Use of solid phase extraction disks for the GC-MS analysis of acidic and neutral herbicides in drinking water

Chemosphere ◽  
1998 ◽  
Vol 36 (14) ◽  
pp. 2867-2878 ◽  
Author(s):  
T.S. Thompson ◽  
B.D. Miller
Keyword(s):  
Drinking Water ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Phase Extraction ◽  
Ms Analysis

scholarly journals Sensitive determination of gentamicin in plasma using ion-exchange solid-phase extraction followed by UHPLC-MS/MS analysis

2021 ◽  
pp. e00246
Author(s):  
Ana Laura Anibaletto dos Santos ◽  
Anne Caroline Cezimbra da Silva ◽  
Lilian de Lima Feltraco Lizot ◽  
Anelise Schneider ◽  
Roberta Zilles Hahn ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Phase Extraction ◽  
Ms Analysis ◽  
Sensitive Determination

Gas Chromatographic/Mass Spectrometric Confirmation of Leucomalachite Green in Catfish (Ictalurus punctatus) Tissue

1995 ◽  
Vol 78 (4) ◽  
pp. 971-977 ◽  
Author(s):  
Sherri B Turnipseed ◽  
José E Roybal ◽  
Jeffrey A Hurlbut ◽  
Austin R Long
Keyword(s):  
Solid Phase Extraction ◽  
Ictalurus Punctatus ◽  
Solid Phase ◽  
Mass Spectrometric ◽  
Phase Extraction ◽  
Neutral Alumina ◽  
Ms Analysis ◽  
Solid Phase Extraction Cartridge ◽  
Leucomalachite Green ◽  
Chromatographic Mass

Abstract A gas chromatographic/mass spectrometric (GC/MS) method was developed to confirm the presence of leucomalachite green (LMG), a metabolite of the triphenylmethane dye malachite green (MG), in catfish tissue. Residues were isolated according to a previously described liquid chromatographic (LC)A/IS spectrometric analysis of MG and LMG in fish. In our isolation procedure, analytes are extracted from tissue with acetonitrile–buffer, partitioned into CH2CI2, and applied to neutral alumina and propylsulfonic acid solid-phase extraction cartridges. Before GC/MS analysis, extracts prepared for the LC determinative method are eluted from a cyano solid-phase extraction cartridge, extracted into organic solvent, and concentrated for GC/MS analysis. Selected ion monitoring was performed by using 5 diagnostic ions (m/z 330,329,253,210, and 165) of LMG. The method was validated by confirming LMG in tissue fortified with mixtures of MG and LMG (5 and 10 ng/g each) and in tissue from fish that had been exposed to low levels of MG.

Graphene based pipette tip solid phase extraction of marine toxins in shellfish muscle followed by UPLC–MS/MS analysis

Talanta ◽  
2013 ◽  
Vol 116 ◽  
pp. 770-775 ◽  
Author(s):  
Qing Shen ◽  
Like Gong ◽  
Joewel T. Baibado ◽  
Wei Dong ◽  
Yixuan Wang ◽  
...  
Keyword(s):  
Solid Phase Extraction ◽  
Solid Phase ◽  
Phase Extraction ◽  
Marine Toxins ◽  
Ms Analysis ◽  
Pipette Tip

Solid-Phase Extraction Coupled to a Paper-Based Technique for Trace Copper Detection in Drinking Water

2018 ◽  
Vol 52 (6) ◽  
pp. 3567-3573 ◽  
Author(s):  
Casey W. Quinn ◽  
David M. Cate ◽  
Daniel D. Miller-Lionberg ◽  
Thomas Reilly ◽  
John Volckens ◽  
...  
Keyword(s):  
Drinking Water ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Phase Extraction ◽  
Copper Detection

scholarly journals Novel Chromatographic Separation and Carbon Solid-Phase Extraction of Acetanilide Herbicide Degradation Products

2002 ◽  
Vol 85 (6) ◽  
pp. 1331-1337 ◽  
Author(s):  
Jody A Shoemaker
Keyword(s):  
Drinking Water ◽  
Solid Phase Extraction ◽  
Chromatographic Separation ◽  
Solid Phase ◽  
Degradation Products ◽  
The United States ◽  
Negative Ion ◽  
Phase Extraction ◽  
Herbicide Degradation ◽  
Relative Standard

Abstract One acetamide and 5 acetanilide herbicides are currently registered for use in the United States. Over the past several years, ethanesulfonic acid (ESA) and oxanilic acid (OA) degradation products of these acetanilide/acetamide herbicides have been found in U.S. ground waters and surface waters. Alachlor ESA and other acetanilide degradation products are listed on the U.S. Environmental Protection Agency's (EPA) 1998 Drinking Water Contaminant Candidate List. Consequently, EPA is interested in obtaining national occurrence data for these contaminants in drinking water. EPA currently does not have a method for determining these acetanilide degradation products in drinking water; therefore, a research method is being developed using liquid chromatography/negative ion electrospray/mass spectrometry with solid-phase extraction (SPE). A novel chromatographic separation of the acetochlor/alachlor ESA and OA structural isomers was developed which uses an ammonium acetate–methanol gradient combined with heating the analytical column to 70°C. Twelve acetanilide degradates were extracted by SPE from 100 mL water samples using carbon cartridges with mean recoveries >90% and relative standard deviations ≤16%.

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