Gas chromatographic determination of nitrite in water by precolumn formation of 2-phenylphenol with flame ionization detection

1997 ◽  
Vol 760 (2) ◽  
pp. 319-325 ◽  
Author(s):  
Archana Jain ◽  
Roger M. Smith ◽  
Krishna K. Verma
1991 ◽  
Vol 71 (3) ◽  
pp. 915-921 ◽  
Author(s):  
Allan J. Cessna

In a 2-yr study, asparagus spears from established plantings at two sites in British Columbia and one site in Ontario were analyzed for terbacil residues following preemergence and early postemergence applications of terbacil at 0.6, 1.1 and 2.2 kg ha−1. Gas chromatographic determination of terbacil residues using N-specific alkali flame ionization detection indicated that at one site, maximum terbacil residues in the preemergence samples were 14 ± 3 μg kg−1 for the 2.2 kg ha−1 application rate, whereas maximum residues in the early postemergence samples for the 2.2 kg ha−1 application rate were 493 ± 250 μg kg−1 at a second site. Recoveries of terbacil from fortified asparagus tissue were 96 ± 19%, 87.2 ± 11.9% and 83.3 ± 7.8% at 10, 50 and 100 μg kg−1, respectively. Key words: Asparagus officinalis L., terbacil, residues, gas chromatography, asparagus


1983 ◽  
Vol 66 (6) ◽  
pp. 1528-1531 ◽  
Author(s):  
Hiroshi Nakanishi

Abstract A gas chromatographic procedure is described for determining monosodium glutamate (MSG) in several types of food. A sample is extracted with acetone- water (1 + 1). Acetone is evaporated and an aliquot of the extract is buffered with 1M NH4OH-1M NH4CI pH 9 solution, and chromatographed directly on a column of QAE Sephadex A-25 that has been pretreated with the same buffer. MSG is eluted with 0.1N HC1, and a portion of the eluate is evaporated to dryness and reacted with dimethylformamide( DMF)-dimethylacetal to form the glutamic acid derivative, which is injected into a gas chromatograph and measured by flame ionization detection. Recoveries of MSG from sample fortified at 5-500 mg ranged from 92.8 to 100%.


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