Iron Formations as Palaeoenvironmental Archives

2021 ◽  
Author(s):  
Kaarel Mänd ◽  
Leslie J. Robbins ◽  
Noah J. Planavsky ◽  
Andrey Bekker ◽  
Kurt O. Konhauser

Ancient iron formations - iron and silica-rich chemical sedimentary rocks that formed throughout the Precambrian eons - provide a significant part of the evidence for the modern scientific understanding of palaeoenvironmental conditions in Archaean (4.0–2.5 billion years ago) and Proterozoic (2.5–0.539 billion years ago) times. Despite controversies regarding their formation mechanisms, iron formations are a testament to the influence of the Precambrian biosphere on early ocean chemistry. As many iron formations are pure chemical sediments that reflect the composition of the waters from which they precipitated, they can also serve as nuanced geochemical archives for the study of ancient marine temperatures, redox states, and elemental cycling, if proper care is taken to understand their sedimentological context.

PalZ ◽  
2021 ◽  
Author(s):  
Carolin L. Dreher ◽  
Manuel Schad ◽  
Leslie J. Robbins ◽  
Kurt O. Konhauser ◽  
Andreas Kappler ◽  
...  

AbstractBanded Iron Formations (BIFs) are marine chemical sediments consisting of alternating iron (Fe)-rich and silica (Si)-rich bands which were deposited throughout much of the Precambrian era. BIFs represent important proxies for the geochemical composition of Precambrian seawater and provide evidence for early microbial life. Iron present in BIFs was likely precipitated in the form of Fe3+ (Fe(III)) minerals, such as ferrihydrite (Fe(OH)3), either through the metabolic activity of anoxygenic photoautotrophic Fe2+ (Fe(II))-oxidizing bacteria (photoferrotrophs), by microaerophilic bacteria, or by the oxidation of dissolved Fe(II) by O2 produced by early cyanobacteria. However, in addition to oxidized Fe-bearing minerals such as hematite (FeIII2O3), (partially) reduced minerals such as magnetite (FeIIFeIII2O4) and siderite (FeIICO3) are found in BIFs as well. The presence of reduced Fe in BIFs has been suggested to reflect the reduction of primary Fe(III) minerals by dissimilatory Fe(III)-reducing bacteria, or by metamorphic (high pressure and temperature) reactions occurring in presence of buried organic matter. Here, we present the current understanding of the role of Fe-metabolizing bacteria in the deposition of BIFs, as well as competing hypotheses that favor an abiotic model for BIF deposition. We also discuss the potential abiotic and microbial reduction of Fe(III) in BIFs after deposition. Further, we review the availability of essential nutrients (e.g. P and Ni) and their implications on early Earth biogeochemistry. Overall, the combined results of various ancient seawater analogue experiments aimed at assessing microbial iron cycling pathways, coupled with the analysis of the BIF rock record, point towards a strong biotic influence during BIF genesis.


1994 ◽  
Vol 58 (392) ◽  
pp. 387-399 ◽  
Author(s):  
Peter L. McSwiggen ◽  
G. B. Morey ◽  
Jane M. Cleland

AbstractThe recent discovery of hyalophane [(K,Ba)Al1−2Si3−2O8] on the North range segment of the Early Proterozoic Cuyuna Iron Range of east-central Minnesota has shed new light on the depositional environment of these rocks. This Ba-feldspar occurs in a 10 m thick interval within the main iron-formation and typically contains between 8 and 26 mol.% celsian (BaAl2Si2O8). Its occurrence in several textural settings suggests that barium was being deposited at various stages in the paragenetic history of the iron-formation. Some of the hyalophane grains occur as the cores of micronodules, which are structurally similar to oolites or oncolites, but mineralogically are very complex. The hyalophane also occurs as rims on core grains of diverse mineral composition and as discrete phases in late crosscutting veins.Hyalophane, like other Ba-silicates, has a very restricted paragenesis. They are associated typically either with sedimentary manganese and ferromanganese deposits, or with Cu-Pb-Zn-Ba deposits. The presence of hyalophane in the Early Proterozoic manganiferous iron ores of east-central Minnesota casts doubt on the historic interpretation of these deposits as typical Superior-type sedimentary iron-formations and instead supports the view that these deposits, at least in part, consist of chemical sediments from a hydrothermal fumarolic system. The suggested involvement of a hydrothermal system is also supported by the occurrence of aegirine within the hyalophane-rich layer, and the occurrence of tourmalinites and Sr-rich baryte veins elsewhere in the Cuyuna North range.


2019 ◽  
pp. 28-36 ◽  
Author(s):  
Helena Yu. Lekus

Humanisation of public spaces is an important part of development strategies for a modern city. Design of a luminous environment plays a significant part in this process. We can see a correlation between the existing examples of humanoriented lighting of spaces and the scientific understanding of humanism. This helps us set a goal of space humanisation, select specific tasks that are solved by humanised public spaces, and define factors influencing humanistic quality of the environment at the phase of lighting design.


1998 ◽  
Vol 135 (5) ◽  
pp. 637-655 ◽  
Author(s):  
SHAOCHENG JI ◽  
ZHEMING ZHU ◽  
ZICHAO WANG

This paper consists of three parts. The first part presents a critical review of previous mechanical models on the relationship between joint spacing (s) and bed thickness (t) in sedimentary rocks. The second part describes a new mechanical model dealing with the effects of interbed slip on joint spacing. The third part presents the comparison between theoretical results of the model and joint data measured from Cambrian flysch sediments at Plage Victor in the Saint-Jean-Port-Joli area of the Quebec Appalachians. This study demonstrates two formation mechanisms of tensile joints: near-end fracturing takes place in the layers with smaller tensile fracture strength (C0<30 MPa) and smaller interbed shear strength (τ0<20 MPa) while mid-point fracturing occurs in those layers with larger C0 (>50 MPa) and τ0(>30 MPa) values. For the rocks with moderate tensile fracture strength (30<C0<50 MPa) and interbed shear strength (20<τ0<30 MPa), the near-end fracturing and mid-point fracturing take place preferentially in the thicker and thinner brittle layers, respectively. In the regime of near-end fracturing, the correlation between s and t is linear and independent of the thickness of the bounding non-jointing layers (d). In the regime of mid-point fracturing, however, the s–t relationship can be either linear or non-linear, depending on the variation of d value. The present study also suggests that the near-end fracturing is probably the prevailing process for the formation of tensile joints in bedded sedimentary rocks and that the coefficient of joint spacing (K) defined by the ratio of s to t is considered as an indicator of C0/(2τ0) for the jointed layer.


2020 ◽  
Author(s):  
Jean-Baptiste P. Koehl

Abstract. The present study of field, petrological, exploration well and seismic data shows that backward-dipping duplexes comprised of phyllitic coal and bedding-parallel décollements and thrusts, which localized along lithological transitions in tectonically thickened Lower–lowermost Upper Devonian, uppermost Devonian–Mississippian and uppermost Pennsylvanian–lowermost Permian sedimentary strata of the Wood Bay and/or Widje Bay and/or Grey Hoek formations, of the Billefjorden Group and of the Wordiekammen Formation respectively, partially decoupled uppermost Devonian–Permian sedimentary rocks of the Billefjorden and Gipsdalen groups from Lower–lowermost Upper Devonian rocks of the Andrée Land Group and Mimerdalen Subgroup during early Cenozoic Eurekan deformation in central Spitsbergen. Eurekan strain decoupling along these structures explains differential deformation between Lower–lowermost Upper Devonian rocks of the Andrée Land Group/Mimerdalen Subgroup and overlying uppermost Devonian–Permian sedimentary strata of the Billefjorden and Gipsdalen groups in central–northern Spitsbergen without requiring an episode of (Ellesmerian) contraction in the Late Devonian. Potential formation mechanisms for bedding-parallel décollements and thrusts include shortcut faulting, and/or formation as a roof décollement in a fault-bend hanging wall (or ramp) anticline, as an imbricate fan, as an antiformal thrust stack, and/or as fault-propagation folds over reactivated/overprinted basement-seated faults. The interpretation of seismic data in Reindalspasset indicates that Devonian sedimentary rocks of the Andrée Land Group and Mimerdalen Subgroup might be preserved east of the Billefjorden Fault Zone, suggesting that the Billefjorden Fault Zone did not accommodate reverse movement in the Late Devonian. Hence, the thrusting of Proterozoic basement rocks over Lower Devonian sedimentary rocks along the Balliolbreen Fault and fold structures within strata of the Andrée Land Group and Mimerdalen Subgroup in central Spitsbergen may be explained by a combination of down-east Carboniferous normal faulting with associated footwall rotation and exhumation, and subsequent top-west early Cenozoic Eurekan thrusting along the Billefjorden Fault Zone. Finally, the study shows that major east-dipping faults, like the Billefjorden Fault Zone, may consists of several, discrete, unconnected (soft-linked and/or stepping) or, most probably, offset fault segments that were reactivated/overprinted with varying degree during Eurekan deformation due to strain partitioning and/or decoupling along sub-orthogonal NNE-dipping reverse faults.


1976 ◽  
Vol 13 (9) ◽  
pp. 1161-1185 ◽  
Author(s):  
Erich Dimroth ◽  
Michael M. Kimberley

The sedimentary distributions of carbon, sulfur, uranium, and ferric and ferrous iron depend greatly upon ambient oxygen pressure and should reflect any major change in proportion of oxygen in the atmosphere or hydrosphere. The similar distributions of these elements in sedimentary rocks of all ages are here interpreted to indicate the existence of a Precambrian atmosphere containing much oxygen.Organic carbon contents and distributions are similar in Precambrian and Quaternary sedimentary rocks and sediments, although distributions in both would have been sensitive to variations in rates of organic productivity and atmospheric oxygen pressure. Sedimentary pyrite is almost invariably closely associated with organic carbon, suggestive of formation by sulfate reduction, in sedimentary rocks of any age. Archean and Middle Precambrian cherty iron formations and uranium ores resemble Phanerozoic ores and probably formed similarly by diagenetic concentration. In general, we find no evidence in the sedimentary distributions of carbon, sulfur, uranium, or iron, that an oxygen-free atmosphere has existed at any time during the span of geological history recorded in well preserved sedimentary rocks.


1972 ◽  
Vol 9 (6) ◽  
pp. 652-663 ◽  
Author(s):  
B. J. Fryer

Rb-Sr whole-rock isochron studies on volcanic and sedimentary rocks from the Belcher Fold Belt in Hudson Bay, and sedimentary rocks from the Labrador Trough and the Lake Mistassini area of Quebec, yield ages of 1800, 1870, and 1790 m.y., respectively. These age determinations substantiate previous correlations between these areas based on stratigraphic and structural similarities. Consequently, the concept of a Circum – Ungava Geosyncline appears to be valid on geochronological grounds, with geosynclinal development terminating with the onset of the Hudsonian orogeny at about 1800 m.y.The Circum – Ungava Geosyncline contains banded iron-formations exhibiting shallow-water sedimentary structures which distinguish them from older banded iron-formations. These deposits probably represent the hydrospheric response to the initial large scale introduction of oxygen to the atmosphere by evolving life forms. Because of their probable unique nature these younger banded iron-formations may serve as a valuable marker horizon for global correlations of Proterozoic strata.


Solid Earth ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 1025-1049
Author(s):  
Jean-Baptiste P. Koehl

Abstract. The present study of field, petrological, exploration well, and seismic data describes backward-dipping duplexes comprised of phyllitic coal and bedding-parallel décollements and thrusts localized along lithological transitions in tectonically thickened Lower Devonian to lowermost Upper Devonian; uppermost Devonian–Mississippian; and uppermost Pennsylvanian–lowermost Permian sedimentary strata of the Wood Bay and/or Wijde Bay and/or Grey Hoek formations; of the Billefjorden Group; and of the Wordiekammen Formation, respectively. The study shows that these structures partially decoupled uppermost Devonian–Permian sedimentary rocks of the Billefjorden and Gipsdalen groups from Lower Devonian to lowermost Upper Devonian rocks of the Andrée Land Group and Mimerdalen Subgroup during early Cenozoic Eurekan deformation in central Spitsbergen. Eurekan strain decoupling along these structures explains differential deformation between Lower Devonian to lowermost Upper Devonian rocks of the Andrée Land Group and/or Mimerdalen Subgroup and overlying uppermost Devonian–Permian sedimentary strata of the Billefjorden and Gipsdalen groups in central–northern Spitsbergen without requiring an episode of (Ellesmerian) contraction in the Late Devonian. Potential formation mechanisms for bedding-parallel décollements and thrusts include shortcut faulting and/or formation as a roof décollement in a fault-bend hanging wall (or ramp) anticline, as an imbricate fan, as an antiformal thrust stack, and/or as fault-propagation folds over reactivated or overprinted basement-seated faults. The interpretation of seismic data in Reindalspasset indicates that Devonian sedimentary rocks of the Andrée Land Group and Mimerdalen Subgroup might be preserved east of the Billefjorden Fault Zone, suggesting that the Billefjorden Fault Zone did not accommodate reverse movement in the Late Devonian. Hence, the thrusting of Proterozoic basement rocks over Lower Devonian sedimentary rocks along the Balliolbreen Fault and fold structures within strata of the Andrée Land Group and Mimerdalen Subgroup in central Spitsbergen may be explained by a combination of down-east Carboniferous normal faulting with associated footwall rotation and exhumation, and subsequent top-west early Cenozoic Eurekan thrusting along the Billefjorden Fault Zone. Finally, the study shows that major east-dipping faults, like the Billefjorden Fault Zone, may consist of several discrete, unconnected (soft-linked and/or stepping) or, most probably, offset fault segments that were reactivated or overprinted to varying degrees during Eurekan deformation due to strain partitioning and/or decoupling along sub-orthogonal NNE-dipping reverse faults.


1978 ◽  
Vol 73 (6) ◽  
pp. 1167-1170 ◽  
Author(s):  
K. A. Harmon ◽  
D. M. Shaw ◽  
J. H. Crocket

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