Effects of high pressure on the crystallization of carbon fiber reinforced polyetheretherketone (CF/PEEK) laminate composites

Author(s):  
Hong-Ming Lin ◽  
C. H. Liu ◽  
R. F. Lee

Polyetheretherketone (PEEK) is a crystallizable thermoplastic used as composite matrix materials in application which requires high yield stress, high toughness, long term high temperature service, and resistance to solvent and radiation. There have been several reports on the crystallization behavior of neat PEEK and of CF/PEEK composite. Other reports discussed the effects of crystallization on the mechanical properties of PEEK and CF/PEEK composites. However, these reports were all concerned with the crystallization or melting processes at or close to atmospheric pressure. Thus, the effects of high pressure on the crystallization of CF/PEEK will be examined in this study.The continuous carbon fiber reinforced PEEK (CF/PEEK) laminate composite with 68 wt.% of fibers was obtained from Imperial Chemical Industry (ICI). For the high pressure experiments, HIP was used to keep these samples under 1000, 1500 or 2000 atm. Then the samples were slowly cooled from 420 °C to 60 °C in the cooling rate about 1 - 2 degree per minute to induce high pressure crystallization. After the high pressure treatment, the samples were scanned in regular DSC to study the crystallinity and the melting temperature. Following the regular polishing, etching, and gold coating of the sample surface, the scanning electron microscope (SEM) was used to image the microstructure of the crystals. Also the samples about 25mmx5mmx3mm were prepared for the 3-point bending tests.

2021 ◽  
pp. 089270572110214
Author(s):  
Weiller M Lamin ◽  
Flávio LS Bussamra ◽  
Rafael TL Ferreira ◽  
Rita CM Sales ◽  
José E Baldo

This work presents the experimental determination of fracture mechanics parameters of composite specimens manufactured by fused filament fabrication (FFF) with continuous carbon fiber reinforced thermoplastic filaments, based on Linear Elastic Fracture Mechanics (LEFM). The critical mode I translaminar fracture toughness (KIc) and the critical energy release rate (GIc) are found for unidirectional and cross-ply laminates. The specimens were submitted to quasi-static tensile testing. Digital Image Correlation (DIC) is used to find the stress field. The stress fields around the crack tip are compared to linear elastic finite element simulations. The results demonstrate the magnitude of fracture toughness is in the same range as for polymers and some metals, depending on lay-up configuration. Besides, fractographic analyses show some typical features as river lines, fiber impression, fiber pulls-out and porosity aspects.


2021 ◽  
pp. 002199832110075
Author(s):  
Minchang Sung ◽  
Hyunchul Ahn ◽  
Jinhyeok Jang ◽  
Dongil Kwon ◽  
Woong-Ryeol Yu

The fracture strain of carbon fiber-reinforced plastics (CFRPs) within CFRP/steel hybrid laminate composites is reportedly higher than that of CFRPs due to transverse compressive stress induced by the steel lamina. A micromechanical model was developed to explain this phenomenon and also to predict the mechanical behavior of CFRP/steel hybrid laminate composites. First, the shear lag theory was extended to calculate stress distributions on fibers and matrix material in a CFRP under multiaxial stress condition, considering three deformation states of matrix (elastic and plastic deformation and fracture) and the transverse compressive stress. Then, the deformation behavior of CFRP was predicted using average stress in the ineffective region and the Weibull distribution of carbon fibers. Finally, the mechanical properties of CFRP/steel hybrid laminate composites were predicted by considering the thermal residual stress generated during the manufacturing process. The micromechanical model revealed that increased transverse compressive stress decreases the ineffective lengths of partially broken fibers in the CFRP and results in increased fracture strain of the CFRP, demonstrating the validity of the current micromechanical model.


Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 301
Author(s):  
Jiale Hu ◽  
Suhail Mubarak ◽  
Kunrong Li ◽  
Xu Huang ◽  
Weidong Huang ◽  
...  

Three-dimensional (3D) printing of continuous fiber-reinforced composites has been developed in recent decades as an alternative means to handle complex structures with excellent design flexibility and without mold forming. Although 3D printing has been increasingly used in the manufacturing industry, there is still room for the development of theories about how the process parameters affect microstructural properties to meet the mechanical requirements of the printed parts. In this paper, we investigated continuous carbon fiber-reinforced polyphenylene sulfide (CCF/PPS) as feedstock for fused deposition modeling (FDM) simulated by thermocompression. This study revealed that the samples manufactured using a layer-by-layer process have a high tensile strength up to 2041.29 MPa, which is improved by 68.8% compared with those prepared by the once-stacked method. Moreover, the mechanical–microstructure characterization relationships indicated that the compactness of the laminates is higher when the stacked CCF/PPS are separated, which can be explained based on both the void formation and the nanoindentation results. These reinforcements confirm the potential of remodeling the layer-up methods for the development of high-performance carbon fiber-reinforced thermoplastics. This study is of great significance to the improvement of the FDM process and opens broad prospects for the aerospace industry and continuous fiber-reinforced polymer matrix materials.


2016 ◽  
Vol 42 (5) ◽  
pp. 178-184 ◽  
Author(s):  
Hiroyuki OGUMA ◽  
Tomoya KUMAGAI ◽  
Daisuke SAKAMOTO ◽  
Masahiro SEKINE ◽  
Norio HIRAYAMA ◽  
...  

2016 ◽  
Vol 17 (12) ◽  
pp. 2143-2152 ◽  
Author(s):  
Xiaoping Chen ◽  
Lihua Zhan ◽  
Minghui Huang ◽  
Tengfei Chang ◽  
Shujian Li ◽  
...  

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