Finding the Needle in a Haystack: Capturing Veiled Plexcitonic Coupling through Differential Spectroscopy

2020 ◽  
Vol 124 (48) ◽  
pp. 26387-26395
Author(s):  
Meera Mohankumar ◽  
Mahima Unnikrishnan ◽  
Gopal Narmada Naidu ◽  
Sanoop Mambully Somasundaran ◽  
Mavilakizhakke Puthiyaveetil Ajaykumar ◽  
...  
2010 ◽  
Vol 3 (6) ◽  
pp. 1629-1646 ◽  
Author(s):  
H. K. Roscoe ◽  
M. Van Roozendael ◽  
C. Fayt ◽  
A. du Piesanie ◽  
N. Abuhassan ◽  
...  

Abstract. In June 2009, 22 spectrometers from 14 institutes measured tropospheric and stratospheric NO2 from the ground for more than 11 days during the Cabauw Intercomparison Campaign of Nitrogen Dioxide measuring Instruments (CINDI), at Cabauw, NL (51.97° N, 4.93° E). All visible instruments used a common wavelength range and set of cross sections for the spectral analysis. Most of the instruments were of the multi-axis design with analysis by differential spectroscopy software (MAX-DOAS), whose non-zenith slant columns were compared by examining slopes of their least-squares straight line fits to mean values of a selection of instruments, after taking 30-min averages. Zenith slant columns near twilight were compared by fits to interpolated values of a reference instrument, then normalised by the mean of the slopes of the best instruments. For visible MAX-DOAS instruments, the means of the fitted slopes for NO2 and O4 of all except one instrument were within 10% of unity at almost all non-zenith elevations, and most were within 5%. Values for UV MAX-DOAS instruments were almost as good, being 12% and 7%, respectively. For visible instruments at zenith near twilight, the means of the fitted slopes of all instruments were within 5% of unity. This level of agreement is as good as that of previous intercomparisons, despite the site not being ideal for zenith twilight measurements. It bodes well for the future of measurements of tropospheric NO2, as previous intercomparisons were only for zenith instruments focussing on stratospheric NO2, with their longer heritage.


1993 ◽  
Vol 324 ◽  
Author(s):  
N. Dietz ◽  
D.J. Stephens ◽  
G. Lucovsky ◽  
K.J. Bachmann

AbstractBrewster Angle Reflectance Differential Spectroscopy (BARDS) has been proposed as an optical method for real-time characterization of the growth of thin films. BARDS is based on changes in the reflectivity, Rp, of parallel (p)-polarized light incident at, or near, the Brewster angle of the substrate material. Changes in R are sufficiently large to monitor layer growth, and to determine the thickness and the optical constants of the deposited film. In this paper we extend the method to multilayer film deposition. The derivative properties of R are correlated with differences in the optical constants of the two materials, and with the sharpness of their interface. We present spectra for SiO2/Si3N4/SiO2/Si, demonstrating some of these aspects of this new and effective approach to in-situ monitoring.


1987 ◽  
Vol 36 (12) ◽  
pp. 6581-6584 ◽  
Author(s):  
H. Mathieu ◽  
P. Lefebvre ◽  
J. Allegre ◽  
B. Gil ◽  
A. Regreny

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