Relationships Between Grain Boundary Structure and Material Properties

Author(s):  
Brian Ralph ◽  
Barlow Claire ◽  
Nicola Ecob

This brief review seeks to summarize some of the main property changes which may be induced by altering the grain structure of materials. Where appropriate an interpretation is given of these changes in terms of current theories of grain boundary structure, and some examples from current studies are presented at the end of this paper.

2005 ◽  
Vol 475-479 ◽  
pp. 3891-3896 ◽  
Author(s):  
Si Young Choi ◽  
Suk Joong L. Kang

The design of microstructure in materials, ranging from ultrafine, moderately sized, duplex to single crystalline, has long been a challenging subject to material scientists. A basic means to achieve this goal is related to the control of grain growth. Taking BaTiO3 as a model system, this investigation shows that control of grain boundary structure between rough and faceted and control of initial grain size can allow us to achieve the goal. When the grain boundary is rough, normal grain growth occurs with a moderate rate. On the other hand, for faceted boundaries, either abnormal grain growth or grain growth inhibition occurs resulting in a duplex grain structure or fine-grained structure, respectively. Growth of single crystals is also possible when the boundary is faceted. During crystal growth amorphous films can form and thicken at dry grain boundaries above the eutectic temperature. As the film thickness increases, the growth rate of the crystals is reduced. This observed growth behavior of grains with boundary structure is explained in terms of the difference in mobility between the two types of boundaries. The results demonstrate the basic principles of obtaining various microstructures from the same material.


Author(s):  
P. Humble

There has been sustained interest over the last few years into both the intrinsic (primary and secondary) structure of grain boundaries and the extrinsic structure e.g. the interaction of matrix dislocations with the boundary. Most of the investigations carried out by electron microscopy have involved only the use of information contained in the transmitted image (bright field, dark field, weak beam etc.). Whilst these imaging modes are appropriate to the cases of relatively coarse intrinsic or extrinsic grain boundary dislocation structures, it is apparent that in principle (and indeed in practice, e.g. (1)-(3)) the diffraction patterns from the boundary can give extra independent information about the fine scale periodic intrinsic structure of the boundary.In this paper I shall describe one investigation into each type of structure using the appropriate method of obtaining the necessary information which has been carried out recently at Tribophysics.


1975 ◽  
Vol 36 (C4) ◽  
pp. C4-17-C4-22 ◽  
Author(s):  
R. W. BALLUFFI ◽  
P. J. GOODHEW ◽  
T. Y. TAN ◽  
W. R. WAGNER

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