scholarly journals Ultrasonic-assisted biosurface modification of multi-walled carbon nanotubes with Thiamine and its influence on the properties of PVC/Tm-MWCNTs nanocomposite films

2017 ◽  
Vol 39 ◽  
pp. 589-596 ◽  
Author(s):  
Shadpour Mallakpour ◽  
Amir Abdolmaleki ◽  
Faezeh Azimi
2016 ◽  
Vol 16 (4) ◽  
pp. 4224-4232
Author(s):  
Xiaoning Liang ◽  
Wei Li

We studied the dispersity of multi-walled carbon nanotubes (MWNTs) combined with different metallic particles (Ni and Fe). An ultrasonic-assisted water-bath dispersion process was used to disperse the metal-coated MWNTs in different solutions and the dispersity was measured using an ultraviolet-visible spectrophotometer. The dispersity and morphology of the MWNTs were characterized using field-emission scanning electron microscopy (FE-SEM) together with digital image processing technology. Effects of dispersant type (sodium dodecyl benzene sulfonate (SDBS), oleic acid, and polymer (TNEDIS)) and surfactant dosage on the dispersity of the metal-coated MWNTs were investigated under controlled and uncontrolled temperatures and results were compared with those from the untreated MWNTs. The results showed that the negative effects of temperature on the ultrasonic dispersion process could be eliminated through a temperature-controlled system. Moreover, the TNEDIS, SDBS, and oleic acid were arranged in the descending order of the dispersion effect degree. The untreated MWNTs, Ni-coated MWNTs, and Fe-coated MWNTs were arranged in the descending degree of dispersity order. Since the metal coating makes the MWNTs harder and more fragile, the metal-coated MWNTs are more likely to fracture during the ultrasonic dispersion process.


2021 ◽  
Vol 13 (4) ◽  
pp. 457-464
Author(s):  
Sergey V. Vasin ◽  
◽  
Azat M. Nizametdinov ◽  
Viacheslav A. Sergeev ◽  
Michael S. Efimov ◽  
...  

The results of the study of the effect of the permanent magnetic field of a neodymium magnet on the polymerization process and the electrophysical characteristics of polyvinyl alcohol (PVA) films with the inclusion of multi-walled carbon nanotubes (MWCNTs) are presented. When studying the morphology of films using a scanning electron microscope, it was found that nanocomposite films with a thickness of 30 microns, cured in the presence of a magnetic field with the direction of the magnetic induction vector perpendicular to the surface of the films, have a homogeneous structure, while a significant number of MWCNTs agglomerations are observed in control samples of films. Measurements of the conductivity of films in the direction of the MWCNTs orientation at direct and alternating current showed that the conductivity of films obtained in a magnetic field significantly (by almost two orders of magnitude) exceeds the conductivity of control samples. The obtained results are analyzed on the basis of known models of electrical conductivity of nanocomposites with oriented MWCNTs. The degree of orientation of the MWCNTs during the curing of films in a magnetic field is estimated, taking into account the increase in the viscosity of the nanocomposite during the curing process.


2018 ◽  
Vol 6 (40) ◽  
pp. 10829-10837 ◽  
Author(s):  
Guifang Liu ◽  
Yi Chen ◽  
Minjie Gong ◽  
Xiaoyun Liu ◽  
Zhong-Kai Cui ◽  
...  

Enhanced dielectric constant of PDMS incorporating chain-ball structured CCTO@MWCNT nanoparticles.


2022 ◽  
Author(s):  
Fatma Sarf ◽  
Irmak Karaduman ◽  
Ahmad Ajjaq ◽  
Emin Yakar ◽  
Ali Orkun Çağırtekin ◽  
...  

Abstract In this research, pure SnO2 and Ni-doped SnO2 (Ni:SnO2) nanocomposite films were produced by chemical bath deposition method and the latter were coated with multi-walled carbon nanotubes (Ni:SnO2/MWCNTs) or graphene nanoplatelets (Ni:SnO2/GNPs) by spin coating. All samples have tetragonal rutile SnO2 structure with the presence of carbon (002) peak in MWCNTs- or GNPs-coated films. Crystallite size of SnO2 films decreased remarkably with Ni doping followed by a slight decrease with MWCNTs coating and slight increase with GNPs coating. Scanning electron microscope images manifested a dispersed agglomerative nature of SnO2 nanoparticles which reduced especially with MWCNTs coating due to the porous surface provided by carbon nanotubes. From the photoluminescence measurements, oxygen defects-related peaks were spotted in the SnO2-based structures with different luminescence intensities. The most significant decrease in resistance was observed with the addition of GNPs into Ni-doped SnO2 nanocomposites compared to the other produced films mainly due to the synergetic effect that promotes excellent charge transfer between surfaces of Ni:SnO2 and graphene nanosheet. The huge increase in conductivity of GNPs-coated films led to a huge increase in dielectric losses and this followed by a drop down of dielectric constant of the GNPs-coated films.


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