Metal–Organic Frameworks and Metal–Organic Framework-Derived N-Doped Porous Carbon Materials as Heterogeneous Catalysts: Chemical Fixation of Carbon Dioxide under Mild Conditions and Electrochemical Hydrogen Evolution

2019 ◽  
Vol 19 (11) ◽  
pp. 6672-6681 ◽  
Author(s):  
Karabi Nath ◽  
Chandan Kumar Karan ◽  
Kumar Biradha
Keyword(s):  
Carbon Dioxide ◽  
Porous Carbon ◽  
Heterogeneous Catalysts ◽  
Carbon Materials ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Chemical Fixation ◽  
Mild Conditions ◽  
Metal Organic ◽  
Fixation Of Carbon Dioxide

Chemical fixation of carbon dioxide catalyzed via covalent triazine frameworks as metal free heterogeneous catalysts without a cocatalyst

2019 ◽  
Vol 7 (45) ◽  
pp. 26071-26076 ◽  
Author(s):  
Yi-Meng Li ◽  
Li Yang ◽  
Lei Sun ◽  
Lei Ma ◽  
Wei-Qiao Deng ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Heterogeneous Catalysts ◽  
Chemical Fixation ◽  
Co Catalyst ◽  
Metal Free ◽  
Mild Conditions ◽  
Fixation Of Carbon Dioxide

2,5-DCP-CTF performs as an efficient metal-free catalyst in the chemical fixation of CO2 under mild conditions without the employment of any co-catalyst.

Recent Advance on Chemical Fixation of Carbon Dioxide by Metal-organic Frame-works as Heterogeneous Catalysts

2018 ◽  
Vol 22 (18) ◽  
pp. 1809-1824 ◽  
Author(s):  
Zhen Zhou ◽  
Lu Yang ◽  
Yefei Wang ◽  
Cheng He ◽  
Chunying Duan
Keyword(s):  
Carbon Dioxide ◽  
Heterogeneous Catalysts ◽  
Chemical Fixation ◽  
Metal Organic ◽  
Fixation Of Carbon Dioxide

scholarly journals Beyond pristine MOFs: carbon dioxide capture by metal–organic frameworks (MOFs)-derived porous carbon materials

RSC Advances ◽  
2017 ◽  
Vol 7 (3) ◽  
pp. 1266-1270 ◽  
Author(s):  
Hye Ryeon Kim ◽  
Tae-Ung Yoon ◽  
Seung-Ik Kim ◽  
Jihyun An ◽  
Youn-Sang Bae ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Porous Carbon ◽  
Carbon Materials ◽  
Carbon Dioxide Capture ◽  
Metal Organic Frameworks ◽  
Porous Carbon Materials ◽  
Metal Organic

Porous carbon materials were synthesized by pyrolysis of zinc-based MOFs. These materials exhibited superior CO2 capacities and better CO2 separation ability under humid conditions compared to those of the pristine MOFs.

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma
Keyword(s):  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Flexible Structures ◽  
Biodiesel Production ◽  
Biodiesel Synthesis ◽  
Metal Organic ◽  
Organic Framework

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

From metal–organic frameworks to magnetic nanostructured porous carbon composites: towards highly efficient dye removal and degradation

RSC Advances ◽  
2015 ◽  
Vol 5 (11) ◽  
pp. 8228-8235 ◽  
Author(s):  
Cong Zhang ◽  
Fanggui Ye ◽  
Shufen Shen ◽  
Yuhao Xiong ◽  
Linjing Su ◽  
...  
Keyword(s):  
High Temperature ◽  
Porous Carbon ◽  
Carbon Material ◽  
Dye Removal ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Porous Carbon Material ◽  
Carbon Composites ◽  
Highly Efficient ◽  
Metal Organic

A magnetic nanostructured porous carbon material (γ-Fe2O3/C) was easily synthesized using a microwave-enhanced high-temperature ionothermal method with an iron terephthalate metal–organic framework-MIL-53(Fe), as a template.

A New Multi-Functional Cu(II)-Organic Framework as a Platform for Selective Carbon Dioxide Chemical Fixation and Separation of Organic Dyes

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yang-Tian Yan ◽  
Chen-Yang Wang ◽  
Li-Na Zheng ◽  
Yun-Long Wu ◽  
Jiao Liu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Benzoic Acid ◽  
Organic Dyes ◽  
Metal Organic Framework ◽  
Chemical Fixation ◽  
Acid Ligand ◽  
Metal Organic ◽  
Organic Framework

A new multi-functional metal-organic framework, {[Cu2(HL)(H2O)2]·NMP·2H2O}n (1), was assembled employing a asymmetrical V-shaped rigid multicarboxylic acid ligand H5L (H5L= 2,4-di(2′,5′-dicarboxylphenyl)benzoic acid) with Cu(II) ions. 1 possesses a 3D pore formed...

Selective adsorption behaviour of carbon dioxide in OH-functionalized metal–organic framework materials

CrystEngComm ◽  
2017 ◽  
Vol 19 (36) ◽  
pp. 5346-5350 ◽  
Author(s):  
Jinjie Qian ◽  
Jinni Shen ◽  
Qipeng Li ◽  
Yue Hu ◽  
Shaoming Huang
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bond ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Adsorption Behaviour ◽  
Weak Hydrogen Bond ◽  
Oh Groups ◽  
Framework Materials ◽  
Metal Organic

The theoretically optimal adsorption locations in hydroxyl (OH)-decorated metal–organic frameworks show that the captured CO2 molecules interact with the cis-μ2-OH groups in an end-on mode, which shows a moderate to weak hydrogen bond.

Efficient Solvent-Free Carbon Dioxide Fixation Reactions with Epoxides Under Mild Conditions by Mixed-Ligand Zinc(II) Metal-Organic Frameworks

ChemCatChem ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 2401-2408 ◽  
Author(s):  
Parth Patel ◽  
Bhavesh Parmar ◽  
Rukhsana I. Kureshy ◽  
Noor-ul Khan ◽  
Eringathodi Suresh
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Fixation ◽  
Mixed Ligand ◽  
Free Carbon ◽  
Solvent Free ◽  
Mild Conditions ◽  
Free Carbon Dioxide ◽  
Metal Organic

Metal–organic framework-derived porous carbon polyhedra for highly efficient capacitive deionization

2015 ◽  
Vol 51 (60) ◽  
pp. 12020-12023 ◽  
Author(s):  
Yong Liu ◽  
Xingtao Xu ◽  
Miao Wang ◽  
Ting Lu ◽  
Zhuo Sun ◽  
...  
Keyword(s):  
Electrode Material ◽  
Porous Carbon ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Capacitive Deionization ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

Porous carbon polyhedra were synthesized through direct carbonization of metal–organic frameworks and used as an electrode material for capacitive deionization.

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