06/00846 Effect of pyrolysis pressure and heating rate on radiata pine char structure and apparent gasification reactivity

2006 ◽  
Vol 47 (2) ◽  
pp. 125
2017 ◽  
Vol 128 ◽  
pp. 13-17 ◽  
Author(s):  
Shenghua Zhu ◽  
Yonghui Bai ◽  
Kang Luo ◽  
Chenghao Hao ◽  
Weiren Bao ◽  
...  

2010 ◽  
Vol 6 (6) ◽  
pp. 905-911 ◽  
Author(s):  
Hao Liu ◽  
He Zhu ◽  
Liye Yan ◽  
Yongjun Huang ◽  
Shigeru Kato ◽  
...  

2000 ◽  
Vol 79 (11) ◽  
pp. 1078-1087 ◽  
Author(s):  
Chunhua LUO ◽  
Makoto NAKAMURA ◽  
Masaomi TOYODA ◽  
Shigeyuki UEMIYA ◽  
Toshinori KOJIMA

2010 ◽  
Vol 101 (20) ◽  
pp. 7935-7943 ◽  
Author(s):  
Mohammad Asadullah ◽  
Shu Zhang ◽  
Zhenhua Min ◽  
Piyachat Yimsiri ◽  
Chun-Zhu Li

2013 ◽  
Vol 295-298 ◽  
pp. 3110-3113
Author(s):  
Pei Wang ◽  
Wen Jian Zhu ◽  
Yong Hui Bai ◽  
Fan Li

The Yining char samples were prepared in following conditions that raw coal particle size was in range 5-6mm and pyrolysis final temperature was 900oC, 1000oC and 1100oC, respectively, with a heating rate 20oC/min under atmospheric pressure. The gasification reactivity of chars was performed by thermogravimetric analysis (TGA) at 900oC in steam, CO2 and steam/CO2 mixture, respectively. The results show that the gasification reactivity of chars decreases with the increasing of pyrolysis final temperatures and there is synergistic effect between steam and CO2 during co-gasification that influences the char reactivity. The reason may be explained by char structure change, which FTIR showed that –CH3 and –O–CH3 decreased and even disappeared and XRD analysis suggested that the thickness of microcrystalline Lc, the values of microcrystalline diameter La and the aromatic of char fa became larger with increasing pyrolysis temperature.


2012 ◽  
Vol 479-481 ◽  
pp. 586-589
Author(s):  
Dan Dan Hao ◽  
Wen Sheng Liu ◽  
Le Ping Dang ◽  
Hong Yuan Wei

At present, the CFD numerical simulation, combined with an experiments involving heat transfer has become an important approach to studying coal carbonization. The aim of this paper is to illustrate how a standard CFD package may be modified so it can be used to simulate temperature distribution, coking time and carbonization processes that occur in coke oven charge. Content of volatile matters and moisture have important influence on heating rate during carbonization. Further, heating rate have effects on char structure an inner coking condition, as well as the carbonization time. In addition, furnace wall temperature have important effects on carbonization, because they can change the coking time. Our simulation results for the coke oven model are in agreement with experimental and virtual data.


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