A comprehensive population balance model of emulsion polymerisation for PSD & MWD: Comparison to experimental data

Author(s):  
S.J. Sweetman ◽  
C.D. Immanuel ◽  
T.I. Malik ◽  
S. Emmett ◽  
N. Williams
Processes ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 1345
Author(s):  
Hassan Pouraria ◽  
Ki-Heum Park ◽  
Yutaek Seo

Formation of a dispersed oil—water flow pattern is a common occurrence in flow lines and pipelines. The capability of predicting the size of droplets, as well as the distribution of dispersed phase volume fraction is of utmost importance for proper design of such systems. The present study aims at modelling dispersed water in oil flows in a horizontal pipe by employing a multi-fluid Eulerian approach along with the population balance model. To this end, momentum and continuity equations are solved for oil and water phases, and the coupling between the phases is achieved by considering the drag, lift, turbulent dispersion, and virtual mass forces. Turbulent effects are modelled by employing the standard k-ε model. Furthermore, a population balance model, based on the method of class, along with the breakup and coalescence kernels is adopted for modelling the droplet size distribution. The obtained numerical results are compared to the experimental data in literature for either the in situ Sauter mean diameter or water volume fraction. A comparison among the obtained numerical results and the published experimental data shows a reasonable agreement.


2020 ◽  
pp. 014459872098361
Author(s):  
Zhongbao Wu ◽  
Qingjun Du ◽  
Bei Wei ◽  
Jian Hou

Foam flooding is an effective method for enhancing oil recovery in high water-cut reservoirs and unconventional reservoirs. It is a dynamic process that includes foam generation and coalescence when foam flows through porous media. In this study, a foam flooding simulation model was established based on the population balance model. The stabilizing effect of the polymer and the coalescence characteristics when foam encounters oil were considered. The numerical simulation model was fitted and verified through a one-dimensional displacement experiment. The pressure difference across the sand pack in single foam flooding and polymer-enhanced foam flooding both agree well with the simulation results. Based on the numerical simulation, the foam distribution characteristics in different cases were studied. The results show that there are three zones during foam flooding: the foam growth zone, stable zone, and decay zone. These characteristics are mainly influenced by the adsorption of surfactant, the gas–liquid ratio, the injection rate, and the injection scheme. The oil recovery of polymer-enhanced foam flooding is estimated to be 5.85% more than that of single foam flooding. Moreover, the growth zone and decay zone in three dimensions are considerably wider than in the one-dimensional model. In addition, the slug volume influences the oil recovery the most in the foam enhanced foam flooding, followed by the oil viscosity and gas-liquid ratio. The established model can describe the dynamic change process of foam, and can thus track the foam distribution underground and aid in optimization of the injection strategies during foam flooding.


2001 ◽  
Vol 27 (1) ◽  
pp. 63-71 ◽  
Author(s):  
S Sivakumar ◽  
Manjunath Subbanna ◽  
Satyam S Sahay ◽  
Vijay Ramakrishnan ◽  
P.C Kapur ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document