Birnessite as a Highly Efficient Catalyst for Low-Temperature NH3-SCR: The Vital Role of Surface Oxygen Vacancies

2020 ◽  
Vol 59 (33) ◽  
pp. 14606-14615
Author(s):  
Xue Fang ◽  
Yongjun Liu ◽  
Wanglai Cen ◽  
Yan Cheng
2014 ◽  
Vol 4 (10) ◽  
pp. 3611-3614 ◽  
Author(s):  
Haili Huang ◽  
Wenpo Shan ◽  
Shijian Yang ◽  
Jinhua Zhang

A highly-efficient NH3-SCR catalyst, CeO2/WO3–TiO2, was prepared by a novel stepwise precipitation approach. This catalyst showed excellent catalytic performance with superior low-temperature activity, high N2 selectivity and a broad operational temperature window.


ChemSusChem ◽  
2021 ◽  
Author(s):  
Meng-Jie Zhao ◽  
Sheng-Ying Su ◽  
Ning Deng ◽  
Jun-Qing Shi ◽  
Fang Li ◽  
...  

Fuel ◽  
2021 ◽  
Vol 303 ◽  
pp. 121239
Author(s):  
Zhiping Zhang ◽  
Yingying Li ◽  
Piaoping Yang ◽  
Yushi Li ◽  
Chen Zhao ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1020
Author(s):  
Yizhe Helian ◽  
Suping Cui ◽  
Xiaoyu Ma

Selective catalytic reduction (SCR) technology is the most widely used flue gas denitration technology at present. The stability of a catalyst is the main factor limiting the development of this technology. In this study, an environmentally friendly and highly efficient NH3-SCR catalyst was prepared by coprecipitation method from acidolysis residue of industrial waste and tourmaline. We found that the addition of tourmaline has an important impact on the denitration activity of the catalytic material. The NOx conversion exceeded 97% at 200 °C with the dosage of 10% tourmaline, which is about 7% higher than that without doping. The improvement of catalytic performance was mostly attributed to the permanent electrodes of tourmaline, which effectively promotes the dispersion of MnOx/TiO2 catalytic materials, increases the number of acidic sites and changes the valence distribution of manganese ions in products, which speeds up the diffusion of protons and ions, resulting in the acceleration of redox reaction. These as-developed tourmaline-modified MnOx/TiO2 materials have been demonstrated to be promising as a new type of highly efficient low-temperature NH3-SCR catalyst.


ACS Catalysis ◽  
2015 ◽  
Vol 5 (10) ◽  
pp. 5973-5983 ◽  
Author(s):  
Dongmei Meng ◽  
Wangcheng Zhan ◽  
Yun Guo ◽  
Yanglong Guo ◽  
Li Wang ◽  
...  

Fuel ◽  
2021 ◽  
Vol 283 ◽  
pp. 119336
Author(s):  
Lu Liu ◽  
Bangda Wang ◽  
Xiaojiang Yao ◽  
Lin Yang ◽  
Wenju Jiang ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (24) ◽  
pp. 14809-14815 ◽  
Author(s):  
Min Wang ◽  
Lingxia Zhang ◽  
Weimin Huang ◽  
Yajun Zhou ◽  
Han Zhao ◽  
...  

The obtained catalyst Pt/MnO2-48 h demonstrated complete removal of 20 ppm C2H4at 50 °C for at least 12 h due to the large amount of adsorbed oxygen species and synergetic catalytic effect between Pt and the MnO2support.


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