Rational design of novel isoindigo based donor–acceptor type conjugated polymers with low bandgaps as solution-processed high-performance electrochromic materials

2020 ◽  
Vol 270 ◽  
pp. 116589
Author(s):  
Xinfeng Cheng ◽  
Yueqiang Ma ◽  
Xiuping Ju ◽  
Wei Zhao ◽  
Jinsheng Zhao ◽  
...  
2015 ◽  
Vol 6 (9) ◽  
pp. 1487-1494 ◽  
Author(s):  
Qun Ye ◽  
Wei Teng Neo ◽  
Tingting Lin ◽  
Jing Song ◽  
Hong Yan ◽  
...  

Novel solution-processable pyrrolophthalazine dione-containing electrochromic conjugated polymers with high optical contrast, high coloration efficiency, and good long-term stability were reported.


2016 ◽  
Vol 4 (28) ◽  
pp. 6769-6777 ◽  
Author(s):  
Sunil Kumar ◽  
Meenu Singh ◽  
Jwo-Huei Jou ◽  
Subrata Ghosh

A methodology to delimit the large Stokes shifts in the donor–acceptor (D–A) design by studying D and A in para-relationship with solution processed blue OLED device application is reported.


2015 ◽  
Vol 17 (30) ◽  
pp. 20014-20020 ◽  
Author(s):  
Jing Lu ◽  
Yiying Zheng ◽  
Jingping Zhang

The rational design of a novel phenoxazine-based D–B–A2–B–D TADF candidate with smaller ΔEST values and higher carrier transport.


2021 ◽  
pp. 2101105
Author(s):  
Kyumin Lee ◽  
Moon‐Ki Jeong ◽  
Eui Hyun Suh ◽  
WonJo Jeong ◽  
Jong Gyu Oh ◽  
...  

2020 ◽  
Author(s):  
Hanyu Jia ◽  
Zhen Huang ◽  
Peiyun Li ◽  
song zhang ◽  
yunfei wang ◽  
...  

To date, high-performance organic electrochemical transistors (OECTs) are all based on polythiophene systems. Donor-acceptor (D-A) conjugated polymers are expected to be promising materials for OECTs owing to their high mobility and comparatively low crystallinity (good for ion diffusion). However, the OECT performance of D-A polymers lags far behind that of the polythiophenes. Here we synergistically engineered the backbone, side chain of a series of diketopyrrolopyrrole (DPP)-based D-A polymers and found that redox potential, molecular weight, solution processability, and film microstructures are essential to their performance. Among the polymers, P(bgDPP-MeOT2) exhibited a figure-of-merit (μC*) of 225 F cm<sup>–1</sup> V<sup>–1</sup> s<sup>–1</sup>, <a>over one order of magnitude higher than previously reported D-A polymers. Besides, the DPP polymers exhibited high hole mobility over 2 cm<sup>2</sup> V</a><sup>−1</sup> s<sup>−1</sup>, significantly higher than all D-A polymers employed in OECTs, leading to fast response OECTs with a record low turn-off response time of 30 μs. <a>The polymer also exhibited better stability than polythiophene systems with current retention of 98.8% over 700 electrochemical switching cycles.</a> This work provides a systematic solution to unleash the high-performance and fast-response nature of D-A polymers in OECTs.


2017 ◽  
Vol 5 (1) ◽  
pp. 12-28 ◽  
Author(s):  
Xiaojing Lv ◽  
Weijun Li ◽  
Mi Ouyang ◽  
Yujian Zhang ◽  
Dominic S. Wright ◽  
...  

Conjugated polymers with various electron-donor (D) and -acceptor (A) structures present diverse electrochemical, optical–physical and EC properties.


2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Yanlian Lei ◽  
Ping Deng ◽  
Jun Li ◽  
Ming Lin ◽  
Furong Zhu ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (41) ◽  
pp. 34849-34854 ◽  
Author(s):  
Yunfeng Deng ◽  
Jesse Quinn ◽  
Bin Sun ◽  
Yinghui He ◽  
Jackson Ellard ◽  
...  

Two donor–acceptor (D–A) conjugated polymers,PIDTOBTandPIDTOBTz, based on thiophene-S,S-dioxidized indophenine (IDTO) as the acceptor building block are synthesized for solution processed organic thin-film transistors.


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