In-situ TEM Study of Internal and External Stress on Lithiation behavior of High Capacity Anode Materials with a Large Volume Change

2014 ◽  
Vol 20 (S3) ◽  
pp. 1536-1537
Author(s):  
Chong-Min Wang ◽  
Meng Gu ◽  
Hui Yang ◽  
Daniel E. Perea ◽  
Sulin Zhang
Nanoscale ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 3808-3816
Author(s):  
Hongjin Xue ◽  
Yong Cheng ◽  
Qianqian Gu ◽  
Zhaomin Wang ◽  
Yabin Shen ◽  
...  

A close-knit CNTs coating that in-situ grown on the SiOx particles realizes the “soft-combination” between SiOx and CNTs, thus conquering the long-lasting issues of poor conductivity and large volume change of SiOx faced.


2018 ◽  
Vol 6 (27) ◽  
pp. 13153-13163 ◽  
Author(s):  
Hui Xu ◽  
Liguang Qin ◽  
Jian Chen ◽  
Zuankai Wang ◽  
Wei Zhang ◽  
...  

The WS structure with a multipoint model succeeds in addressing the sluggish electron/ion transfer at the yolk–shell interface and structural degradation.


Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 861
Author(s):  
Zhiqi Li ◽  
Hao Sun ◽  
Yuepeng Pang ◽  
Mingming Yu ◽  
Shiyou Zheng

Lithium-sulfur (Li-S) battery is considered one of the possible alternatives for next-generation high energy batteries. However, its practical applications are still facing great challenges because of poor electronic conductivity, large volume change, and polysulfides dissolution inducing “shuttle reaction” for the S cathode. Many strategies have been explored to alleviate the aforementioned concerns. The most common approach is to embed S into carbonaceous matrix for constructing C-S composite cathodes. Herein, we fabricate the C-S cathode reduced graphene oxide-S (rGO-S) composites via one step hydrothermal and in-situ thermal reduction methods. The structural features and electrochemical properties in Li-S cells of the two type rGO-S composites are studied systematically. The rGO-S composites prepared by one step hydrothermal method (rGO-S-HT) show relatively better comprehensive performance as compared with the ones by in-situ thermal reduction method (rGO-S-T). For instance, with a current density of 100 mA g−1, the rGO-S-HT composite cathodes possess an initial capacity of 1290 mAh g−1 and simultaneously exhibit stable cycling capability. In particular, as increasing the current density to 1.0 A g−1, the rGO-S-HT cathode retains a reversible capacity of 582 mAh g−1 even after 200 cycles. The enhanced electrochemical properties can be attributed to small S particles uniformly distributed on rGO sheets enabling to significantly improve the conductivity of S and effectively buffer large volume change during lithiation/delithiation.


2019 ◽  
Vol 297 ◽  
pp. 46-54 ◽  
Author(s):  
Libing Yao ◽  
Meng Nie ◽  
Chongyang Zhu ◽  
Ran Cai ◽  
Weiwei Xia ◽  
...  

2020 ◽  
Vol 87 (4) ◽  
Author(s):  
Yingxi Wang ◽  
Leon Yeong Wei Loh ◽  
Ujjaval Gupta ◽  
Choon Chiang Foo ◽  
Jian Zhu

Abstract The buoyancy control mechanism is critical for undersea robots to achieve effective vertical motion. However, current buoyancy control mechanisms are associated with problems such as complex design, bulky structure, noisy operation, and slow response. Inspired by the swim bladder of natural fish, we develop an artificial swim bladder, using dual membranes of the dielectric elastomer, which exhibit interesting attributes, including fast response, light weight, silent operation, especially large volume change. Both the experiments and theoretical simulations are conducted to analyze the performance of this artificial swim bladder, and they quantitatively agree with each other. This artificial swim bladder of dual membranes is capable of large voltage-induced volume change, 112% larger than the conventional single-membrane design. Consequently, this soft actuator can generate a buoyancy force of 0.49 N. This artificial swim bladder demonstrates effective up-and-down motion in water, due to its large reversible volume change. Future work includes adding horizontal-motion and turning capabilities to the existing robotic structure, so that the soft robotic fish can achieve successful navigation in undersea environments.


2014 ◽  
Vol 9 (3) ◽  
pp. 187-192 ◽  
Author(s):  
Nian Liu ◽  
Zhenda Lu ◽  
Jie Zhao ◽  
Matthew T. McDowell ◽  
Hyun-Wook Lee ◽  
...  

2020 ◽  
Vol 34 (2) ◽  
pp. 2480-2491 ◽  
Author(s):  
Huihui Zeng ◽  
Baolin Xing ◽  
Chuantao Zhang ◽  
Lunjian Chen ◽  
Huihui Zhao ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 37923-37928 ◽  
Author(s):  
Min-Young Cho ◽  
Seung-Beom Yoon ◽  
Kwang-Bum Kim ◽  
Dae Soo Jung ◽  
Kwang Chul Roh

Thin carbon-coated single Fe3O4 nanocomposite were synthesized by a solvothermal process using dodecylamine. The composite structure can accommodate the large volume change of Fe3O4 and thus enabled excellent electrochemical performance.


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