Quasi-crystalline grain-boundary phase in the magnesium die-cast alloy ZA85

2001 ◽  
Vol 45 (5) ◽  
pp. 517-524 ◽  
Author(s):  
M Vogel ◽  
O Kraft ◽  
G Dehm ◽  
E Arzt
Keyword(s):  
Grain Boundary ◽  
Cast Alloy ◽  
Boundary Phase ◽  
Die Cast

Examination of Fracture Interfaces in Silicon Nitride

1975 ◽  
Vol 33 ◽  
pp. 60-61
Author(s):  
Nancy J. Tighe
Keyword(s):  
Silicon Nitride ◽  
Grain Boundary ◽  
Crack Growth ◽  
Subcritical Crack Growth ◽  
Slow Crack Growth ◽  
Ceramic Materials ◽  
Grain Boundary Sliding ◽  
Boundary Phase ◽  
Turbine Engines ◽  
Boundary Sliding

Silicon nitride is one of the ceramic materials being considered for the components in gas turbine engines which will be exposed to temperatures of 1000 to 1400°C. Test specimens from hot-pressed billets exhibit flexural strengths of approximately 50 MN/m2 at 1000°C. However, the strength degrades rapidly to less than 20 MN/m2 at 1400°C. The strength degradition is attributed to subcritical crack growth phenomena evidenced by a stress rate dependence of the flexural strength and the stress intensity factor. This phenomena is termed slow crack growth and is associated with the onset of plastic deformation at the crack tip. Lange attributed the subcritical crack growth tb a glassy silicate grain boundary phase which decreased in viscosity with increased temperature and permitted a form of grain boundary sliding to occur.

Characterization of intergranular cuprous oxide in polycrystalline YBa2Cu3O7-x

1988 ◽  
Vol 46 ◽  
pp. 880-881
Author(s):  
Bradley L. Thiel ◽  
Chan Han R. P. ◽  
Kurosky L. C. Hutter ◽  
I. A. Aksay ◽  
Mehmet Sarikaya
Keyword(s):  
Grain Boundary ◽  
Cuprous Oxide ◽  
Room Temperature ◽  
Boundary Phase ◽  
Spectroscopic Techniques ◽  
Transition Width ◽  
Practical Applications ◽  
Thin Foils ◽  
Superconducting Oxides

The identification of extraneous phases is important in understanding of high Tc superconducting oxides. The spectroscopic techniques commonly used in determining the origin of superconductivity (such as RAMAN, XPS, AES, and EXAFS) are surface-sensitive. Hence a grain boundary phase several nanometers thick could produce irrelevant spectroscopic results and cause erroneous conclusions. The intergranular phases present a major technological consideration for practical applications. In this communication we report the identification of a Cu2O grain boundary phase which forms during the sintering of YBa2Cu3O7-x (1:2:3 compound).Samples are prepared using a mixture of Y2O3. CuO, and BaO2 powders dispersed in ethanol for complete mixing. The pellets pressed at 20,000 psi are heated to 950°C at a rate of 5°C per min, held for 1 hr, and cooled at 1°C per min to room temperature. The samples show a Tc of 91K with a transition width of 2K. In order to prevent damage, a low temperature stage is used in milling to prepare thin foils which are then observed, using a liquid nitrogen holder, in a Philips 430T at 300 kV.

Evaluations of antimony and strontium interaction in an Al–Si–Cu–Zn die cast alloy

2014 ◽  
Vol 584 ◽  
pp. 72-78 ◽  
Author(s):  
Saeed Farahany ◽  
Mohd Hasbullah Idris ◽  
Ali Ourdjini
Keyword(s):  
Cast Alloy ◽  
Die Cast

Long Term Creep Properties of a Die-Cast Mg-Al-Ca Alloy

2007 ◽  
Vol 561-565 ◽  
pp. 163-166
Author(s):  
Yoshihiro Terada ◽  
Tatsuo Sato
Keyword(s):  
Creep Rate ◽  
Magnesium Alloys ◽  
Cast Alloy ◽  
Rupture Life ◽  
Testing Temperature ◽  
Creep Rupture ◽  
Die Cast ◽  
Cast Magnesium Alloys ◽  
Term Creep ◽  
Cast Magnesium

Creep rupture tests were performed for a die-cast Mg-Al-Ca alloy AX52 (X representing calcium) at 29 kinds of creep conditions in the temperature range between 423 and 498 K. The creep curve for the alloy is characterized by a minimum in the creep rate followed by an accelerating stage. The minimum creep rate (ε& m) and the creep rupture life (trup) follow the phenomenological Monkman-Grant relationship; trup = C0 /ε& m m. It is found for the AX52 die-cast alloy that the exponent m is unity and the constant C0 is 2.0 x 10-2, independent of creep testing temperature. The values of m and C0 are compared with those for another die-cast magnesium alloys. The value m=1 is generally detected for die-cast magnesium alloys. On the contrary, the value of C0 sensitively depends on alloy composition, which is reduced with increasing the concentration of alloying elements such as Al, Zn and Ca.

Galvanic corrosion properties of differently PVD-treated magnesium die cast alloy AZ91

2005 ◽  
Vol 193 (1-3) ◽  
pp. 223-229 ◽  
Author(s):  
H. Hoche ◽  
C. Blawert ◽  
E. Broszeit ◽  
C. Berger
Keyword(s):  
Cast Alloy ◽  
Galvanic Corrosion ◽  
Corrosion Properties ◽  
Alloy Az91 ◽  
Die Cast

Grain Boundary Phase Segregation for Dramatic Improvement of the Thermoelectric Performance of Oxide Ceramics

2018 ◽  
Vol 10 (45) ◽  
pp. 39018-39024 ◽  
Author(s):  
Xueyan Song ◽  
Sergio A. Paredes Navia ◽  
Liang Liang ◽  
Cullen Boyle ◽  
Cesar-Octavio Romo-De-La-Cruz ◽  
...  
Keyword(s):  
Grain Boundary ◽  
Phase Segregation ◽  
Thermoelectric Performance ◽  
Boundary Phase ◽  
Dramatic Improvement ◽  
Oxide Ceramics

scholarly journals Microstructure and Magnetic Properties of NdFeB Sintered Magnets Diffusion-Treated with Cu/Al Mixed Dyco Alloy-Powder

2017 ◽  
Vol 62 (2) ◽  
pp. 1263-1266 ◽  
Author(s):  
M.-W. Lee ◽  
K.-H. Bae ◽  
S.-R. Lee ◽  
H.-J. Kim ◽  
T.-S. Jang
Keyword(s):  
Grain Boundary ◽  
Diffusion Path ◽  
Boundary Phase ◽  
Core Shell ◽  
Phase Layer ◽  
Sintered Magnets ◽  
The Core ◽  
Shell Type ◽  
Property Changes ◽  
And Diffusion

AbstractWe investigated the microstructural and magnetic property changes of DyCo, Cu + DyCo, and Al + DyCo diffusion-treated NdFeB sintered magnets. The coercivity of all diffusion treated magnet was increased at 880ºC of 1stpost annealing(PA), by 6.1 kOe in Cu and 7.0 kOe in Al mixed DyCo coated magnets, whereas this increment was found to be relatively low (3.9 kOe) in the magnet coated with DyCo only. The diffusivity and diffusion depth of Dy were increased in those magnets which were treated with Cu or Al mixed DyCo, mainly due to comparatively easy diffusion path provided by Cu and Al because of their solubility with Ndrich grain boundary phase. The formation of Cu/Al-rich grain boundary phase might have enhanced the diffusivity of Dy-atoms. Moreover, relatively a large number of Dy atoms reached into the magnet and mostly segregated at the interface of Nd2Fe14B and grain boundary phases covering Nd2Fe14B grains so that the core-shell type structures were developed. The formation of highly anisotropic (Nd, Dy)2Fe14B phase layer, which acted as the shell in the core-shell type structure so as to prevent the reverse domain movement, was the cause of enhancing the coercivity of diffusion treated NdFeB magnets. Segregation of cobalt in Nd-rich TJP followed by the formation of Co-rich phase was beneficial for the coercivity enhancement, resulting in the stabilization of the metastable c-Nd2O3phase.

Sign in / Sign up

Export Citation Format

Share Document