Spectroscopical characterization of carbonaceous matter prepared through the Glaser coupling reaction route

Poly(vinylbiphenyl)s bearing glycoside ligands at the side chains were prepared using the Suzuku coupling reaction. Effects of glycoside reactant concentration, halide species, glycoside species, and catalyst species on the incorporation...

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On the reaction of GeCl2·dioxane with KFeCp(CO)2: isolation and characterization of novel bimetallic clusters

Dalton Transactions ◽

10.1039/c9dt00097f ◽

2019 ◽

Vol 48 (12) ◽

pp. 3831-3834 ◽

Cited By ~ 2

Author(s):

Lars Preißing ◽

Claudio Schrenk ◽

Andreas Schnepf

Keyword(s):

Cluster Compounds ◽

Bimetallic Clusters ◽

Complex Reaction ◽

Reaction Route ◽

Isolation And Characterization

The reaction of GeCl2·dioxane with KFeCp(CO)2 leads to polyhedral cluster compounds with six germanium atoms like Ge6[FeCp(CO)2]6 or Ge6Cl2[FeCp(CO)2]6via a complex reaction route.

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Synthesis and Characterization of Novel PEPPSI type Pd–BICAAC Complexes

10.26434/chemrxiv-2022-0m443 ◽

2022 ◽

Author(s):

Márton Nagyházi ◽

Balázs Almási ◽

Ádám Lukács ◽

Attila Bényei ◽

Tibor Nagy ◽

...

Keyword(s):

High Activity ◽

Coupling Reaction ◽

Kinetic Studies ◽

Elemental Mercury ◽

Palladium Complexes ◽

Synthesis And Characterization ◽

Heck Coupling ◽

Moisture Resistant

A series of bicyclic alkylamino carbenes (BICAAC) (where N-aryl = dipp, mes, 2,6-dimethyl-4-(dimethylamino)phenyl, 5a-d) and their novel air- and moisture-resistant pyridine (pyridine, 4 dimethylaminopyridine) containing palladium PEPPSI-type Pd(II) complexes (6a-e) were synthetized and characterized. The new palladium complexes have shown high activity in Mizoroki–Heck coupling reaction even at as low as 100 ppm loading (TON up to 10000). Kinetic studies revealed that reactions carried out in the presence of elemental mercury resulted in decrease in activity. It indicates that the coupling reaction may have both molecular and Pd(0)-mediated catalytic paths.

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Conductive Polymers Based on Phenothiazine-Benzothiadiazole: Synthesis, Characterization of Photovoltaics

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.634-638.2643 ◽

2013 ◽

Vol 634-638 ◽

pp. 2643-2650 ◽

Cited By ~ 3

Author(s):

Dae Hee Yun ◽

Han Sol Yoo ◽

Tae Won Ko ◽

Yong Sung Park ◽

Je Wan Woo

Keyword(s):

Conjugated Polymers ◽

Power Conversion ◽

Coupling Reaction ◽

Band Gap Energy ◽

Suzuki Coupling Reaction ◽

Gap Energy ◽

Solution State ◽

Conversion Efficiencies ◽

Film State

Two new π-conjugated polymers (Poly[(N-10’-(octan-3-yl)-phenothiazin-3,7-ylene)-alt- (4’,7’-bis(thiophen-2-yl)benzo[c][1,2,5]thiadiazole)] (PoPTZ-BT-BTD), Poly[(N-10`-(octan-3-yl) -phenothiazin-3,7-ylene)-alt-(4’,7’-bis(thiophen-2-yl)-5,6-bis(octyloxy)benzo[c][1,2,5]thiadiazole)] (PoPTZ-BT-BoBTD) ) were synthesized through the Suzuki coupling reaction for organic photovoltaics (OPVs), and their optical and electrochemical properties were analyzed. Their wavelength of maximun absorption was 526 nm and 506 nm in solution state, repectively, and 560 nm and 522 nm in film state, respectively. Their band-gap energy was 2.01 eV and 2.09 eV in solution state, and 1.82 eV and 1.91 eV in film state, respectively. The results of analysis of the chrateristics of photovoltaics, 0.79 % and 0.99 % of the maximum power conversion efficiencies (PCE), repectively.

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Preparation and characterization of novel immobilized Fe3O4@SiO2@mSiO2–Pd(0) catalyst with large pore-size mesoporous for Suzuki coupling reaction

Applied Catalysis A General ◽

10.1016/j.apcata.2013.04.010 ◽

2013 ◽

Vol 459 ◽

pp. 65-72 ◽

Cited By ~ 93

Author(s):

Wei Li ◽

Baoliang Zhang ◽

Xiangjie Li ◽

Hepeng Zhang ◽

Qiuyu Zhang

Keyword(s):

Pore Size ◽

Coupling Reaction ◽

Suzuki Coupling ◽

Suzuki Coupling Reaction ◽

Large Pore ◽

Large Pore Size

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Study on Synthesis and Properties of Novel HTPB/PEG Polyurethane Copolymers

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.66-68.170 ◽

2011 ◽

Vol 66-68 ◽

pp. 170-173 ◽

Cited By ~ 1

Author(s):

Yan Ling Luo ◽

Yan Miao ◽

Feng Xu

Keyword(s):

Microphase Separation ◽

Coupling Reaction ◽

Hydroxyl Groups ◽

Sequence Structure ◽

Reaction Route ◽

In Vitro Degradation ◽

Random Block ◽

Separation Degree ◽

Crystal Characterization

Two novel polyurethanes (PU) with alternating and random block architectures, hydroxyl-terminated polybutadiene (HTPB)/polyethylene glycol (PEG) block copolymers, HTPB-alt-PEG and HTPB-co-PEG, were synthesized via a coupling reaction route between hydroxyl groups and isocyanate groups. The structural and crystal characterization was conducted by means of FTIR, and phase behavior was examined by SEM and DSC. The biodegradation in a simulated human body fluid was investigated through mass loss and SEM. The experimental results indicate that all polyurethane samples form the microphase separation structure, and the separation degree depended on their sequence structure and the molecular weight (MW) of PEG, and further affecte their in-vitro degradation.

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