Role of water adsorption and salt content in atmospheric corrosion products of steel

1997 ◽  
Vol 39 (4) ◽  
pp. 815-820 ◽  
Author(s):  
F. Corvo ◽  
A.R. Mendoza ◽  
M. Autie ◽  
N. Betancourt
2019 ◽  
Vol 25 (37) ◽  
pp. 23-33 ◽  
Author(s):  
Zhenhua Dan ◽  
Izumi Muto ◽  
Nobuyoshi Hara

Author(s):  
Chicgoua Noubactep ◽  
Peter Volke ◽  
Broder Merkel ◽  
Günther Meinrath

Abstract This study was conducted to investigate the influence of iron corrosion products on the removal precipitation of uranium (VI) from aqueous solutions by zero valent iron (ZVI). Batch experiments were conducted with solutions containing 20 mg /L U(VI) (0.084 mM) at room temperature with washed and untreated scrap iron. The results show significant decrease of the immobilization efficiency of ZVI for uranium in the presence of both atmospheric corrosion products and those generated in situ. Among the relevant groundwater components, those who promote the iron corrosion e.g. SO42−, Cl− produce more corrosion products and have a stronger negative effect on the immobilization process. Carbonate ions also have a negative effect on the immobilization efficiency since they form stable complexes with uranium and reduce the adsorption on the iron surface which is the first step to immobilization. Humic substances didn’t show any negative effect but rather a slight enhancement of the immobilization rate. These results show that washing ZVI materials with hydrochloric acid before testing will overestimate their efficiency in practical use.


Author(s):  
Lumeng Liu ◽  
Wenmao Zeng ◽  
Shiliang Johnathan Tan ◽  
Meng Liu ◽  
Duong Do

Functional groups (FGs) in porous carbon play a pivotal role in water adsorption by nucleating water clusters followed by their coalescence, the process for which is the precursor for the...


1998 ◽  
Vol 145 (1) ◽  
pp. 39-44 ◽  
Author(s):  
T. Falk ◽  
J.‐E. Svensson ◽  
L.‐G. Johansson

2018 ◽  
Vol 4 (2) ◽  
Author(s):  
Maria F. Guerra

Abstract Gold alloys and silver alloys have always been widely employed in the production of significant objects. With high reflectivity, precious metals are perceived as both materials and colours, and can be skilfully combined to produce metallic polychrome effects. Because their structure and composition contain information on their manufacture, use, disclaim and degradation, items in gold and in silver enclose major information on the technologies employed by past societies and on exchange networks. This information can be acquired using appropriate analytical protocols, established according to the nature of the query and the characteristics of the objects. By using physicochemical techniques, it is possible to identify the technologies, materials and tools used by the artisan and, in particular cases, to situate the sources of raw materials and the workshops producing the objects, as well as to follow the trade routes. The aim of this work is to outline major achievements in the study of goldwork and silverwork based on the different physicochemical methods that are available, and to refer the analytical difficulties that have to be faced when studying objects made from precious metals. Based on several examples, three topics are addressed. The first concerns the major role of the techniques of exam when describing shaping, decorating, assembling and finishing; the second considers the search for metallic polychrome effects in some cultural areas; and the third discusses the challenging question of fingerprinting. A fourth section is dedicated to a short reflection on the difficulties related to the identification of the atmospheric corrosion mechanisms of precious metals.


1987 ◽  
Vol 65 (11) ◽  
pp. 2270-2275 ◽  
Author(s):  
Douglas A. Wilcox ◽  
Richard E. Andrus

Secondary succession of Sphagnum mosses was studied for 7 years along a belt transect in a bog that had been impacted by sodium chloride highway deicing salts. Laboratory studies on Sphagnum fimbriatum Wils., the dominant recolonizing species, were conducted to determine its salt tolerance level and ability to reproduce from spores and fragments across a salt gradient. Vegetative reproduction was also compared with that of four other recolonizing species. Sphagnum fimbriatum represented a high percentage of all recolonizing Sphagnum and generally began growing on low hummocks in quadrats where the salt content of the interstitial peat pore waters had dropped to about 300 mg/L as chloride. This salt concentration was also found to be the basic tolerance limit for mature plants and reproducing spores and fragments. The success of Sphagnum fimbriatum as a pioneer species seems to be associated with its prolific production and probable dispersal of spores, its superior vegetative reproduction, its tolerance of mineralized waters, and its ability to grow on hummocks out of direct contact with mineralized waters.


2020 ◽  
Vol 832 ◽  
pp. 137-146
Author(s):  
Monika Kubzová ◽  
Vit Křivý ◽  
Viktor Urban ◽  
Katerina Kreislova

This article deals with the topic of atmospheric corrosion. Atmospheric corrosion causes damage to nearly 80% of all existing steel structures. The main parameters of atmospheric corrosion are the time of wetness (TOW), air temperature and aggressive corrosive agents such as chlorides, sulfur dioxide and others. Currently, low alloy steels with improved atmospheric corrosion resistance called weathering steels are used for the steel structures located in outdoor environment. A protective layer of corrosion products is created on the steel surface and this layer can reduce continuation of corrosion of steel. The time of wetness together with the effect of aggressive corrosive agents are various for surfaces oriented vertically or horizontally. Experimental tests of atmospheric weathering steel were carried out to monitor the impact of location and position of surface on the different constructions. These tests allow monitoring the development of corrosion products in real exposures. The article presents a part of the research, which includes monitoring the development of the thickness of corrosion products with regard to the position on the structure. Research is developed to refine of prediction models with the aim of improving determination of corrosion losses during the service life of the structure. Second part of these experiments is dedicated to measuring the deposition rate of chlorides. Chlorides have a corrosive impact on the steel surface. Under normal conditions the chlorides does not create suitable environment for the development of a protective layer of corrosion products.


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