Iron Formations as Palaeoenvironmental Archives

Ancient iron formations - iron and silica-rich chemical sedimentary rocks that formed throughout the Precambrian eons - provide a significant part of the evidence for the modern scientific understanding of palaeoenvironmental conditions in Archaean (4.0–2.5 billion years ago) and Proterozoic (2.5–0.539 billion years ago) times. Despite controversies regarding their formation mechanisms, iron formations are a testament to the influence of the Precambrian biosphere on early ocean chemistry. As many iron formations are pure chemical sediments that reflect the composition of the waters from which they precipitated, they can also serve as nuanced geochemical archives for the study of ancient marine temperatures, redox states, and elemental cycling, if proper care is taken to understand their sedimentological context.

Weathering events recorded in uppermost Hauterivian–lower Barremian clay-dominated continental successions from the NW Iberian Range: climatic vs. tectonic controls

The facies and clay mineral study of clay/marl-rich levels from the Torrelapaja Formation (latest Hauterivian–early Barremian, NW Iberian Range, NE Spain) allowed to establish the palaeoclimatic and palaeoenvironmental conditions under they were generated. The muddy levels and pisoids contained therein of two logs were sampled and studied by X-ray diffraction and optical and electron microscopy. A similar mineralogical upwards trend is recorded in both logs, with a decrease in calcite coupled with an increase in quartz and orthoclase content and constant proportions in goethite, hematite, diaspore, anatase, rutile, ilmenite, and clay mineral content. The lower muddy levels have higher kaolinite content than the upper levels, where illitic phases are the dominant clay minerals. Smectite and intergrowths of illitic phases and kaolinite are also detected upwards. The kaolinite and smectite textures indicate an authigenic origin, whereas the illitic phases are former phases acting as a substrate for kaolinite crystallization. Pisoids mineralogy and texture show an in-situ origin, but some are fractured, indicating reworking processes. The mineral association found in the muddy levels is characteristic of oxisols formed under warm and humid conditions. The upward decrease in kaolinite content is coeval with an increase in the illitic phases and quartz content, related to siliciclastic input, but is also coeval with the presence of authigenic smectite. This indicates a decrease in chemical weathering, not fully registered due to the siliciclastic contribution, which was possibly associated with a change to colder, drier conditions during the latest Hauterivian–early Barremian in the studied area.

Diversity and Ecology of Diatoms in Pliocene Deposits of the Tunka Valley (Baikal Rift Zone)

Fossil diatoms are an excellent tool for reconstructing the palaeoenvironmental and palaeogeographic changes involving lacustrine systems. In this work, the diatom content of Pliocene sediments recovered from a core extracted in the Tunka Basin (Baikal Rift Zone, Russia) is described. Revealed by light and scanning electron microscopy, 170 species of diatoms were found. Benthic, alkaliphilic, indifferent, cosmopolitan, and oligosaprobe species predominated. Ecological, geographical, and stratigraphic analysis of diatoms showed two ecozones, differing in taxonomic diversity of species. From the data obtained, palaeoenvironmental conditions of these zone formations have been reconstructed. It was shown that during the period corresponding to sedimentation in Ecozone II, the reservoir was cooler, as suggested by the increase of arctic-alpine taxa. The absence of Baikal Pliocene endemics and the presence of local endemics in the Tunka core indicate that there was no geographical connection between the palaeolake of the Tunka Valley and Lake Baikal during the Pliocene.

Cladocera from the Sediment of High Arctic Lake in Svalbard (Norway)

The High Arctic Region’s freshwater ecosystems serve as hot spots to study the impact of extreme warming conditions on the biota. The cladoceran remains have been recovered from the surface sediments of a non-marine water body near Ny-Alesund, Svalbard, Norway. The cladoceran (crustaceans) belongs to the Chydorus sphaericus group Frey, 1980 and Daphnia pulex Leydig, 1860. The ecology of the species suggests that they lived in a well-developed ecosystem with Water Quality Class 3. This study has implications for understanding the response of the present-day biota experiencing the changing climate conditions and using these remains for assessing palaeoenvironmental conditions.

Another thermophilic "Miocene survivor" from the Italian Pliocene: A geologically young occurrence of the pelagic eagle ray Aetobatus in the Euro-Mediterranean region

Aetobatus (Myliobatiformes: Aetobatidae) is a living genus of eagle rays that occurs in shallow-marine, tropical and subtropical environments of the Atlantic, Pacific, and Indian Oceans. Nowadays, Aetobatus does not inhabit the cool- to warm-temperate European and Mediterranean waters, though it is known from this broad region by virtue of several fossil teeth ranging chronostratigraphically from the lower Palaeogene to the upper Neogene. The present paper reports on a fossil aetobatid tooth discovered in mid-Pliocene (upper Zanclean to lower Piacenzian, 3.82-3.19 Ma) marine deposits exposed in the vicinities of Certaldo (Tuscany, Italy) and identified as belonging to †Aetobatus cf. cappettai. This specimen comprises the youngest occurrence of Aetobatus along the coasts of mainland Europe; furthermore, together with previous finds from roughly coeval deposits of Mallorca (Balearic Islands, Spain), it represents the most recent record of this genus in the whole Euro-Mediterranean region. In light of the environmental preferences of extant Aetobatus spp., our discovery suggests palaeoenvironmental conditions favourable to the persistence of tropical/subtropical taxa of "Miocene survivors" along the Pliocene coasts of Tuscany. In addition, it raises the question of whether or not the Messinian Salinity Crisis really resulted in the complete collapse of the Mediterranean marine biota and in the subsequent recolonisation of the Mediterranean Basin from the adjoining Atlantic waters and/or scattered marginal intrabasinal refugia at the beginning of the Pliocene. The possibility of Aetobatus recolonising the Mediterranean Sea through the Suez Canal in the near future is discussed.

A multimethod dating study of ancient permafrost, Batagay megaslump, east Siberia

Dating of ancient permafrost is essential for understanding long-term permafrost stability and interpreting palaeoenvironmental conditions but presents substantial challenges to geochronology. Here, we apply four methods to permafrost from the megaslump at Batagay, east Siberia: (1) optically stimulated luminescence (OSL) dating of quartz, (2) post-infrared infrared-stimulated luminescence (pIRIR) dating of K-feldspar, (3) radiocarbon dating of organic material, and (4) 36Cl/Cl dating of ice wedges. All four chronometers produce stratigraphically consistent and comparable ages. However, OSL appears to date Marine Isotope Stage (MIS) 3 to MIS 2 deposits more reliably than pIRIR, whereas the latter is more consistent with 36Cl/Cl ages for older deposits. The lower ice complex developed at least 650 ka, potentially during MIS 16, and represents the oldest dated permafrost in western Beringia and the second-oldest known ice in the Northern Hemisphere. It has survived multiple interglaciations, including the super-interglaciation MIS 11c, though a thaw unconformity and erosional surface indicate at least one episode of permafrost thaw and erosion occurred sometime between MIS 16 and 6. The upper ice complex formed from at least 60 to 30 ka during late MIS 4 to 3. The sand unit above the upper ice complex is dated to MIS 3–2, whereas the sand unit below formed at some time between MIS 4 and 16.

Impacts of vegetation and palaeohydrological changes on the n-alkane composition of a Holocene peat sequence from the Upper Vistula Valley (southern Poland)

Purpose The analysis of n-alkanes in palaeoenvironmental studies of peatlands is mainly limited to ombrogenous peatlands which are a rare feature in the environment. Using n-alkane and plant macrofossil analysis, we have tracked changes in the environment in the valley of a large Central European river. We tested the possibilities for applying such studies to low-moor bogs which are the most commonly occurring type of bog in the world. Materials and methods Representative peat samples were taken from two profiles in a peatland located in the Vistula Valley (southern Poland), and they were analysed for the occurrence and distribution of biomarkers. The distribution of n-alkanes was determined using gas chromatography-mass spectrometry (GC–MS). The botanical composition of the samples was determined by analysis of plant macrofossil remains, and the degree of peat decomposition was also determined. Results and discussion Samples of low-moor peat were characterised by a prevalence of medium- and long-chain n-alkane homologues, which is typical for higher plants. The variable values of the CPI, CPI (25–31), and the C23/C25 ratio have provided information on the stages of formation of the Zapadź bog. The source of n-alkane differentiation is vegetation change related to palaeohydrological dynamics and palaeoenvironmental conditions within the peatland. Conclusions We have shown that analysis of n-alkanes can be successfully used in low-moor bogs as a complement to palaeobotanical and palaeozoological methods. The bringing together of these types of research enables changes in the ecosystems of large river valleys to be tracked.

Eocene to Oligocene nannofossils stratigraphy and environmental conditions in Izeh Province, Zagros Basin, East Tethys

Data obtained from the calcareous nannofossils, distributed in the upper part of the Pabdeh Formation (Priabonian–Rupelian) and the lower part of the Asmari Formation (Chattian) in the Bid-Zard section, were used to investigate the Eocene to Oligocene palaeoenvironmental conditions in the southwest of Izeh, southwestern Iran (eastern Tethys). The upper part of the Pabdeh Formation was composed of shale, thin-bedded pelagic limestone and dolostone, which is disconformably overlain by the Asmari Formation. For the first time, 29 species of calcareous nannofossils belonging to 13 genera were identified in the studied section. The calcareous nannofossils in the upper part of the Pabdeh Formation indicate the Isthmolithus recurvus Zone/Sphenolithus pseudoradians Zone (combined zone), Ericsonia subdisticha Zone, Helicosphaera reticulata Zone and Sphenolithus praedistentus Zone, from the Priabonian to the Rupelian. The Sphenolithus ciperoensis Zone of the Chattian was identified in the lower part of the Asmari Formation. Calcareous nannofossil stratigraphy across the upper Eocene–Oligocene interval also reveals a disconformity at the Rupelian/Chattian transition due to a bio-event. Shallowing of the basin and environmental changes in this part of the Tethyan domain could have led to the lithostratigraphic and biostratigraphic changes. In fact, during the late Eocene to late Oligocene, marine phytoplankton was sensitive to climate changes such as decreasing temperature, as well as possibly to a nutrient increase and changes in basin depth.

Geochemical and sedimentological responses of Arctic glacial Lake Ilirney, Chukotka (Far East Russia) to palaeoenvironmental change since ~ 51.8 ka BP

<p>Palaeoenvironmental reconstructions with temporal coverages extending beyond Marine Isotope Stage (MIS) three are scarce within the data sparse region of Chukotka, Far East Russia. The objective of this work was to infer palaeoenvironmental variability from a 10.76 m long, radiocarbon and OSL dated sediment core from Lake Ilirney, Chukotka (67°21´N, 168°19´E). We performed acoustic sub-bottom profiling of the lake basin and analysed high-resolution elements (XRF), organic carbon (TC, TN, TOC), grain-size, mineralogy (XRD) and partly also diatoms and pollen from the core. Our results affirm the application of XRF-based sediment-geochemical proxies as effective tracers of palaeoenvironmental variability within arctic lake systems. Our work reveals that a lake formed during MIS 3 from ca. 51.8 ka BP, following an extensive MIS 4 glaciation in the Ilirney valley. Catchment palaeoenvironmental conditions during this time likely remained cold associated with the continued presence of a catchment glacier until ca. 36.2 ka BP. Partial amelioration reflected by increased diatom, catchment vegetation and lake organic productivity and clastic sediment input from mixed sources from ca. 36.2 ka BP potentially resulted in a lake high-stand ~15 m above the present level and may represent evidence of a more productive palaeoenvironment overlapping in timing with the MIS 3 interstadial optimum. A transitional period of deteriorating palaeoenvironmental conditions occurred ca. 30- 27.9 ka BP and was superseded by periglacial-glacial conditions from ca. 27.9 ka BP, during MIS 2. Deglaciation as marked by sediment-geochemical proxies commenced ca. 20.2 ka BP. Our findings are compared with lacustrine, Yedoma and river-bluff records from across Beringia and potentially yield limited support for a marked Younger Dryas cooling in the study area.</p>