturally explains the varying gradients measured in local spirals, local dwarfs, and high-redshift star-forming galaxies. We use the model to study the cosmic evolution of gradients across redshift, showing that the gradient in Milky Way-like galaxies has steepened over time, in good agreement with both observations and simulations. We also predict the evolution of metallicity gradients with redshift in galaxy samples constructed using both matched stellar masses and matched abundances. Our model shows that massive galaxies transition from the advection-dominated to the accretion-dominated regime from high to low redshifts, which mirrors the transition from gravity-driven to star formation feedback-driven turbulence. Lastly, we show that gradients in local ultraluminous infrared galaxies (major mergers) and inverted gradients seen both in the local and high-redshift galaxies may not be in equilibrium. In subsequent papers in this series, we show that the model also explains the observed relationship between galaxy mass and metallicity gradients, and between metallicity gradients and galaxy kinematics.

Thermodynamic-driven metal diffusion strategy for controlled synthesis of high-entropy alloy electrocatalysts

We have reported the thermodynamic-driven metal diffusion strategy for the controlled synthesis of high-entropy alloy (HEA) nanocrystals using electrospun carbon nanofibers (CNFs) as nanoreactors. This conceptually pathway overcome the high...

Transparent-Conductive-Oxide-Free Front Contacts for High Efficiency Silicon Heterojunction Solar Cells

In order to compensate the insufficient conductance of heterojunction thin films, transparent conductive oxides (TCO) have been used for decades in both-sides contacted crystalline silicon heterojunction (SHJ) solar cells to provide lateral conduction for efficient carrier collection. In this work, we substitute the TCO layers by utilizing the lateral conduction of c-Si absorber, thereby enabling a TCO-free design. A series resistance of 0.32 Ωcm2 and a fill factor of 80.7% were measured for a TCO-free back-junction SHJ solar cell with a conventional finger pitch of 1.8 mm, thereby proving that relying on lateral conduction in the c-Si bulk is compatible with low series resistances. Achieving high efficiencies in SHJ solar cells with TCO-free front contacts requires suppressing deterioration of the passivation quality induced by direct metal-a-Si:H contacts and in-diffusion of metal into the a-Si:H layer. We show that an ozone treatment at the a-Si:H/metal interface suppresses the metal diffusion and improves the passivation without increasing the contact resistivity. SHJ solar cells with TCO-free front contacts and ozone treatment achieve efficiencies of > 22%.