Water Vapor Sorption Properties of Polyethylene Terephthalate over a Wide Range of Humidity and Temperature

2017 ◽  
Vol 121 (8) ◽  
pp. 1953-1962 ◽  
Author(s):  
Florence Dubelley ◽  
Emilie Planes ◽  
Corine Bas ◽  
Emmanuelle Pons ◽  
Bernard Yrieix ◽  
...  
1968 ◽  
Vol 51 (9) ◽  
pp. 1339-1344 ◽  
Author(s):  
E. Berlin ◽  
B.A. Anderson ◽  
M.J. Pallansch

RSC Advances ◽  
2017 ◽  
Vol 7 (2) ◽  
pp. 975-984 ◽  
Author(s):  
Ling Li ◽  
Lei Lv ◽  
Ru-Dan Huang

Six new coordination polymers have been synthesized based on terphenyl tetracarboxylates (H4L1, H4L2) and bis-pyridyl ligands (bpfp, bpe and bpmp).


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 524
Author(s):  
Greta Giacobazzi ◽  
Claudio Gioia ◽  
Micaela Vannini ◽  
Paola Marchese ◽  
Valérie Guillard ◽  
...  

The dynamic and equilibrium water vapor sorption properties of amorphous and highly crystalline poly(ethylene vanillate) (PEV) films were determined via gravimetric analysis, at 20 °C, over a wide range of relative humidity (0–95% RH). At low RH%, the dynamic of the sorption process obeys Fick’s law while at higher relative humidity it is characterized by a drift ascribable to non-Fickian relaxations. The non-Fickian relaxations, which are responsible for the incorporation of additional water, are correlated with the upturn of the sorption isotherms and simultaneously the hysteresis recorded between sorption and desorption cycles. The sorption isotherms of amorphous and highly crystalline PEV are arranged in the same concentration range of that of PET proving the similarity of the two polyesters. Water diffusion coefficients, whose determination from individual kinetic sorption/desorption curves required treatment with the Barens–Hopfenberg model, were demonstrated to be ≈10× higher for amorphous PEV compared to amorphous PET. Such a difference originates from the enhanced segmental flexibility of PEV chains.


2011 ◽  
Vol 56 (3) ◽  
pp. 642-645 ◽  
Author(s):  
Yi Wang ◽  
Cong Guan ◽  
Kean Wang ◽  
Chun Xian Guo ◽  
Chang Ming Li

1992 ◽  
Vol 57 (5) ◽  
pp. 959-968 ◽  
Author(s):  
Michał Rozwadowski ◽  
Jerzy Włoch ◽  
Krzysztof Erdmann ◽  
Jan Kornatowski

The possibility of zeolite Y modification by controlled deposition of coke during the process of methanol conversion was studied. It was found, that coke deposits lower the sorption capacity of the zeolite, which yields the possibility to obtain modified zeolite of definite sorption properties. The process of coking was analysed using the results of kinetic measurements, XRD, IR, TGA, and sorption-isotherms determination. The Polanyi-Dubinin potential theory was applied to describe the water-vapor sorption isotherms.


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