Electron diffraction study of hydrogenated amorphous SiC

Author(s):  
R. L. Sabatini ◽  
F. J. Kampas ◽  
P. E. Vanier ◽  
J. Taftø

Hydrogenated amorphous SiC (a-SiC:H) is a promising new solar cell material. In constrast to structural studies of amorphous Si and amorphous C, studies of amorphous SiC are rare. The main features of the diffraction patterns of amorphous Silicon and amorphous Carbon are two diffuse halos which for Si correspond to interatomic distances of about 2.35 Å and 3.85 Å and for C to 1.50 Å and 2.50 Å. These distances are close to the nearest interatomic distances present in the crystalline form of the same elements.Using 120 KeV electrons, we observe two pronounced halos also for a-SiC:H, similar to what is observed for pure Si and pure C. Figure 1 shows diffraction patterns from a-SiC:H and for comparison from Si and C.

1990 ◽  
Vol 192 ◽  
Author(s):  
Y. Takeuchi ◽  
K. Nomoto ◽  
G. Ganguly ◽  
A. Matsuda

ABSTRACTHighly conductive B-doped hydrogenated amorphous Si (a-Si:H) as well as amorphous SiC alloys (a-SiC:H) have been prepared from (SiH4) / (B2H6/SiH4) and (SiH4/CH4)/(B2H6/SiH4) plasmas, respectively by a novel surface-temperature-modulation method. Films produced by this technique exhibit a higher conductivity as compared to the conventionally prepared films, i.e., 7.0×l0−3scm−l for p-type a-Si:H with an optical gap of 1.7eV and 5.5×l0−5Scm−l for p-type a-SiC:H of optical gap 1.9eV.


1977 ◽  
Vol 45 (1) ◽  
pp. 43-46 ◽  
Author(s):  
D.E. Carlson ◽  
J.I. Pankove ◽  
C.R. Wronski ◽  
P.J. Zanzucchi

2011 ◽  
Vol 1321 ◽  
Author(s):  
Bill Nemeth ◽  
Yueqin Xu ◽  
Haorong Wang ◽  
Ted Sun ◽  
Benjamin G. Lee ◽  
...  

ABSTRACTWe apply a thin luminescent downshifting (LDS) coating to a hydrogenated amorphous Si (a-Si:H) solar cell and study the mechanism of possible current enhancement. The conversion material used in this study converts wavelengths below 400 nm to a narrow line around 615 nm. This material is coated on the front of the glass of the a-Si:H solar cell with a glass/TCO/p/i/n/Ag superstrate configuration. The initial efficiency of the solar cell without the LDS coating is above 9.0 % with open circuit voltage of 0.84 V. Typically, the spectral response below 400 nm of an a-Si:H solar cell is weaker than that at 615 nm. By converting ultraviolet (UV) light to red light, the solar cell will receive more red photons; therefore, solar cell performance is expected to improve. We observe evidence of downshifting in reflectance spectra. The cell Jsc decreases by 0.13 mA/cm2, and loss mechanisms are identified.


Author(s):  
Pierre Moine

Qualitatively, amorphous structures can be easily revealed and differentiated from crystalline phases by their Transmission Electron Microscopy (TEM) images and their diffraction patterns (fig.1 and 2) but, for quantitative structural information, electron diffraction pattern intensity analyses are necessary. The parameters describing the structure of an amorphous specimen have been introduced in the context of scattering experiments which have been, so far, the most used techniques to obtain structural information in the form of statistical averages. When only small amorphous volumes (< 1/μm in size or thickness) are available, the much higher scattering of electrons (compared to neutrons or x rays) makes, despite its drawbacks, electron diffraction extremely valuable and often the only feasible technique.In a diffraction experiment, the intensity IN (Q) of a radiation, elastically scattered by N atoms of a sample, is measured and related to the atomic structure, using the fundamental relation (Born approximation) : IN(Q) = |FT[U(r)]|.


1979 ◽  
Vol 20 (2) ◽  
pp. 716-728 ◽  
Author(s):  
Eva C. Freeman ◽  
William Paul

1994 ◽  
Vol 336 ◽  
Author(s):  
G. De Cesare ◽  
F. Irrera ◽  
F. Lemmi ◽  
F. Palma ◽  
M. Tucci

ABSTRACTWe present a novel family of photodetectors based on hydrogenated amorphous Si/SiC p-i-n-i-p heterostructures. Front p-i-n and rear n-i-p diodes work one as a detector and the other as a load impedance, depending on the polarity of the applied voltage. Due to different absorption at different wavelengths, the devices operate as bias-controlled light detectors in either the blue or the red regions. The energy gap and the thickness of the two intrinsic layers have been optimized to obtain a sharp wavelength selection (centered at 430 and 630 nm) with high rejection-ratios and good quantum efficiencies. The I-V characteristics and the device time response are investigated and simulated by SPICE.


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