Dual-Band Luminescent Lead-Free Antimony Chloride Halides with Near-Unity Photoluminescence Quantum Efficiency

2019 ◽  
Vol 31 (22) ◽  
pp. 9363-9371 ◽  
Author(s):  
Zhongyuan Li ◽  
Ye Li ◽  
Pei Liang ◽  
Tianliang Zhou ◽  
Le Wang ◽  
...  
2002 ◽  
Vol 12 (03) ◽  
pp. 659-690 ◽  
Author(s):  
ARNOLD GOLDBERG

Since the first demonstration of the quantum well infrared photodetector (QWIP) in the 1980s, there has been much progress in the application of QWIPs to the production infrared (IR) imaging systems. At this time, focal plane arrays (FPAs) made from QWIPs are readily available for insertion in IR cameras with formats as large as 640 × 480 pixels. Several organizations now have commercially available IR camera systems using QWIPs. In spite of the low single-pixel quantum efficiency relative to MCT, excellent IR imagery has been demonstrated with large format (640 × 480 pixels) single-band and moderate format (256 × 256 pixels) dual-band FPAs. With a large-format staring FPA, one can integrate the signal current for a relatively long time to produce images of similar quality to that from a scanned line array run at the same frame rate. In fact, it can be shown that due to the nature of the noise in a QWIP device, the noise performance of a QWIP FPA can be better than that of MCT FPA as long as the conversion efficiency (the product of the quantum efficiency and the photoconductive gain) is high enough for the read-out integrated circuit (ROIC) integration capacitor to be filled in a frame time. In this chapter the results of laboratory and field tests on large-format single-color QWIP FPAs operating in the LWIR band and dual-band FPAs operating in both the MWIR and LWIR bands simultaneously will be shown. Single-color and dual-band arrays will be shown to give excellent imaging performance and that dual-band FPAs offer unique capabilities to investigate the phenomenology of targets and backgrounds. The performance of the FPAs will be presented from a system performance perspective over a wide range of operating conditions (temperature, bias, integration time, etc.). Results of measurements of noise-equivalent temperature difference (NEΔT), minimum resolvable temperature difference (MRTD measured as a function of target spatial frequency), responsivity, and dark current will be reported. Imagery collected in the field will show the utility of large-format LWIR FPAs for increasing the range at which targets can be identified over previous-generation scanning imagers. Dual-band imagery collected using a QWIP FPA will show how such an array as part of a future imaging system may be able to exploit differences in the IR signatures of targets and backgrounds in the MWIR and LWIR bands to enhance the visibility of targets in cluttered environments. We also show how such an array can be used to make accurate remote temperature measurements. Finally, we will compare the performance of state-of-the-art FPAs made from QWIPs and MCT.


2021 ◽  
pp. 2584-2593
Author(s):  
Gijun Seo ◽  
Hyocheol Jung ◽  
Tielyr D. Creason ◽  
Vishal Yeddu ◽  
Matthew Bamidele ◽  
...  

2021 ◽  
Author(s):  
Mohammad Bashirpour ◽  
Saeed Khankalantary ◽  
Mohammadreza Kolahdouz

Abstract A new dual band thin film metal-semiconductor-metal infrared photodetector base on InGaAs for wavelength of 1.1–1.7 µm and InSb for wavelength of 3–5 µm is proposed and investigated numerically. One major problem of thin film photodetectors is low quantum efficiency that originates from low optical absorption. The quantum efficiency of proposed structure is improved by locating the array of optimized aluminum nanostructure (Al-NS) between the InGaAs and InSb layers. Using optimized Al-NS between the stack of InGaAs and InSb (InSb/Al-NS/InGaAs) results in plasmon excitation inside the photosensitive layers and so, higher photocarrier generation. Moreover, locating zinc oxide nanorode as an antireflection coating on top of detector reduces the incident light reflection in both spectrum of 1.1–1.7 µm and 3–5 µm. The finite different time domain method is used to investigated the optical properties of proposed structure and optimize the structure. According to the simulation results, designed structure gives rise to 108.1%, 110% and 320% light absorption enhancement at wavelength of 1.33 µm, 1.55 µm and 4 µm, respectively compared to reference conventional structure.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Hong Chen ◽  
Lin Zhu ◽  
Chen Xue ◽  
Pinlei Liu ◽  
Xuerong Du ◽  
...  

AbstractSolution-processed metal-halide perovskites are emerging as one of the most promising materials for displays, lighting and energy generation. Currently, the best-performing perovskite optoelectronic devices are based on lead halides and the lead toxicity severely restricts their practical applications. Moreover, efficient white electroluminescence from broadband-emission metal halides remains a challenge. Here we demonstrate efficient and bright lead-free LEDs based on cesium copper halides enabled by introducing an organic additive (Tween, polyethylene glycol sorbitan monooleate) into the precursor solutions. We find the additive can reduce the trap states, enhancing the photoluminescence quantum efficiency of the metal halide films, and increase the surface potential, facilitating the hole injection and transport in the LEDs. Consequently, we achieve warm-white LEDs reaching an external quantum efficiency of 3.1% and a luminance of 1570 cd m−2 at a low voltage of 5.4 V, showing great promise of lead-free metal halides for solution-processed white LED applications.


Author(s):  
Marco Vallone ◽  
Michele Goano ◽  
Alberto Tibaldi ◽  
Stefan Hanna ◽  
Anne Wegmann ◽  
...  

2019 ◽  
Vol 10 (17) ◽  
pp. 4573-4579 ◽  
Author(s):  
Aifei Wang ◽  
Yanyan Guo ◽  
Zhaobo Zhou ◽  
Xianghong Niu ◽  
Yonggang Wang ◽  
...  

Aqueous acid-based synthesis of lead-free tin halide perovskites with near-unity photoluminescence quantum efficiency and high chemical yield is described.


Author(s):  
Chao Xie ◽  
Yi Liang ◽  
Chengyun Dong ◽  
Xiaowei Tong ◽  
Wenhua Yang ◽  
...  

Multispectral photodetection has garnered enormous research interest and is always challenging to date. Here, we present the realization of an electrically adjusted single-band/dual-band photodetector based on an inorganic lead-free halide...


Author(s):  
Barbara Trask ◽  
Susan Allen ◽  
Anne Bergmann ◽  
Mari Christensen ◽  
Anne Fertitta ◽  
...  

Using fluorescence in situ hybridization (FISH), the positions of DNA sequences can be discretely marked with a fluorescent spot. The efficiency of marking DNA sequences of the size cloned in cosmids is 90-95%, and the fluorescent spots produced after FISH are ≈0.3 μm in diameter. Sites of two sequences can be distinguished using two-color FISH. Different reporter molecules, such as biotin or digoxigenin, are incorporated into DNA sequence probes by nick translation. These reporter molecules are labeled after hybridization with different fluorochromes, e.g., FITC and Texas Red. The development of dual band pass filters (Chromatechnology) allows these fluorochromes to be photographed simultaneously without registration shift.


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