Titrimetric determination of ionic and coordinated azide ion by oxidation with excess nitrite ion in acid solution

1972 ◽  
Vol 44 (11) ◽  
pp. 1870-1871 ◽  
Author(s):  
Wilton R. Biggs ◽  
Richard W. Gaver
1969 ◽  
Vol 47 (8) ◽  
pp. 817-818 ◽  
Author(s):  
A. Szewczuk ◽  
P. Mastalerz ◽  
W. Nadwyczawski

5-Vinyloxazolidine-2-thione (VOT), a goitrogenic substance occurring in plants of the family Cruciferae, was found to catalyze the reduction of iodine by azide ion, the consumption of iodine being proportional to the amount of VOT. Based on these observations, a sensitive, titrimetric method of VOT determination was developed. The new method obviates the necessity of VOT extraction from the aqueous phase with organic solvents. Sensitivity and accuracy of titrimetric determination of VOT are comparable with those of spectrophotometric procedures.


Talanta ◽  
1962 ◽  
Vol 9 (5) ◽  
pp. 452-454
Author(s):  
H.F. Combs ◽  
E.L. Grove
Keyword(s):  

1981 ◽  
Vol 4 (1) ◽  
pp. 35-41 ◽  
Author(s):  
M. L. SHANKARANARAYANA ◽  
B. RAGHAVAN ◽  
K. O. ABRAHAM ◽  
C. P. NATARAJAN

Talanta ◽  
1971 ◽  
Vol 18 (1) ◽  
pp. 112-116 ◽  
Author(s):  
P.P. Naidu ◽  
G.G. Rao

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