Photochemical Kinetics of a Phosphine Oxide Free Radical Initiator from Femtosecond UV-Pump/Mid-IR-Probe Spectroscopy

2017 ◽  
Vol 121 (26) ◽  
pp. 4914-4922 ◽  
Author(s):  
Steffen Straub ◽  
Jörg Lindner ◽  
Peter Vöhringer
Keyword(s):  
Free Radical ◽  
Phosphine Oxide ◽  
Radical Initiator ◽  
Free Radical Initiator ◽  
Probe Spectroscopy ◽  
Kinetics Of

The role of lipid, free radical initiator, and oxygen on the kinetics of lipid peroxidation

1982 ◽  
Vol 63 (1) ◽  
pp. 21-28 ◽  
Author(s):  
Richard C. Dirks ◽  
Morris D. Faiman ◽  
Earl S. Huyser
Keyword(s):  
Lipid Peroxidation ◽  
Free Radical ◽  
Radical Initiator ◽  
Free Radical Initiator ◽  
Kinetics Of ◽  
Lipid Free Radical

PNIPAM-based graft copolymers prepared using potassium persulfate as free-radical initiator: synthesis reproducibility

2016 ◽  
Vol 294 (6) ◽  
pp. 981-991 ◽  
Author(s):  
Nívia N. Marques ◽  
Bruna V. Lima ◽  
Valdelice R. Silveira ◽  
Bruna L. B. Lima ◽  
Ana M. S. Maia ◽  
...  
Keyword(s):  
Free Radical ◽  
Graft Copolymers ◽  
Potassium Persulfate ◽  
Radical Initiator ◽  
Free Radical Initiator

Polymerization of Diphenylbutadiyne Derivatives in Solution by Free Radical Initiator

2007 ◽  
Vol 44 (6) ◽  
pp. 605-611 ◽  
Author(s):  
Miriam F. Beristain ◽  
Eduardo Muñoz ◽  
Takeshi Ogawa
Keyword(s):  
Free Radical ◽  
Radical Initiator ◽  
Free Radical Initiator

Polymerization of Cyclic Acetals by a Free Radical Initiator, Perfluorodibenzoyl Peroxide, in the Presence of Oxygen

2005 ◽  
Vol 38 (14) ◽  
pp. 5841-5843 ◽  
Author(s):  
Yu Yang ◽  
František Mikeš ◽  
Yoshiyuki Okamoto
Keyword(s):  
Free Radical ◽  
Cyclic Acetals ◽  
Radical Initiator ◽  
Free Radical Initiator

1-(Trimethylsilyl)-1,2,4-triazene: A Novel Free Radical Initiator

2002 ◽  
Vol 177 (5) ◽  
pp. 1109-1116 ◽  
Author(s):  
S. Munavalli ◽  
D. K. Rohrbaugh ◽  
D. I. Rossman ◽  
H. D. Durst
Keyword(s):  
Free Radical ◽  
Radical Initiator ◽  
Free Radical Initiator

scholarly journals Effect of Oxygen and Initiator Solubility on Admicellar Polymerization of Styrene on Silica Surfaces

2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
Pohlee Cheah ◽  
Caitlin N. Bhikha ◽  
John H. O’Haver ◽  
Adam E. Smith
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Emulsion Polymerization ◽  
Water Soluble ◽  
Polymer Yield ◽  
Radical Initiator ◽  
Admicellar Polymerization ◽  
Molecular Weights ◽  
Precipitated Silica ◽  
Free Radical Initiator

Although admicellar polymerization has been termed the surface analog of emulsion polymerization, previous reports utilizing free radical-initiated admicellar polymerization relied on high levels of the free radical initiator when compared to emulsion polymerization, likely due to the presence of oxygen in the reported admicellar polymerization systems. Admicellar polymerizations of styrene on the surface of precipitated silica initiated by either a water-soluble or a water-insoluble initiator were studied to determine the effect of dissolved oxygen and free radical initiator solubility on the kinetics, yield, and molecular weight of the polymer formed. Results show that the presence of oxygen reduces the polymer yield and limits molecular weight. The solubility of the initiator also affected the polymer formed in the admicellar polymerization of styrene. While monomer conversions and polymer yield were similar, the molecular weights of polymerizations initiated by a water-soluble initiator were higher than comparable polymerizations initiated by a water-insoluble initiator.

Reaction products of α-tocopherol with a free radical initiator, 2,2′-azobis(2,4-dimethylvaleronitrile)

Lipids ◽  
1989 ◽  
Vol 24 (3) ◽  
pp. 204-209 ◽  
Author(s):  
Roy Yamauchi ◽  
Tomoatsu Matsui ◽  
Yasuko Satake ◽  
Koji Kato ◽  
Yoshimitsu Ueno
Keyword(s):  
Free Radical ◽  
Reaction Products ◽  
Radical Initiator ◽  
Free Radical Initiator
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