Effect of flotation fractions of long-flame coal on regulation of sulfur and coke reactivity during pyrolysis of high-sulfur coking coal

2021 ◽  
Vol 49 (7) ◽  
pp. 881-889
Author(s):  
Wen-guang LI ◽  
Yan-feng SHEN ◽  
Jiang GUO ◽  
Jiao KONG ◽  
Mei-jun WANG ◽  
...  
Keyword(s):  
Metals ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 61
Author(s):  
Asmaa A. El-Tawil ◽  
Bo Björkman ◽  
Maria Lundgren ◽  
Frida Bäck ◽  
Lena Sundqvist Ökvist

Substitution of coal in coking coal blend with bio-coal is a potential way to reduce fossil CO2 emissions from iron and steelmaking. The current study aims to explore possible means to counteract negative influence from bio-coal in cokemaking. Washing and kaolin coating of bio-coals were conducted to remove or bind part of the compounds in the bio-coal ash that catalyzes the gasification of coke with CO2. To further explore how the increase in coke reactivity is related to more reactive carbon in bio-coal or catalytic oxides in bio-coal ash, ash was produced from a corresponding amount of bio-coal and added to the coking coal blend for carbonization. The reaction behavior of coals and bio-coals under carbonization conditions was studied in a thermogravimetric analyzer equipped with a mass spectrometer during carbonization. The impact of the bio-coal addition on the fluidity of the coking coal blend was studied in optical dilatometer tests for coking coal blends with and without the addition of bio-coal or bio-coal ash. The result shows that the washing of bio-coal will result in lower or even negative dilatation. The washing of bio-coals containing a higher amount of catalytic components will reduce the negative effect on bio-coke reactivity, especially with acetic acid washing when the start of gasification temperature is less lowered. The addition of bio-coal coated with 5% kaolin do not significantly lower the dilatation-relative reference coking coal blend. The reactivity of bio-cokes containing bio-coal coated with kaolin-containing potassium oxide was higher in comparison to bio-coke containing the original bio-coal. The addition of ash from 5% of torrefied bio-coals has a moderate effect on lowering the start of gasification temperature, which indicates that the reactive carbon originating from bio-coal has a larger impact.


ACS Omega ◽  
2021 ◽  
Author(s):  
Wenguang Li ◽  
Yanfeng Shen ◽  
Jiang Guo ◽  
Jiao Kong ◽  
Meijun Wang ◽  
...  

Metals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1752
Author(s):  
Asmaa A. El-Tawil ◽  
Bo Björkman ◽  
Maria Lundgren ◽  
Astrid Robles ◽  
Lena Sundqvist Ökvist

Coke corresponds to 2/3–3/4 of the reducing agents in BF, and by the partial replacement of coking coals with 5–10% of bio-coal, the fossil CO2 emissions from the BF can be lowered by ~4–8%. Coking coal blends with 5% and 10% additions of bio-coals (pre-treated biomass) of different origins and pre-treatment degrees were carbonized at laboratory scale and with a 5% bio-coal addition at technical scale, aiming to understand the impact on the bio-coal properties (ash amount and composition, volatile matter content) and the addition of bio-coke reactivity. A thermogravimetric analyzer (TGA) connected to a quadrupole mass spectroscope monitored the residual mass and off-gases during carbonization. To explore the effect of bio-coal addition on plasticity, optical dilatometer tests were conducted for coking coal blends with 5% and 10% bio-coal addition. The plasticity was lowered with increasing bio-coal addition, but pyrolyzed biomass had a less negative effect on the plasticity compared to torrefied biomasses with a high content of oxygen. The temperature for starting the gasification of coke was in general lowered to a greater extent for bio-cokes produced from coking coal blends containing bio-coals with higher contents of catalyzing oxides. There was no significant difference in the properties of laboratory and technical scale produced coke, in terms of reactivity as measured by TGA. Bio-coke produced with 5% of high temperature torrefied pelletized biomass showed a similar coke strength as reference coke after reaction.


2017 ◽  
Vol 155 ◽  
pp. 97-105 ◽  
Author(s):  
Bruno D. Flores ◽  
Ismael V. Flores ◽  
Adrià Guerrero ◽  
Daniel R. Orellana ◽  
Juliana G. Pohlmann ◽  
...  
Keyword(s):  

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 575
Author(s):  
Ze Zhang ◽  
Shuting Zhang

To improve indirect drying efficiency, the effect of soda residue on the drying characteristics of coking coal were studied using a self-made indirect drying system. A tube furnace was used in the dry distillation of coal samples with soda residue, and the coke properties were analyzed. The results indicated that the soda residue has a significant influence on the increase in the heating rate of coal samples in the temperature distribution range of 90 to 110 °C. With the addition of 2%, 5%, and 10% soda residue, the drying rates increased by 11.5%, 25.3%, and 37.3%, respectively at 110 °C. The results of dry distillation show that addition of 2%, 5% and 10% soda residue decreases the carbon loss quantity by 4.67, 4.99, and 8.82 g, respectively. The mechanical strength of coke samples satisfies the industrial conditions when the soda residue ratio ranges from 2% to 5%. Soda residue can improve the active point of coke dissolution reaction and inhibit coke internal solution. Economically, coking coal samples mixed with soda residue have an obvious energy saving advantage in the drying process. Energy saving analysis found that it can reduce cost input by 20% than that of the normal drying method.


2021 ◽  
Vol 10 (1) ◽  
pp. 189-200
Author(s):  
Yuan She ◽  
Chong Zou ◽  
Shiwei Liu ◽  
Keng Wu ◽  
Hao Wu ◽  
...  

Abstract Thermoanalysis was used in this research to produce a comparative study on the combustion and gasification characteristics of semi-coke prepared under pyrolytic atmospheres rich in CH4 and H2 at different proportions. Distinctions of different semi-coke in terms of carbon chemical structure, functional groups, and micropore structure were examined. The results indicated that adding some reducing gases during pyrolysis could inhibit semi-coke reactivity, the inhibitory effect of the composite gas of H2 and CH4 was the most observable, and the effect of H2 was higher than that of CH4; moreover, increasing the proportion of reducing gas increased its inhibitory effect. X-ray diffractometer and Fourier-transform infrared spectrometer results indicated that adding reducing gases in the atmosphere elevated the disordering degree of carbon microcrystalline structures, boosted the removal of hydroxyl- and oxygen-containing functional groups, decreased the unsaturated side chains, and improved condensation degree of macromolecular networks. The nitrogen adsorption experiment revealed that the types of pore structure of semi-coke are mainly micropore and mesopore, and the influence of pyrolytic atmosphere on micropores was not of strong regularity but could inhibit mesopore development. Aromatic lamellar stack height of semi-coke, specific surface area of mesopore, and pore volume had a favorable linear correlation with semi-coke reactivity indexes.


2021 ◽  
pp. 1-12
Author(s):  
Pinaki Sarkar ◽  
Santi G. Sahu ◽  
Omkar S. Patange ◽  
Amit Garg ◽  
Ashis Mukherjee ◽  
...  

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