Enhancing the Synergistic Effect of Cellulose and Polypropylene for Petrochemical Production during Catalytic Fast Pyrolysis by Mesoporous Gallium-MFI Zeolites

Author(s):  
Xiangyu Li ◽  
Yongqiang Pang ◽  
Zheng Ding ◽  
Jian Li ◽  
Xingyi Jiang ◽  
...  
2016 ◽  
Vol 522 ◽  
pp. 109-119 ◽  
Author(s):  
David P. Gamliel ◽  
Hong Je Cho ◽  
Wei Fan ◽  
Julia A. Valla

Catalysts ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 854
Author(s):  
Jian Li ◽  
Xiangyu Li ◽  
Derun Hua ◽  
Xinning Lu ◽  
Yujue Wang

A series of gallium-containing MFI (Ga-MFI) zeolites with varying Ga2O3/Al2O3 ratios were synthesized using hydrothermal synthesis and tested as catalyst in catalytic fast pyrolysis (CFP) of beech wood for aromatic production. The results show that the incorporation of Ga slightly reduced the effective pore size of Ga-MFI zeolites compared to conventional HZSM-5 zeolites. Therefore, the Ga-MFI zeolites increased the aromatic selectivity for smaller aromatics such as benzene, toluene, and p-xylene and decreased the aromatic selectivity for bulkier ones such as m-xylene, o-xylene, and polyaromatics in CFP of beech wood relative to HSZM-5. In particular, the yield and selectivity of p-xylene, the most desired product from CFP of biomass, increased considerably from 1.64 C% and 33.3% for conventional HZSM-5 to 2.98–3.34 C% and 72.1–79.6% for the synthesized Ga-MFI zeolites. These results suggest that slightly reducing the pore size of MFI zeolite by Ga incorporation has a beneficial effect on optimizing the aromatic selectivity toward more valuable monoaromatic products, especially p-xylene, during CFP of biomass.


2019 ◽  
Vol 143 ◽  
pp. 104669 ◽  
Author(s):  
Qiang Lu ◽  
Zhen-xi Zhang ◽  
Xiao-ning Ye ◽  
Kai Li ◽  
Min-shu Cui ◽  
...  

2021 ◽  
Vol 9 (3) ◽  
pp. 1235-1245
Author(s):  
Richard J. French ◽  
Kristiina Iisa ◽  
Kellene A. Orton ◽  
Michael B. Griffin ◽  
Earl Christensen ◽  
...  

2021 ◽  
Vol 127 ◽  
pp. 141-146
Author(s):  
Jun Zhang ◽  
Jing Gu ◽  
Haoran Yuan ◽  
Yong Chen

2013 ◽  
Vol 455 ◽  
pp. 114-121 ◽  
Author(s):  
Xiangyu Li ◽  
Haifeng Zhang ◽  
Jian Li ◽  
Lu Su ◽  
Jiane Zuo ◽  
...  

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