High Yield of CO and Synchronous S Recovery from the Conversion of CO2 and H2S in Natural Gas Based on a Novel Electrochemical Reactor

The requirement for curde oil and natural gas is still increasing. It was observed a growing of interested in the exploration and exploatation of unconventional fuels, including shate gas. There is about 3 to 5 trilion cubic meters resources of that type of gas in Poland. The latest data predicts that in addition to gas in the shale is also petroleum. The development of this branch of mining in our country can cause a significant increase in demand for pipes. The results of basic research of experimental steels for pipe line are presented in this article. Analyse of published materials about steels for pipe line was done. The chemical composition of two types of new steels meeting the requirements for X80 and X100 grade plates according API 5L norm were developed. The heat tratment using dilatometer DIL 805A/D were carried out. The influnce of heat temperature before rolling proces on structure of austenite was defined. The heating schemes were proposed for obtaining a high yield, while not allowing the dissolution of the alloying elements inhibit austenite grain overdevelopment. For samples after tests the structure of primary austenite and the size of former austenite grains were determined. The influence of deformation cinditions on structure were determinated, too. The results obtained from the examinations will be used to develop a technology for rolling sheets of pipelines in the category of X80 and X100 according to the API.

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Quality films from carbon fiber evaporation for thorough coverage of TEM grids

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100104157 ◽

1988 ◽

Vol 46 ◽

pp. 418-419

Author(s):

N. Tempel ◽

M. C. Ledbetter

Keyword(s):

Electron Microscopy ◽

High Resolution Electron Microscopy ◽

Carbon Films ◽

Low Noise ◽

Vacuum Evaporation ◽

High Yield ◽

Good Adhesion ◽

Noise Structure ◽

Resolution Electron ◽

Carbon Foils

Carbon films have been a support of choice for high resolution electron microscopy since the introduction of vacuum evaporation of carbon. The desirable qualities of carbon films and methods of producing them has been extensively reviewed. It is difficult to get a high yield of grids by many of these methods, especially if virtually all of the windows must be covered with a tightly bonded, quality film of predictable thickness. We report here a method for producing carbon foils designed to maximize these attributes: 1) coverage of virtually all grid windows, 2) freedom from holes, wrinkles or folds, 3) good adhesion between film and grid, 4) uniformity of film and low noise structure, 5) predictability of film thickness, and 6) reproducibility.Our method utilizes vacuum evaporation of carbon from a fiber onto celloidin film and grid bars, adhesion of the film complex to the grid by carbon-carbon contact, and removal of the celloidin by acetone dissolution. Materials must be of high purity, and cleanliness must be rigorously maintained.

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Effects of high pressure on the crystallization of carbon fiber reinforced polyetheretherketone (CF/PEEK) laminate composites

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100177519 ◽

1990 ◽

Vol 48 (4) ◽

pp. 876-877

Author(s):

Hong-Ming Lin ◽

C. H. Liu ◽

R. F. Lee

Keyword(s):

High Pressure ◽

Carbon Fiber ◽

Sample Surface ◽

High Yield ◽

Fiber Reinforced ◽

Laminate Composites ◽

Peek Composite ◽

Continuous Carbon Fiber ◽

Carbon Fiber Reinforced

Polyetheretherketone (PEEK) is a crystallizable thermoplastic used as composite matrix materials in application which requires high yield stress, high toughness, long term high temperature service, and resistance to solvent and radiation. There have been several reports on the crystallization behavior of neat PEEK and of CF/PEEK composite. Other reports discussed the effects of crystallization on the mechanical properties of PEEK and CF/PEEK composites. However, these reports were all concerned with the crystallization or melting processes at or close to atmospheric pressure. Thus, the effects of high pressure on the crystallization of CF/PEEK will be examined in this study.The continuous carbon fiber reinforced PEEK (CF/PEEK) laminate composite with 68 wt.% of fibers was obtained from Imperial Chemical Industry (ICI). For the high pressure experiments, HIP was used to keep these samples under 1000, 1500 or 2000 atm. Then the samples were slowly cooled from 420 °C to 60 °C in the cooling rate about 1 - 2 degree per minute to induce high pressure crystallization. After the high pressure treatment, the samples were scanned in regular DSC to study the crystallinity and the melting temperature. Following the regular polishing, etching, and gold coating of the sample surface, the scanning electron microscope (SEM) was used to image the microstructure of the crystals. Also the samples about 25mmx5mmx3mm were prepared for the 3-point bending tests.

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Catalytic enantioselective synthesis of indolizino[8,7-b]indole alkaloid derivatives based on the tandem reaction of tertiary enamides

Organic Chemistry Frontiers ◽

10.1039/d0qo01147a ◽

2021 ◽

Author(s):

Xin-Ming Xu ◽

Ming Xie ◽

Jiazhu Li ◽

Mei-Xiang Wang

Keyword(s):

Indole Alkaloid ◽

Enantioselective Synthesis ◽

High Yield ◽

Tandem Reaction ◽

Indole Derivatives

An exquisite Pybox/Cu(OTf)2-catalyzed asymmetric tandem reaction of tertiary enamides was developed, which enabled the expeditious synthesis of indolizino[8,7-b]indole derivatives in high yield, excellent enantioselectivity and diastereoselectivity.

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