Classical Model of Surface Enhanced Infrared Absorption (SEIRA) Spectroscopy

2022 ◽  
Author(s):  
Yuan Gao ◽  
D. E. Aspnes ◽  
Stefan Franzen
Keyword(s):  
Infrared Absorption ◽  
Classical Model ◽  
Surface Enhanced

scholarly journals Surface-Enhanced Infrared Absorption of o-Nitroaniline on Nickel Nanoparticles Synthesized by Electrochemical Deposition

2014 ◽  
Vol 2014 ◽  
pp. 1-9 ◽  
Author(s):  
Yufang Niu ◽  
Jie Yao ◽  
Keyu Wang
Keyword(s):  
Infrared Absorption ◽  
Indium Tin Oxide ◽  
Nickel Nanoparticles ◽  
Ph Value ◽  
Glass Plate ◽  
Nickel Sulfate ◽  
Nickel Chloride ◽  
Attenuated Total Reflection ◽  
Enhancement Effect ◽  
Surface Enhanced

Nickel nanoparticles were electrochemically deposited on indium-tin oxide (ITO) coated glass plate in a modified Watt’s electrolyte. The surface-enhanced infrared absorption (SEIRA) effect of the nanoparticles was evaluated by attenuated total reflection spectroscopy (ATR-FTIR) using o-nitroaniline as a probe molecule. Electrodeposition parameters such as deposition time, pH value, and the type of surfactants were investigated. The morphology and the microstructure of the deposits were characterized by the field emission scanning electron microscope (FESEM) and the atomic force microscope (AFM), respectively. The results indicate that the optimum parameters were potential of 1.3 V, time of 30 s, and pH of 8.92 in the solution of 0.3756 mol/L diethanolamine, 0.1 mol/L nickel sulfate, 0.01 mol/L nickel chloride, and 0.05 mol/L boric acid. The FESEM observation shows that the morphology of nickel nanoparticles with best enhancement effect is spherical and narrowly distributed particles with the average size of 50 nm. SEIRA enhancement factor is about 68.

Surface-enhanced near-infrared absorption (SENIRA) spectroscopy

2016 ◽  
Author(s):  
Wei-Chuan Shih ◽  
Fusheng Zhao ◽  
Ousamma Zenasni ◽  
Masud Arnob ◽  
Yulung Sung
Keyword(s):  
Infrared Absorption ◽  
Near Infrared ◽  
Surface Enhanced

Surfactant-assisted electroless deposition of silver nanoparticles on Ge crystal for ultra-sensitive detection by surface-enhanced infrared absorption spectroscopy

RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 20390-20395 ◽  
Author(s):  
Gadupudi Purna Chandra Rao ◽  
Vairaperumal Tharmaraj ◽  
Jyisy Yang
Keyword(s):  
Silver Nanoparticles ◽  
Absorption Spectroscopy ◽  
Infrared Absorption ◽  
Electroless Deposition ◽  
Sensitive Detection ◽  
Infrared Absorption Spectroscopy ◽  
Highly Sensitive ◽  
Surface Enhanced ◽  
Surfactant Assisted

Fabrication of highly sensitive substrates for SEIRA measurements via assistance of surfactant to electrolessly deposit silver nanoparticles on Ge crystal.

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